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We propose a possible route to achieve high thermoelectric efficiency in molecular junctions by combining a local chemical tuning of the molecular electronic states with the use of semiconducting electrodes. The former allows to control the…

Materials Science · Physics 2009-08-05 D. Nozaki , H. Sevinçli , W. Li , R. Gutierrez , G. Cuniberti

Molecular junctions comprise small molecules on the order of one or a few nanometers in length, chemically attached to two electrodes of metal or semiconductors. They have recently been identified as promising candidates for…

Mesoscale and Nanoscale Physics · Physics 2021-11-12 Andrea Gemma , Bernd Gotsmann

The energy dependent thermoelectric response of a single molecule contains valuable information about its transmission function and its excited states. However, measuring it requires devices that can efficiently heat up one side of the…

Thermocurrent flowing through a single-molecule device contains valuable information about the quantum properties of the molecular structure and, in particular, on its electronic and phononic excitation spectra, and entropy. Furthermore,…

Mesoscale and Nanoscale Physics · Physics 2023-02-24 Serhii Volosheniuk , Damian Bouwmeester , Chunwei Hsu , H. S. J. van der Zant , Pascal Gehring

Recent developments in nanoscale experimental techniques made it possible to utilize single molecule junctions as devices for electronics and energy transfer with quantum coherence playing an important role in their thermoelectric…

Mesoscale and Nanoscale Physics · Physics 2018-03-12 Feng Chen , Yi Gao , Michael Galperin

We investigate the thermopower of a metal-molecule-metal junction taking into account thermal effects on the junction. Based on analytical expressions and numerical simulations we show that the thermoelectric potential reveals valuable…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Dvira Segal

Novel organic materials formed from functional molecules are attractive for various nanoelectronic applications because they are environmentally friendly, widely available and inexpensive. Recent advancement in bottom-up fabrication methods…

Mesoscale and Nanoscale Physics · Physics 2022-12-14 Abdalghani Daaoub , Renhang Wang , Ross Davidson , Sara Sangtarash , Hatef Sadeghi

Using first-principles approaches, we have investigated the thermoelectric properties and the energy conversion efficiency of the paired metal-Br-Al junction. Owing to the narrow states in the vicinity of the chemical potential, the…

Mesoscale and Nanoscale Physics · Physics 2011-01-21 Yu-Shen Liu , Hsuan-Te Yao , Yu-Chang Chen

Although it was demonstrated that discrete molecular levels determine the sign and magnitude of the thermoelectric effect in single-molecule junctions, full electrostatic control of these levels has not been achieved to date. Here, we show…

The energy efficiency and power of a three-terminal thermoelectric nanodevice are studied by considering elastic tunneling through a single quantum dot. Facilitated by the three-terminal geometry, the nanodevice is able to generate…

Mesoscale and Nanoscale Physics · Physics 2017-08-22 Jincheng Lu , Rongqian Wang , Yefeng Liu , Jian-Hua Jiang

We study the thermopower of a junction between a metal and a strongly correlated semiconductor. Both in the electronic ferroelectric regime and in the Kondo insulator regime the thermoelectric figures of merit, ZT, of these junctions are…

Strongly Correlated Electrons · Physics 2009-07-20 Massimo Rontani , L. J. Sham

Molecular junctions are a versatile test bed for investigating thermoelectricity on the nanoscale1-10 and contribute to the design of new cost-effective environmentally-friendly organic thermoelectric materials11. It has been suggested that…

Nanoscale conductors are interesting for thermoelectrics because of their particular spectral features connecting separated heat and particle currents. Multiterminal devices in the quantum regime benefit from phase-coherent phenomena, which…

Mesoscale and Nanoscale Physics · Physics 2026-02-23 José Balduque , Rafael Sánchez

Thermoelectric energy conversion is perhaps the most promising of the potential applications of molecular electronics. Ultimately, it is desirable for this technology to operate at around room temperature, and it is therefore important to…

Mesoscale and Nanoscale Physics · Physics 2020-06-30 Jakub K. Sowa , Jan A. Mol. Erik M. Gauger

We propose a thermoelectric cooling device based on an atomic-sized junction. Using first-principles approaches, we investigate the working conditions and the coefficient of performance (COP) of an atomic-scale electronic refrigerator where…

Mesoscale and Nanoscale Physics · Physics 2011-06-09 Yu-Shen Liu , Bailey C. Hsu , Yu-Chang Chen

We report here metal to insulator transition, colossal Seebeck coefficient and ultralow thermal conductivity (0.0057th of its bulk value, significantly smaller than many well-known thermoelectric materials and silicon, showing potential…

Materials Science · Physics 2020-01-28 Vikash Sharma , Gunadhor Singh Okram , Yung-Kang Kuo

Thermoelectric device is a promising next-generation energy solution owing to its capability to transform waste heat into useful electric energy, which can be realized in materials with high elec- tric conductivities and low thermal…

Materials Science · Physics 2018-07-10 Kisung Chae , Seoung-Hun Kang , Seon-Myeong Choi , Duck Young Kim , Young-Woo Son

We present a detailed study of the non-linear thermoelectric properties of a molecular junction, represented by a dissipative Anderson-Holstein model. A single orbital level with strong Coulomb interaction is coupled to a localized…

Mesoscale and Nanoscale Physics · Physics 2013-01-10 M. Leijnse , M. R. Wegewijs , K. Flensberg

Thermoelectric devices convert temperature gradients into electrical power and vice versa, thus enabling energy scavenging from waste heat, sensing and cooling. Yet, many of these attractive applications are hindered by the limited…

Materials Science · Physics 2019-02-14 Davide Donadio

Metal-string complexes in the quasi-1D framework may play an important role in molecular electronics by serving not only as nanoscale interconnects but also as active functional elements for nanoelectronic devices. However, because of the…

Mesoscale and Nanoscale Physics · Physics 2020-01-03 Talem Rebeda Roy , Arijit Sen
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