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We study thermoelectric properties of inhomogeneous nanogranular materials for weak tunneling conductance between the grains, g_t < 1. We calculate the thermopower and figure of merit taking into account the shift of the chemical potential…

Mesoscale and Nanoscale Physics · Physics 2009-10-16 A. Glatz , I. S. Beloborodov

Using first-principles approaches, this study investigated the efficiency of energy conversion in nanojunctions, described by the thermoelectric figure of merit $ZT$. We obtained the qualitative and quantitative descriptions for the…

Mesoscale and Nanoscale Physics · Physics 2011-06-09 Yu-Shen Liu , Yi-Ren Chen , Yu-Chang Chen

Nanostructuring has spurred a revival in the field of direct thermoelectric energy conversion. Nanograined materials can now be synthesized with higher figures of merit (ZT) than the bulk counterparts. This leads to increased conversion…

Materials Science · Physics 2024-01-25 Jesús Carrete , Natalio Mingo , Shidong Wang , Stefano Curtarolo

Several models of thermionic energy nanoconverters have been proposed to study the transport phenomena that take place in electronic devices. For example, in resonant tunneling junctions those phenomena are manifested through the…

Mesoscale and Nanoscale Physics · Physics 2020-06-02 G. Valencia-Ortega , L. A. Arias-Hernandez

Electrically connected and plasmonically enhanced molecular junctions combine the optical functionalities of high field confinement and enhancement (cavity function), and of high radiative efficiency (antenna function) with the electrical…

When biased at a voltage just below a superconductor's energy gap, a tunnel junction between this superconductor and a normal metal cools the latter. While the study of such devices has long been focussed to structures of submicron size and…

Mesoscale and Nanoscale Physics · Physics 2016-12-21 H Courtois , Hung Q. Nguyen , Clemens Winkelmann , J. P. Pekola

We predict an enormous order-dependent quantum enhancement of thermoelectric effects in the vicinity of a higher-order `supernode' in the transmission spectrum of a nanoscale junction. Single-molecule junctions based on 3,3'-biphenyl and…

Mesoscale and Nanoscale Physics · Physics 2011-08-04 J. P. Bergfield , M. Solis , C. A. Stafford

This mini review focuses on conductance measurements through molecular junctions containing few tens of molecules, which are fabricated along two approaches: (i) conducting atomic force microscope contacting a self-assembled monolayers on…

Applied Physics · Physics 2019-11-12 Dominique Vuillaume

A numerical study of thermoelectric nanocomposites is presented. Thermoelectric properties as a function of average grain size or nanoparticle density are examined by simulating the measurements as they would be done experimentally. In…

Materials Science · Physics 2020-01-08 Xufeng Wang , Mark Lundstrom

Within the framework of nonequilibrium Green's functions, we investigate the thermoelectric transport in a single molecular junction with electron-phonon and electron-electron interactions. By transforming into a displaced phonon basis, we…

Mesoscale and Nanoscale Physics · Physics 2012-04-26 Jie Ren , Jian-Xin Zhu , James E. Gubernatis , Chen Wang , Baowen Li

Single molecules are nanoscale thermodynamic systems with few degrees of freedom. Thus, the knowledge of their entropy can reveal the presence of microscopic electron transfer dynamics, that are difficult to observe otherwise. Here, we…

Mesoscale and Nanoscale Physics · Physics 2021-12-08 Eugenia Pyurbeeva , Chunwei Hsu , David Vogel , Christina Wegeberg , Marcel Mayor , Herre van der Zant , Jan A. Mol , Pascal Gehring

We propose here a feasible and effective design of new thermoelectric systems based on physical gaps in nanoscale junctions. We show that, depending on the type of features, i.e. the character of surface/edge states, on both sides of the…

Mesoscale and Nanoscale Physics · Physics 2023-01-18 Víctor M. García-Suárez

The field of thermoelectric materials has undergone a revolutionary transformation over the last couple of decades as a result of the ability to nanostructure and synthesize myriads of materials and their alloys. The ZT figure of merit,…

The thermoelectric properties of a molecular junction model, appropriate for large molecules such as fullerenes, are studied within a non-equilibrium adiabatic approach in the linear regime at room temperature. A self-consistent calculation…

Mesoscale and Nanoscale Physics · Physics 2014-09-26 C. A. Perroni , D. Ninno , V. Cataudella

We identify the operational conditions for maximum power of a nanothermoelectric engine consisting of a single quantum level embedded between two leads at different temperatures and chemical potentials. The corresponding thermodynamic…

Statistical Mechanics · Physics 2010-03-01 Massimiliano Esposito , Katja Lindenberg , Christian Van den Broeck

Coherent charge and heat transport through periodically driven nanodevices provide a platform for studying thermoelectric effects on the nanoscale. Here we study a junction comprising a quantum dot connected to two fermionic terminals by…

Mesoscale and Nanoscale Physics · Physics 2024-04-03 Debashree Chowdhury , O. Entin-Wohlman , A. Aharony

In this work we present a detailed study and derivation of the thermopower and thermoelectric coefficient of nano-granular metals at large tunneling conductance between the grains, g_T>> 1. An important criterion for the performance of a…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Andreas Glatz , I. S. Beloborodov

We report a method using scanning tunnelling microscope single molecular break junction to simultaneously measure and correlate the single-molecule thermopower and electrical conductance. In contrast to previously reported approaches, it…

Mesoscale and Nanoscale Physics · Physics 2021-09-24 Joseph M. Hamill , Christopher Weaver , Tim Albrecht

Thermoelectric properties of a nanocontact made of two capped single wall nanotubes (SWNT) are calculated within the tight-binding approximation and Green's function method. It is found that semiconducting nanotubes can have high Seebeck…

Materials Science · Physics 2007-05-23 Keivan Esfarjani , Mona Zebarjadi , Ali Shakouri , Yoshiyuki Kawazoe

The energetic positions of molecular electronic states at molecule/electrode interfaces are crucial factors for determining the transport and optoelectronic properties of molecular junctions. Strong light--matter coupling offers a potential…

Mesoscale and Nanoscale Physics · Physics 2023-05-10 Kuniyuki Miwa , Souichi Sakamoto , Akihito Ishizaki