Related papers: Detection of TiH$_2$ molecule in the interstellar …
We use a simple one-zone model of the thermal and chemical evolution of interstellar gas to study whether molecular hydrogen (H2) is ever an important coolant of the warm, diffuse interstellar medium (ISM). We demonstrate that at solar…
Carbon chains are sometimes considered as possible carriers of some diffuse interstellar bands. Spectroscopic observations in UV band carried by spectrometer STIS fed with HST, give us the possibility to detect many interstellar molecules.…
We report the first detection of SiC$_2$ in the interstellar medium. The molecule was identified through six rotational transitions toward G\,+0.693$-$0.027, a molecular cloud located in the Galactic center. The detection is based on a line…
When a slightly defective rutile TiO$_2$(110) surface is exposed to O$_2$ at elevated temperatures, the molecule dissociates at defects, filling O vacancies (\ov) and creating O adatoms (\oad) on {\tifc} rows. The adsorption of molecular…
The formation of molecules in the interstellar medium (ISM) remains a complex and unresolved question in astrochemistry. A group of molecules of particular interest involves the linkage between a -carboxyl and -amine group, similar to that…
The recent detection of the hydrocarbon anion C6H- in the interstellar medium has led us to investigate the synthesis of hydrocarbon anions in a variety of interstellar and circumstellar environments. We find that the anion/neutral…
The first experimental formation of thiocarbonic acid (H$_2$CO$_3$) is presented in this work from low-temperature interstellar ice analogs composed of hydrogen sulfide (H$_2$S) and carbon disulfide (CS$_2$) exposed to electron irradiation…
Gas-phase hydroxylamine (NH$_2$OH) has recently been detected within dense clouds in the interstellar medium. However, it is also likely present within interstellar ices, as well as on the icy surfaces of outer Solar System bodies, where it…
Supersonic turbulence results in strong density fluctuations in the interstellar medium (ISM), which have a profound effect on the chemical structure. Particularly useful probes of the diffuse ISM are the ArH$^+$, OH$^+$, H$_2$O$^+$…
C$_2$H is a representative hydrocarbon that is abundant and ubiquitous in the interstellar medium (ISM). To study its chemical properties, we present Submillimeter Array (SMA) observations of the C$_2$H $N=3-2$ and HC$_3$N $J=30-29$…
Molecular hydrogen (H2) is the primary component of the reservoirs of cold, dense gas that fuel star formation in our galaxy. While the H2 abundance is ultimately regulated by physical processes operating on small scales in the interstellar…
The interstellar medium (ISM) is a key ingredient in galaxy formation and evolution as it provides the molecular gas reservoir which fuels star formation and supermassive black hole accretion. Yet the ISM is one of the least studied aspects…
Contrary to popular belief, the interstellar medium (ISM) is not empty; it is filled with atoms, dust particles, and molecules. Some of these molecules may have been the very building blocks of life that, delivered to Earth via comets and…
The interstellar medium (ISM) of galaxies very often contains a gas component that reaches the temperature of several million degrees, whose physical and chemical properties can be investigated through imaging and spectroscopy in the…
We present a semi-analytical description of the relative HD/H2 abundance in the diffuse interstellar medium. We found three asymptotics of the relative HD/H$_2$ abundance for different parts of the medium and their dependence on the…
The Interstellar Medium (ISM) comprises gases at different temperatures and densities, including ionized, atomic, molecular species, and dust particles. The neutral ISM is dominated by neutral hydrogen and has ionization fractions up to 8%.…
We present numerical computations and analytic scaling relations for interstellar ion-molecule gas phase chemistry down to very low metallicities ($ 10^{-3} \times$ solar), and/or up to high driving ionization rates. Relevant environments…
A gas-phase formation route is proposed for the recently detected propargylimine molecule. In analogy to other imines, such as cyanomethanimine, the addition of a reactive radical (C$_2$H in the present case) to methanimine (CH$_2$NH})…
The interstellar medium (ISM) is a very complex medium which contains the matter needed to form stars and planets. The ISM is in permanent interaction with radiation, turbulence, magnetic and gravitational fields, and accelerated particles.…
We describe the assignment of a previously unidentified interstellar absorption line to ArH$^+$ and discuss its relevance in the context of hydride absorption in diffuse gas with a low H$_2$ fraction. The column densities along several…