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Though several theoretical models have been proposed to design electronic flat-bands, the definite experimental realization in two-dimensional atomic crystal is still lacking. Here we propose a novel and realistic flat-band model based on…

Materials Science · Physics 2021-02-04 Jiang Zeng , Ming Lu , Haiwen Liu , Hua Jiang , X. C. Xie

High-entropy MBenes (HE-MBenes) represent a promising, unexplored class of 2D materials for electrocatalysis. In this work, we present a systematic computational screening of 56 equiatomic quinary HE-MBene compositions from the {Ti, V, Cr,…

Materials Science · Physics 2026-05-12 Sree Harsha Bharadwaj H , Raghavan Ranganathan

Chalcogen vacancies in the semiconducting monolayer transition-metal dichalcogenides (TMDs) have frequently been invoked to explain a wide range of phenomena, including both unintentional p-type and n-type conductivity, as well as sub-band…

Materials Science · Physics 2024-02-27 Shoaib Khalid , Bharat Medasani , John L. Lyons , Darshana Wickramaratne , Anderson Janotti

In the last few years, interest in monomolecular layers of transition metal dichalcogenides (TMDs) has been driven by their unusual electronic and optical properties, which are very attractive for designing functional elements of new…

Mesoscale and Nanoscale Physics · Physics 2021-12-08 P. L. Pekh , P. V. Ratnikov , A. P. Silin

Based on first-principles simulations and calculations, we explore the evolution of crystal structure, electronic structure and transport properties of quasi 2D layered PdS2 under uniaxial stress and hydrostatic pressure. The coordination…

Superconductivity · Physics 2020-07-01 Wen Lei , Wei Wang , Xing Ming , Shengli Zhang , Gang Tang , Xiaojun Zheng , Huan Li , Carmine Autieri

Quantum Monte Carlo (QMC) is applied to obtain the fundamental (quasiparticle) electronic band gap, $\Delta_f$, of a semiconducting two-dimensional (2D) phosphorene whose optical and electronic properties fill the void between graphene and…

Mesoscale and Nanoscale Physics · Physics 2019-02-06 Tobias Frank , Rene Derian , Kamil Tokar , Lubos Mitas , Jaroslav Fabian , Ivan Stich

Semiconducting transition metal dichalcogenides (TMDs) have emerged as materials that can be used to realize two-dimensional (2D) crystals possessing rather unique transport and optical properties. Most research has so far focused on sulfur…

Density Functional Tight-Binding (DFTB), an approximative approach derived from Density Functional Theory (DFT), has the potential to pave the way for simulations of large periodic or non-periodic systems. We have specifically tailored DFTB…

Recent results on the optical properties of mono- and few-layers of semiconducting transition metal dichalcogenides are reviewed. Experimental observations are presented and discussed in the frame of existing models, highlighting the limits…

Mesoscale and Nanoscale Physics · Physics 2017-09-19 M. Koperski , M. R. Molas , A. Arora , K. Nogajewski , A. O. Slobodeniuk , C. Faugeras , M. Potemski

By performing high-throughput first-principles calculations combined with a semiempirical van der Waals dispersion correction, we have screened 74 direct- and 185 indirect-gap two dimensional (2D) nonmagnetic semiconductors from near 1000…

Mesoscale and Nanoscale Physics · Physics 2022-12-12 Vei Wang , Gang Tang , Ren-Tao Wang , Ya-Chao Liu , Hiroshi Mizuseki , Yoshiyuki Kawazoe , Jun Nara , Wen-Tong Geng

Substitutional transition metal (TM) point defects have recently been controllably introduced in two-dimensional (2D) transition metal dichalcogenides. We identify quantum defect candidates through a first-principles materials discovery…

Materials Science · Physics 2025-10-13 Jingda Zhang , Su Ying Quek

Two-dimensional (2D) transition metal dichalcogenide (TMD) van der Waals heterostructures (vdWHs) hold promise for high-performance electronics, but their large-scale synthesis remains limited by size constraints and alloying…

Materials Science · Physics 2026-02-26 Luneng Zhao , Hongsheng Liu , Yuan Chang , Xiaoran Shi , Jijun Zhao , Feng Ding , Junfeng Gao

Doping via electrostatic gating is a powerful and widely used technique to tune the electron densities in layered materials. The microscopic details of how these setups affect the layered material are, however, subtle and call for careful…

Mesoscale and Nanoscale Physics · Physics 2021-01-15 Peiliang Zhao , Jin Yu , H. Zhong , Malt. Rosner , Mikhail I. Katsnelson , Shengjun Yuan

This study presents a comprehensive first-principles investigation of the structural, electronic and optical properties of monolayer \ch{Mo_{1-x}W_xS2} alloys, systematically exploring the full compositional range ($x=0$ to $1$) using…

The QS$GW$ method is used to study the electronic band structure, optical dielectric function, and exchange interactions in chalcopyrite, $I\bar{4}2d$, structure MnGeP$_2$. The material is found to be an antiferromagnetic semiconductor with…

Materials Science · Physics 2025-10-16 Ilteris K. Turan , Walter R L. Lambrecht , Jerome Jackson

Two-dimensional transition metal dichalcogenides (TMDs) of Mo and W in their 1T' crystalline phase host the quantum spin Hall (QSH) insulator phase. We address the electronic properties of the QSH edge states by means of first-principles…

Materials Science · Physics 2019-07-30 Artem Pulkin , Oleg V. Yazyev

Unlike covalent two-dimensional (2D) materials like graphene, 2D metals have non-layered structures due to their non-directional, metallic bonding. While experiments on 2D metals are still scarce and challenging, density-functional theory…

Materials Science · Physics 2023-01-06 Kameyab Raza Abidi , Pekka Koskinen

Magnetic quantum oscillations (MQO) are traditionally applied to investigate the electronic structure of metals. In layered quasi-two-dimensional (Q2D) materials the MQO have several qualitative features giving additional useful…

Strongly Correlated Electrons · Physics 2024-05-17 Taras Mogilyuk , Pavel Grigoriev , Vladislav Kochev , Ivan Volokhov , Ilya Polishchuk

We report quasiparticle-energy calculations of the electronic bandstructure as measured by valence-band photoemission for selected II-VI compounds and group-III-nitrides. By applying GW as perturbation to the ground state of the fictitious,…

Materials Science · Physics 2009-11-11 Patrick Rinke , Abdallah Qteish , Joerg Neugebauer , Christoph Freysoldt , Matthias Scheffler

The recent discovery of ambient-pressure superconductivity in thin-film bilayer nickelates opens new possibilities for investigating electronic structures in this new class of high-transition temperature $T_C$ superconductors. Here, we…