English

Electric field induced phase transition and electrocaloric effect in PMN-PT

Materials Science 2017-08-29 v2

Abstract

Ferroelectric perovskite oxides possess a large electrocaloric (EC) effect, but usually at high temperatures near the ferroelectric/paraelectric phase transition temperature, which limits their potential application as next-generation solid-state cooling devices. We use classical molecular dynamics to study the electric field induced phase transitions and EC effect in PMN-PT (PbMg1/3Nb2/3O3-PbTiO3). We find that the maximum EC strength of PMN-PT occurs within the morphotropic phase boundary (MPB) region at 300 K. The large adiabatic temperature change is caused by easy rotation of polarization within the MPB region.

Keywords

Cite

@article{arxiv.1706.01034,
  title  = {Electric field induced phase transition and electrocaloric effect in PMN-PT},
  author = {H. H. Wu and R. E. Cohen},
  journal= {arXiv preprint arXiv:1706.01034},
  year   = {2017}
}

Comments

17 pages, 7 figures

R2 v1 2026-06-22T20:08:29.425Z