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Two-dimensional (2D) materials have become a fertile playground for the exploration and manipulation of novel collective electronic states. Recent experiments have unveiled a variety of robust 2D orders in highly-crystalline materials…

Since the advent of graphene, two-dimensional (2D) materials become very attractive and there is growing interest to explore new 2D beyond graphene. Here, through density functional theory (DFT) calculations, we predict 2D wide-band-gap…

Mesoscale and Nanoscale Physics · Physics 2016-10-31 Xue-Jing Zhang , Bang-Gui Liu

Understanding and controlling the electronic properties of two-dimensional materials is crucial for their potential applications in nano- and optoelectronics. Monolayer transition metal dichalcogenides such as WS$_2$ have garnered…

We present a novel "linear combination of atomic orbitals"-type of approximation, enabling accurate electronic structure calculations for systems of up to 20 or more electronically coupled quantum dots. Using realistic single quantum dot…

Mesoscale and Nanoscale Physics · Physics 2021-03-10 Alexander Mittelstädt , Ludwig A. Th. Greif , Stefan T. Jagsch , Andrei Schliwa

The structural, electronic, and dielectric (optical) properties of graphene-like 2D MgO monolayer have been explored through first-principles calculations under bi-axial tensile and compressive mechanical strain within a range of -10% to…

Materials Science · Physics 2024-05-31 Kamal Kumar , Anjali Kumari , Soni Mishra , Ramesh Sharma , Abhishek Kumar Mishra

Based on first-principles calculations we show that the oxidation of ultrathin films of Ca$_2$N electrides, electrenes, drives a hexagonal$\rightarrow$tetragonal structural transition. The ground state configuration of the oxidized…

Materials Science · Physics 2020-05-06 Pedro H. Souza , José E. Padilha , Roberto H. Miwa

Heterostructures are ubiquitous in many optoelectronic devices and as photocatalysts. One of the key features of a heterojunction is the proper band alignment between the two materials. Estimation of the correct relative band positions with…

Mesoscale and Nanoscale Physics · Physics 2024-08-13 Raheel Hammad , Snehith Adabala , Soumya Ghosh

A study is presented of the electronic band structure and optical absorption spectrum of monolayer WSe$_2$ using an all-electron quasiparticle self-consistent $GW$ approach, QS$G\hat W$, in which the screened Coulomb interaction $\hat W$ is…

Materials Science · Physics 2024-02-29 Niloufar Dadkhah , Walter R. L. Lambrecht

We investigate a simplified continuum model of a twisted homotrilayer TMD with negligible next-nearest layer couplings. We systematically analyze band structure and topology of various stacking configurations in a twist angle range from…

Mesoscale and Nanoscale Physics · Physics 2023-10-10 Hassan AlBuhairan , Michael Vogl

The band structure and electronic properties in a series of vinylene-linked heterocyclic conducting polymers are investigated using density functional theory (DFT). In order to accurately calculate electronic band gaps, we utilize hybrid…

Materials Science · Physics 2015-03-13 Bryan M. Wong , Joseph G. Cordaro

Monolayer transition metal dichalcogenides (TMDs) offer a novel two-dimensional platform for semiconductor devices. One such application, whereby the added low dimensional crystal physics (i.e. optical spin selection rules) may prove TMDs a…

Mesoscale and Nanoscale Physics · Physics 2020-02-05 Matthew Brooks , Guido Burkard

Chemical bonding and electronic structure of MgB2, a boron-based newly discovered superconductor, is studied using self-consistent band structure techniques. Analysis of the transformation of the band structure for the hypothetical series…

Condensed Matter · Physics 2009-11-07 K. D. Belashchenko , M. van Schilfgaarde , V. P. Antropov

Alloying enables engineering of the electronic structure of semiconductors for optoelectronic applications. Due to their similar lattice parameters, the two-dimensional semiconducting transition metal dichalcogenides of the MoWSeS group…

We study the origin of layer dependence in band structures of two-dimensional materials. We find that the layer dependence, at the density functional theory (DFT) level, is a result of quantum confinement and the non-linearity of the…

Materials Science · Physics 2017-04-26 Mit H. Naik , Manish Jain

Transition metal dichalcogenides (TMD) are currently among the most interesting two-dimensional (2D) materials due to their outstanding properties. MoTe2 involves attractive polymorphic TMD crystals which can exist in three different 2D…

Computational Physics · Physics 2018-02-05 Bohayra Mortazavi , Golibjon R Berdiyorov , Meysam Makaremi , Timon Rabczuk

Transition metal dichalcogenides (TMDs) are a branch of two-dimensional materials which in addition to having an easy-to-exfoliate layered structure, also host semiconducting, metallic, superconducting, and topological properties in various…

Superconductivity · Physics 2023-01-25 Suvodeep Paul , Saswata Talukdar , Ravi Shankar Singh , Surajit Saha

We extend density matrix embedding theory to periodic systems, resulting in an electronic band structure method for solid-state materials. The electron correlation can be captured by means of a local impurity model using various choices of…

Strongly Correlated Electrons · Physics 2019-09-27 Hung Q. Pham , Matthew R. Hermes , Laura Gagliardi

Two-dimensional transition-metal dichalcogendes $MX_2$ (es. MoS$_2$, WS$_2$, MoSe$_2$, \ldots) are among the most promising materials for bandgap engineering. Widely studied in these compounds, by means of ab-initio techniques, is the…

Mesoscale and Nanoscale Physics · Physics 2019-01-25 L. Ortenzi , L. Pietronero , E. Cappelluti

We have investigated the surface and bulk electronic structures of the superconducting type-II Dirac semimetal 1T-PdSeTe. The superconducting transition temperature $T_C = 3.2$ K was almost twice as high as $T_C = 1.6$ K in 1T-PdTe$_2$.…

The combination of two-dimensional (2D) materials into vertical heterostructures has emerged as a promising path to designer quantum materials with exotic properties. Here, we extend this concept from inorganic 2D materials to 2D…