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Due to efficient scaling with electron number N, density functional theory (DFT) is widely used for studies of large molecules and solids. Restriction of an exact mean-field theory to local potential functions has recently been questioned.…

Other Condensed Matter · Physics 2015-06-24 Robert K. Nesbet

By applying dynamical mean-field theory in combination with exact diagonalization at zero temperature to a half-filled Hubbard model with two orbitals having distinct noninteracting densities of states, we show that an orbital selective…

Strongly Correlated Electrons · Physics 2016-03-17 Ze-Yi Song , Hunpyo Lee , Yu-Zhong Zhang

For electronic systems with multi-reference (MR) character, Kohn-Sham density functional theory (KS-DFT) with the conventional exchange-correlation (xc) energy functionals can lead to incorrect spin densities and related properties. For…

Chemical Physics · Physics 2024-06-14 Yu-Yang Wang , Jeng-Da Chai

We discuss the notions of spin-orbital polarization and ordering in paramagnetic materials, and address their consequences in transition metal oxides. Extending the combined density functional and dynamical mean field theory scheme to the…

Strongly Correlated Electrons · Physics 2014-12-16 Cyril Martins , Markus Aichhorn , Loig Vaugier , Silke Biermann

Neutron scattering was used to determine the spin structure and the magnon spectrum of the Mott--Hubbard insulator YTiO$_3$. The magnetic structure is complex, comprising substantial G-type and A-type antiferromagnetic components in…

Strongly Correlated Electrons · Physics 2009-11-07 C. Ulrich , G. Khaliullin , S. Okamoto , M. Reehuis , A. Ivanov , H. He , Y. Taguchi , Y. Tokura , B. Keimer

The magnetic properties of the transition metal monoxides MnO and NiO are investigated at equilibrium and under pressure via several advanced first-principles methods coupled with Heisenberg Hamiltonian MonteCarlo. The comparative…

Strongly Correlated Electrons · Physics 2015-05-28 T. Archer , C. D. Pemmaraju , S. Sanvito , C. Franchini , J. He , A. Filippetti , P. Delugas , D. Puggioni , V. Fiorentini , R. Tiwari , P. Majumdar

The dynamical mean-field theory together with the non-crossing approximation is used to set up a novel scheme to study the electronic structure of strongly correlated electron systems. The non-interacting band structure is obtained from a…

Strongly Correlated Electrons · Physics 2007-05-23 M. B. Zoelfl , Th. Pruschke , J. Keller , A. I. Poteryaev , I. A. Nekrasov , V. I. Anisimov

A band structure description of the observed large band gaps and moments in both the antiferromagnetic (AFM) and paramagnetic (PM) phases of the classic NaCl-structure Mott insulators MnO, FeO, CoO, and NiO is provided by ordinary,…

Materials Science · Physics 2018-01-10 Giancarlo Trimarchi , Alex Zunger

In this work, we propose a self-consistent minimization procedure for functionals in reduced density matrix functional theory. We introduce an effective noninteracting system at finite temperature which is capable of reproducing the…

Other Condensed Matter · Physics 2015-03-20 Tim Baldsiefen , E. K. U. Gross

The doping induced insulator-metal transition in $La_{1-x}Sr_{x}TiO_{3}$ is studied using the ab-initio LDA+DMFT method. Combining the LDA bandstructure for the actual, distorted structure found recently with multi-orbital DMFT to treat…

Strongly Correlated Electrons · Physics 2016-08-31 L. Craco , M. S. Laad , S. Leoni , E. Müller-Hartmann

Iron-based superconductivity develops near an antiferromagnetic order and out of a bad metal normal state, which has been interpreted as originating from a proximate Mott transition. Whether an actual Mott insulator can be realized in the…

The insulating state is one of the most basic electronic phases in condensed matter. This state is characterised by an energy gap for electronic excitations that makes an insulator electrically inert at low energy. However, for complex…

Using conceptually and procedurally consistent density functional theory (DFT) calculations with an advanced meta-GGA exchange-correlation functional in ab initio molecular dynamics simulations, we determine the insulator-metal transition…

This study leverages density function theory (DFT) accompanied with Boltzmann transport equation approaches to investigate the electronic mobility as a function of inorganic substitution and functionalization in a thermally stable UiO-66…

Materials Science · Physics 2018-05-09 Terence D. Musho , Alhassan S. Yasin

In this study, we evaluate the predictive power of density functional theory (DFT) for the magnetic properties of MnBi\(_2\)Te\(_4\) (MBT), an intrinsically magnetic topological insulator with potential applications in spintronics and…

We address the nature of the Mott transition in the Hubbard model at half-filling using cluster Dynamical Mean Field Theory (DMFT). We compare cluster DMFT results with those of single site DMFT. We show that inclusion of the short range…

Strongly Correlated Electrons · Physics 2009-11-13 H. Park , K. Haule , G. Kotliar

Quantum transitions between the Mott insulator and metals by controlling filling in two-dimensional square lattice are characterized by a large dynamical exponent $z=4$ where the origin of unusual metallic properties near the Mott insulator…

Strongly Correlated Electrons · Physics 2007-05-23 Masatoshi Imada , Fakher F. Assaad , Hirokazu Tsunetsugu , Yukitoshi Motome

Providing highly simplified models of strongly correlated electronic systems that challenge {\it ab initio} calculations can serve as a valuable testing ground to improve these methods. In this study, we present a comprehensive study of the…

Strongly Correlated Electrons · Physics 2025-09-25 Jila Amini , Mojtaba Alaei , Stefano de Gironcoli

To efficiently manipulate magnetism is a key physical issue for modern condensed matter physics, which is also crucial for magnetic functional applications. Most previous relevant studies rely on the tuning of spin texture, while the spin…

Strongly Correlated Electrons · Physics 2020-11-04 Yakui Weng , Xing'ao Li , Shuai Dong

Density functional theory (DFT) embedding provides a formally exact framework for interfacing correlated wave-function theory (WFT) methods with lower-level descriptions of electronic structure. Here, we report techniques to improve the…

Chemical Physics · Physics 2015-06-12 Jason D. Goodpaster , Taylor A. Barnes , Frederick R. Manby , Thomas F. Miller
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