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The proton ordering model for the KH$_{2}$PO$_{4}$ type ferroelectrics is modified by taking into account non-linear effects, namely, the dependence of the effective dipole moments on the proton ordering parameter. Within the four-particle…

Materials Science · Physics 2014-05-07 A. S. Vdovych , A. P. Moina , R. R. Levitskii , I. R. Zachek

The proton ordering model for the KH$_{2}$PO$_{4}$ type ferroelectrics is modified by taking into account the dependence of the effective dipole moments on the proton ordering parameter. Within the four-particle cluster approximation we…

Materials Science · Physics 2015-02-10 A. S. Vdovych , A. P. Moina , R. R. Levitskii , I. R. Zachek

Within the four-particle cluster approximation for the proton ordering model we study the influence of shear stress $\sigma_6$ on the phase transition, static dielectric, elastic and thermal properties of deuterated KD2PO4 type…

Condensed Matter · Physics 2007-05-23 I. V. Stasyuk , R. R. Levitskii , I. R. Zachek , A. P. Moina , A. S. Duda

To investigate the caloric effects in the CsH$_2$PO$_4$ ferroelectric, a modified pseudospin model of this crystal is used, which takes into account the dependence of the parameters of interaction between pseudospins on lattice strains. The…

Materials Science · Physics 2023-01-05 A. S. Vdovych , R. R. Levitskii , I. R. Zachek

We present the results of the thermodynamic theory of piezoelectric ferroelectrics and of the phenomenological theory of thermodynamic characteristics of the KH$_{2}$PO$_{4}$ type ferroelectrics. Available experimental data for the…

Materials Science · Physics 2014-01-27 R. Levitskii , I. Zachek , L. Korotkov , D. Likhovaja , A. Vdovych , S. Sorokov , Z. Trybula , Sz. Los

We verify whether the previously developed model of a KD2PO4 crystal, with the shear strain eps6 taken into account, is able to describe the longitudinal electric field E3 influence on the KH2PO4 family ferroelectrics. Major effects of the…

Materials Science · Physics 2007-05-23 R. R. Levitskii , A. P. Moina , B. M. Lisnii

An atomistic effective Hamiltonian is used to compute electrocaloric (EC) effects in rare-earth substituted BiFeO$_{3}$ multiferroics. A phenomenological model is then developed to interpret these computations, with this model indicating…

We propose a two-sublattice proton ordering model for the quasione-dimensional CsH$_2$PO$_4$ ferroelectric with hydrogen bonds, which takes into account linear on lattice strains $u_1$, $u_2$, $u_3$ and $u_5$ contribution to the energy of…

Materials Science · Physics 2021-01-20 A. S. Vdovych , I. R. Zachek , R. R. Levitskii

The three primary ferroics, namely ferromagnets, ferroelectrics and ferroelastics exhibit corresponding large (or even giant) magnetocaloric,electrocaloric and elastocaloric effects when a phase transition is induced by the application of…

Materials Science · Physics 2012-05-08 Teresa Castan , Antoni Planes , Avadh Saxena

The multicaloric effect, which represents the reversible entropy change that occurs when both external magnetic and electric fields are applied, is an interesting phenomenon characteristic to multiferroics. Targeting the multicaloric effect…

In this letter, we report the structural, electronic and ferroelectric properties of the layered mixed-valent transition-metal compound, Sr$_{4}$Fe$_{6}$O$_{12}$ (SFO). We demonstrate how SFO undergoes a phase transition from a…

Strongly Correlated Electrons · Physics 2025-02-05 Arindam Sarkar , Hena Das , Prashant Singh , Aftab Alam

The origin of ferroelectricity in KH_2PO_4 (KDP) is studied by first-principles electronic structure calculations. In the low-temperature phase, the collective off-center ordering of the protons is accompanied by an electronic charge…

Materials Science · Physics 2007-05-23 S. Koval , J. Kohanoff , R. L. Migoni , A. Bussmann-Holder

The model of NH$_3$CH$_2$COOH$\cdot$H$_2$PO$_3$, modified by taking into account the piezoelectric coupling between the ordering structure elements and the strains $\varepsilon_i$, $\varepsilon_j$, is used for investigation of the effects…

Materials Science · Physics 2017-12-15 I. R. Zachek , R. R. Levitskii , A. S. Vdovych

Solid-state cooling presents an energy-efficient and environmentally friendly alternative to traditional refrigeration technologies that rely on thermodynamic cycles involving greenhouse gases. However, conventional caloric effects face…

Molecular dynamics simulations predict a giant electrocaloric effect at the ferroelectric-antiferroelectric phase boundary in PZT (PbTiO$_3$-PbZrO$_3$). These large-scale simulations also give insights into the atomistic mechanisms of the…

Materials Science · Physics 2019-07-24 A. V. Kimmel , O. T. Gindele , D. M. Duffy , R. E. Cohen

Within the framework of proton ordering model with taking into account the piezoelectric interaction with the shear strain $\varepsilon_6$, a dynamic dielectric response of KD2PO4 type ferroelectrics is considered. An expression for the…

Materials Science · Physics 2013-07-09 R. R. Levitskii , I. R. Zachek , A. P. Moina , A. S. Vdovych

The mechanocaloric effect is the temperature change of a material upon application or removal of an external stress. Beyond its fundamental interest, this caloric response represents a promising and ecofriendly alternative to current…

Materials Science · Physics 2021-12-01 Diana E. Murillo-Navarro , Mónica Graf , Jorge Íñiguez

We report an experimental demonstration of the magnetoelectrocaloric effect (MECE) in multiferroic $\mathrm{GdFeO_3}$. The temperature of the magnetic material changes when an external electric field is suddenly changed. MECE is the largest…

Strongly Correlated Electrons · Physics 2024-09-05 Rintaro Ikeda , Takashi Kurumaji , Yusuke Tokunaga , Taka-hisa Arima

We present calculations on the deformation of two- and three-layer electret systems. The electrical field is coupled with the stress-strain equations by means of the Maxwell stress tensor. In the simulations, two-phase systems are…

Materials Science · Physics 2007-05-23 Enis Tuncer , Michael Wegener , Reimund Gerhard-Multhaupt

Ferroelectric perovskite oxides possess a large electrocaloric (EC) effect, but usually at high temperatures near the ferroelectric/paraelectric phase transition temperature, which limits their potential application as next-generation…

Materials Science · Physics 2017-08-29 H. H. Wu , R. E. Cohen
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