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We generalize nonequilibrium integral equalities to situations involving absolutely irreversible processes for which the forward-path probability vanishes and the entropy production diverges, rendering conventional integral fluctuation…

Statistical Mechanics · Physics 2016-08-11 Yûto Murashita , Ken Funo , Masahito Ueda

We derive quantum nonequilibrium equalities in absolutely irreversible processes. Here by absolute irreversibility we mean that in the backward process the density matrix does not return to the subspace spanned by those eigenvectors that…

Statistical Mechanics · Physics 2015-07-14 Ken Funo , Yûto Murashita , Masahito Ueda

The question of how irreversibility can emerge as a generic phenomena when the underlying mechanical theory is reversible has been a long-standing fundamental problem for both classical and quantum mechanics. We describe a mechanism for the…

Quantum Physics · Physics 2013-09-20 Cozmin Ududec , Nathan Wiebe , Joseph Emerson

The entropy production is commonly interpreted as measuring the distance from equilibrium. However, this explanation lacks a rigorous description due to the absence of a natural equilibrium measure. The present analysis formalizes this…

Statistical Mechanics · Physics 2025-10-23 David Andrieux

Through extended consideration of two wide classes of case studies -- dilute gases and linear systems -- I explore the ways in which assumptions of probability and irreversibility occur in contemporary statistical mechanics, where the…

Statistical Mechanics · Physics 2021-04-23 David Wallace

It is shown that the Gibbs paradox is actually paralogism, viz. an erroneous statement sounding credible due to the statistic-mechanical interpretation of entropy as a measure of "any and all" irreversibility. As an alternative, the…

General Physics · Physics 2014-02-10 V. A. Etkin

This paper discusses the thermodynamic irreversibility realized in high-dimensional Hamiltonian systems with a time-dependent parameter. A new quantity, the irreversible information loss, is defined from the Lyapunov analysis so as to…

Statistical Mechanics · Physics 2009-10-31 Shin-ichi Sasa , Teruhisa S. Komatsu

Statistical thermodynamics is valuable as a conceptual structure that shapes our thinking about equilibrium thermodynamic states. A cloud of unresolved questions surrounding the foundations of the theory could lead an impartial observer to…

Statistical Mechanics · Physics 2025-10-31 O. B. Ericok , J. K. Mason

A generalization of the Gibbs entropy postulate is proposed based on the BBGKY hierarchy as the nonequilibrium entropy for a system of N interacting particles. This entropy satisfies the basic principles of thermodynamics in the sense that…

Statistical Mechanics · Physics 2007-05-23 A. Perez-Madrid

Recently a number of approaches has been developed to connect the microscopic dynamics of particle systems to the macroscopic properties of systems in nonequilibrium stationary states, via the theory of dynamical systems. This way a direct…

Statistical Mechanics · Physics 2009-10-31 L. Rondoni , E. G. D. Cohen

We assume that markovian dynamics on a finite graph enjoys a gauge symmetry under local scalings of the probability density, derive the transformation law for the transition rates and interpret the thermodynamic force as a gauge potential.…

Statistical Mechanics · Physics 2015-05-30 Matteo Polettini

We introduce a new information-theoretic formulation of quantum measurement uncertainty relations, based on the notion of relative entropy between measurement probabilities. In the case of a finite-dimensional system and for any approximate…

Mathematical Physics · Physics 2018-03-02 Alberto Barchielli , Matteo Gregoratti , Alessandro Toigo

Irreversibility is one of the most intriguing concepts in physics. While microscopic physical laws are perfectly reversible, macroscopic average behavior has a preferred direction of time. According to the second law of thermodynamics, this…

Quantum Physics · Physics 2017-04-12 T. B. Batalhao , A. M. Souza , R. S. Sarthour , I. S. Oliveira , M. Paternostro , E. Lutz , R. M. Serra

Irreversibility is a fundamental concept with important implications at many levels. It pinpoints the fundamental difference between the intrinsically reversible microscopic equations of motion and the unidirectional arrow of time that…

Quantum Physics · Physics 2019-05-01 T. B. Batalhao , S. Gherardini , J. P. Santos , G. T. Landi , M. Paternostro

The second law of thermodynamics, which deals with irreversibility and makes the theory so special, is usually considered empirical. The definition of equilibrium as an attractor, on the other hand, requires a postulate. This article shows…

History and Philosophy of Physics · Physics 2026-04-29 Didier Lairez

We propose a new approach concerning the introduction of time-irreversibility in statistical mechanics. It is based on a transition function defined in terms of path integral and verifying a time-irreversible equation. We show first how…

Statistical Mechanics · Physics 2015-03-02 J. P. Badiali

Gibbs paradox in the context of statistical mechanics addresses the issue of additivity of entropy of mixing gases. The usual discussion attributes the paradoxical situation to classical distinguishability of identical particles and credits…

Quantum Physics · Physics 2018-11-12 C. S. Unnikrishnan

We consider irreversible translation-invariant interacting particle systems on the $d$-dimensional cubic lattice with finite local state space, which admit at least one Gibbs measure as a time-stationary measure. Under some mild degeneracy…

Probability · Mathematics 2025-09-30 Benedikt Jahnel , Jonas Köppl

The existence of observables that are incompatible or not jointly measurable is a characteristic feature of quantum mechanics, which lies at the root of a number of nonclassical phenomena, such as uncertainty relations, wave--particle dual…

Quantum Physics · Physics 2015-11-17 Huangjun Zhu

The existence of incompatibility is one of the most fundamental features of quantum theory, and can be found at the core of many of the theory's distinguishing features, such as Bell inequality violations and the no-broadcasting theorem. A…

Quantum Physics · Physics 2018-06-27 Sergey N. Filippov , Teiko Heinosaari , Leevi Leppäjärvi
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