Related papers: Detection of TiH$_2$ molecule in the interstellar …
Interstellar hydrides -- that is, molecules containing a single heavy element atom with one or more hydrogen atoms -- were among the first molecules detected outside the solar system. They lie at the root of interstellar chemistry, being…
The molecular species hydrogen peroxide, HOOH, is likely to be a key ingredient in the oxygen and water chemistry in the interstellar medium. Our aim with this investigation is to determine how abundant HOOH is in the cloud core {\rho} Oph…
Using previous measurements and quantum chemical calculations to derive the molecular properties of the TiH molecule, we obtain new values for its ro-vibrational constants, thermochemical data, spectral line lists, line strengths, and…
The presence of carbon-chain molecules in the interstellar medium (ISM) has been known since the early 1970s and $>130$ such species have been identified to date, making up $\sim 43$% of the total of detected ISM molecules. They are…
The interstellar medium (ISM) seems to have a significant surplus of oxygen which was dubbed as the "O crisis": independent of the adopted interstellar reference abundance, the total number of O atoms depleted from the gas phase far exceeds…
We report the first detection in the interstellar medium of a C$_2$H$_5$O$_2$N isomer: $syn$-glycolamide (NH$_2$C(O)CH$_2$OH). The exquisite sensitivity at sub-mK levels of an ultra-deep spectral survey carried out with the Yebes 40m and…
The first observations of deuterium and oxygen in the Local Interstellar Medium (LISM) obtained with the Far Ultraviolet Spectroscopic Explorer (FUSE) can be used to search for local abundance variations. While the very limited sample of…
Molecular oxygen has been the subject of many observational searches as chemical models predicted it to be a reservoir of oxygen. Although it has been detected in two regions of the interstellar medium, its rarity is a challenge for…
Molecular hydrogen is the most abundant molecule in the universe. It is the first one to form and survive photo-dissociation in tenuous environments. Its formation involves catalytic reactions on the surface of interstellar grains. The…
Observations show that the global deuterium-to-hydrogen ratio (D/H) in the local interstellar medium (ISM) is about 90% of the primordial ratio predicted by big bang nucleosynthesis. The high (D/H)$_{ISM}$ implies that only a small fraction…
The origin of the observed variability of the gas-phase D/H ratio in the local interstellar medium is still debated, and in particular the role of deuterium depletion onto dust grains. Here we extend the study of the relationship between…
The interstellar medium (ISM) has a multiphase structure characterized by gas, dust and molecules. The gas can be found in different charge states: neutral, low-ionized (warm) and high-ionized (hot). It is possible to probe the multiphase…
We present observations of Ti~II~$\lambda 3384$ absorption towards 15 distant stars in the Galactic halo and the Magellanic Clouds. These new data extend existing surveys of the distribution of Ti$^+$ to larger distances from the plane of…
We present the first detection in space of thionylimide (HNSO) toward the Galactic Center molecular cloud G+0.693-0.027, thanks to the superb sensitivity of an ultradeep molecular line survey carried out with the Yebes 40$\,$m and IRAM…
The majority of hydrogen in the interstellar medium (ISM) is in atomic form. The transition from atoms to molecules and, in particular, the formation of the H$_2$ molecule, is a key step in cosmic structure formation en route to stars.…
The chemical compounds carrying the thiol group (-SH) have been considered essential in recent prebiotic studies regarding the polymerization of amino acids. We have searched for this kind of compounds toward the Galactic Centre quiescent…
Current measurements indicate that the deuterium abundance in diffuse interstellar gas varies spatially by a factor of ~4 among sightlines extending beyond the Local Bubble. One plausible explanation for the scatter is the variable…
Oxygen is the third most abundant element in the universe, but its chemistry in the interstellar medium is still not well understood. In order to critically examine the entire oxygen budget, we attempt here initially to estimate the…
As an exoplanet transits its host star, some of the light from the star is absorbed by the atoms and molecules in the planet's atmosphere, causing the planet to seem bigger; plotting the planet's observed size as a function of the…
The presence of H3+ in the interstellar medium was forecast almost four decades ago. Almost three decades ago it was asserted that its reactions with neutral molecular and atomic species directly lead to the production of many of the…