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We propose here a two-dimensional material based on a single layer of violet or Hittorf's phosphorus. Using first-principles density functional theory, we find it to be energetically very stable, comparable to other previously proposed…

Materials Science · Physics 2016-06-13 Georg Schusteritsch , Martin Uhrin , Chris J. Pickard

Structural degeneracies underpin the ferroic behavior of next-generation two-dimensional materials, and lead to peculiar two-dimensional structural transformations under external fields, charge doping and/or temperature. The most direct…

Mesoscale and Nanoscale Physics · Physics 2020-06-19 Albert Du , Zachary Pendergrast , Salvador Barraza-Lopez

We report the results of density functional theory (DFT) based calculations on monolayer and bilayer green phosphorene and their heterostructures with MoSe2. Both monolayer and bilayer green phosphorene are direct band gap semiconductors…

Materials Science · Physics 2018-11-26 Sumandeep Kaur , Ashok Kumar , Sunita Srivastava , K. Tankeshwar , Ravindra Pandey

Low-dimensional multiferroicity, though highly scarce in nature, has attracted great attention due to both fundamental and technological interests. Using first-principles density functional theory, we show that ferromagnetism and…

Materials Science · Physics 2018-07-26 Jingshan Qi , Hua Wang , Xiaofang Chen , Xiaofeng Qian

We simulate the electronic and transport properties of metal/two-dimensional material/metal vertical heterostructures, with a focus on graphene, hexagonal boron nitride and two phases of molybdenum diselenide. Using density functional…

Mesoscale and Nanoscale Physics · Physics 2025-02-06 Gaëlle Bigeard , Zineb Kerrami , François Triozon , Alessandro Cresti

We study the mechanical and electronic properties of heterobilayers composed of black phosphorus (BP) on hexagonal boron nitride (hBN) and of blue phosphorus (\Pblue) on hBN by means of ab-intio density functional theory. Emphasis is put on…

Materials Science · Physics 2020-07-15 Baptiste Bienvenu , Hakim Amara , François Ducastelle , Lorenzo Sponza

The results of differential-thermal analysis of various samples as well as dielectric measurements of solid solutions $TlIn_{1-x}Fe_x^{56,57}S_2$ are presented. It has been established that phase transitions become blurred and shift to low…

Condensed Matter · Physics 2007-05-23 R. M. Sardarli , A. P. Abdullayev , O. A. Samedov , N. A. Eubova , B. R. Gadjiyev

Since the advent of graphene, two-dimensional (2D) materials become very attractive and there is growing interest to explore new 2D beyond graphene. Here, through density functional theory (DFT) calculations, we predict 2D wide-band-gap…

Mesoscale and Nanoscale Physics · Physics 2016-10-31 Xue-Jing Zhang , Bang-Gui Liu

Artificial semiconductor heterostructures played a pivotal role in modern electronic and photonic technologies, providing a highly effective mean for the manipulation and control of carriers, from the visible to the far-infrared. Despite…

Mesoscale and Nanoscale Physics · Physics 2018-05-01 Leonardo Viti , Miriam S. Vitiello

Monolayers of group VA elements have attracted great attention with the rising of black phosphorus. Here, we derive a simple tight-binding model for monolayer grey arsenic, referred as arsenene (ML-As), based on the first-principles…

Materials Science · Physics 2018-09-19 Jin Yu , Mikhail I. Katsnelson , Shengjun Yuan

Many properties of layered materials change as they are thinned from their bulk forms down to single layers, with examples including indirect-to-direct band gap transition in 2H semiconducting transition metal dichalcogenides as well as…

We suggest indirect excitons in 2D semiconductor heterostructures as a platform for realization of a bosonic analog of the Bardeen-Cooper-Schrieffer superconductor. The quantum phase transition to a biexcitonic gapped state can be…

Quantum Gases · Physics 2016-10-12 Sergey V. Andreev

We study the conversion of bulk Se and Te, consisting of intertwined a helices, to structurally very dissimilar, atomically thin two-dimensional (2D) layers of these elements. Our ab initio calculations reveal that previously unknown and…

Mesoscale and Nanoscale Physics · Physics 2018-08-29 Dan Liu , Xianqing Lin , David Tomanek

Anisotropy refers to the property of a material exhibiting directionally dependent features. In this paper, we introduce black phosphorous (BP), the most stable allotrope of phosphorus in layered orthorhombic structure with a bandgap of 0.3…

Mesoscale and Nanoscale Physics · Physics 2014-07-30 Fengnian Xia , Han Wang , Yichen Jia

Moir\'e superlattices of van der Waals heterostructures provide a powerful new way to engineer the electronic structures of two-dimensional (2D) materials. Many novel quantum phenomena have emerged in different moir\'e heterostructures,…

Atomic and electronic structures of phosphorene nanoribbons are studied within density functional theory. These novel materials present different physical phenomena expected in two very different physical systems: one dimensional metallic…

Materials Science · Physics 2014-04-22 Ajanta Maity , Akansha Singh , Prasenjit Sen

We review the basic optical, electronic, optoelectronic, thermoelectric and mechanical properties of few-layer black phosphorus (BP), a layered semiconductor that can be exfoliated from bulk BP, the most stable allotrope of phosphorus. The…

Mesoscale and Nanoscale Physics · Physics 2017-10-17 Andrey Chaves , W. Ji , J. Maassen , T. Dumitrica , T. Low

Next-generation electronics calls for new materials beyond silicon for increased functionality, performance, and scaling in integrated circuits. Carbon nanotubes and semiconductor nanowires are at the forefront of these materials, but have…

Materials Science · Physics 2016-07-15 Mervin Zhao , Yu Ye , Yimo Han , Yang Xia , Hanyu Zhu , Yuan Wang , David A. Muller , Xiang Zhang

The electronic structure of a vortex line trapped by a planar defect in a type-II superconductor is analyzed within the Bogoliubov-de Gennes theory. The normal reflection of electrons and holes at the defect plane results in the topological…

Superconductivity · Physics 2020-11-11 A. V. Samokhvalov , V. D. Plastovets , A. S. Mel'nikov

In this letter, we show that a new class of two-dimensional phosphorus allotropes can be constructed via assembling the previously proposed ultrathin metastable phosphorus nanotube into planar structures in different stacking orientations.…

Materials Science · Physics 2018-05-02 Zhenqing Li , Chaoyu He , Tao Ouyang , Chunxiao Zhang , Cao Tang , Rudolf A. Romer , Jianxin Zhong