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The dynamical behavior of field-induced ferroelectric phase transitions in compositions of PbMg1/3Nb2/3O3(1-x)-PbTiO3(x) (PMN-PT) near the morphotropic phase boundary (MPB) was investigated using several electric-field application…

Materials Science · Physics 2026-04-07 Shivjeet Chanan , Joseph Kerchenfaut , Eduard Illin , Eugene V. Colla

Solid-state cooling presents an energy-efficient and environmentally friendly alternative to traditional refrigeration technologies that rely on thermodynamic cycles involving greenhouse gases. However, conventional caloric effects face…

The electrocaloric effect (ECE) offers a promising alternative to the traditional gas compressing refrigeration due to its high efficiency and environmental friendliness. The unusual negative electrocaloric effect refers to the adiabatic…

Materials Science · Physics 2023-07-14 Xingyue Ma , Mingxing Chen , Jun-Ming Liu , Di Wu , Yurong Yang

An atomistic effective Hamiltonian is used to investigate electrocaloric (EC) effects of Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ (PMN) relaxor ferroelectrics in its ergodic regime, and subject to electric fields applied along the pseudocubic [111]…

Materials Science · Physics 2018-04-03 Zhijun Jiang , Y. Nahas , S. Prokhorenko , S. Prosandeev , D. Wang , Jorge Íñiguez , L. Bellaiche

Using first-principles calculations, we estimated the impact of large applied electric E fields on the structural, dielectric, and ferroelectric properties of typical ferroelectrics. At large fields, the structural parameters change…

Materials Science · Physics 2016-05-25 Daniel I. Bilc , Liviu Zarbo , Sorina Garabagiu , Eric Bousquet , Liliana Mitoseriu

Structural phase transformations of [110] electric field cooled Pb(Mg1/3Nb2/3)O3-30%PbTiO3 (PMN-30%PT) crystals have been performed by x-ray diffraction in a field-cooled (FC) condition. A phase sequence of…

Materials Science · Physics 2009-11-11 Hu Cao , Feiming Bai , Naigang Wang , Jiefang Li , D. Viehland , Guangyong Xu , Gen Shirane

Single-crystalline ferroelectric (FE) perovskites show a large electrocaloric effect at electric field-induced phase transitions, promising for solid-state cooling technologies. However, paraelectric-FE transition temperatures are often too…

Materials Science · Physics 2024-10-03 Lan-Tien Hsu , Frank Wendler , Anna Grünebohm

Exchange bias (EB) phenomena have been observed in Nd2/3Ca1/3MnO3 colossal magnetoresistance perovskite below the Curie temperature $T_{C}$ = 70 K and attributed to an antiferromagnetic (AFM) - ferromagnetic (FM) spontaneous phase…

Mesoscale and Nanoscale Physics · Physics 2014-06-18 Elena Fertman , Sergiy Dolya , Vladimir Desnenko , Liudmia A. Pozhar , Marcela Kajnakova , Alexander Feher

A detailed study of the electric field gradient (EFG) across the Pr1-xCaxMnO3 phase diagram and its temperature dependence is given. Clearly, distinct EFG behaviours for samples outside/inside the charge order (CO) region are observed. The…

Strongly Correlated Electrons · Physics 2009-11-13 A. M. L. Lopes , J. P. Araujo , V. S. Amaral , J. G. Correia , Y. Tomioka , Y. Tokura

Molecular dynamics simulations predict a giant electrocaloric effect at the ferroelectric-antiferroelectric phase boundary in PZT (PbTiO$_3$-PbZrO$_3$). These large-scale simulations also give insights into the atomistic mechanisms of the…

Materials Science · Physics 2019-07-24 A. V. Kimmel , O. T. Gindele , D. M. Duffy , R. E. Cohen

An applied electric field can reversibly change the temperature of an electrocaloric material under adiabatic conditions, and the effect is strongest near phase transitions. This phenomenon has been largely ignored because only small…

Materials Science · Physics 2009-11-11 A. Mischenko , Q. Zhang , J. F. Scott , R. W. Whatmore , N. D. Mathur

Anomalous electrocaloric effect (ECE) with decreasing temperature upon application of an electric field is known to occur in antiferroelectrics (AFEs), and previous understanding refers to the field-induced canting of electric dipoles if…

Materials Science · Physics 2022-12-28 Ningbo Fan , Jorge Íñiguez , L. Bellaiche , Bin Xu

We report an isothermal electric field-induced first-order phase transition from Mott-insulator to the metallic state in the epitaxial thin film of V$_2$O$_3$ in the temperature regime below its Mott transition temperature $\approx$ 180 K.…

Strongly Correlated Electrons · Physics 2024-07-17 Binoy Krishna De , V. G. Sathe , S. B. Roy

Experimental data obtained with the perovskite compounds Pr$_{0.55}$Sr$_{0.45}$MnO$_{3}$ show that the magnetization decreases with increasing temperature $T$ and undergoes a very sharp phase transition to the paramagnetic phase. The sharp…

Materials Science · Physics 2024-01-12 Yethreb Essouda , Hung T. Diep , Mohamed Ellouze

Exchange bias (EB) refers to a shift of the hysteresis loop along the field axis in materials consisting of ferromagnetic (FM) and antiferromagnetic (AFM) layers, generally after a cooling procedure in high magnetic field. This effect is…

Strongly Correlated Electrons · Physics 2019-10-03 Lei Ding , Lihua Chu , Pascal Manuel , Fabio Orlandi , Meicheng Li , Yanjiao Guo , Zhuohai Liu

High-temperature (T) and high-electric-field (E) effects on Pb[(Zn_{1/3} Nb_{2/3})_{0.92} Ti_{0.08}]O_3 (PZN-8%PT) were studied comprehensively by neutron diffraction in the ranges 300 <= T <= 550 K and 0 <= E <= 15 kV/cm. We have focused…

Materials Science · Physics 2009-11-07 Kenji Ohwada , Kazuma Hirota , Paul W. Rehrig , Yasuhiko Fujii , Gen Shirane

Giant electrocaloric (EC) effect is observed in BaTiO3 multilayer thick film structure. The temperature change is as high as 4.0 oC under an applied electric field of 352 kV/cm. Most importantly, the EC effect is found to depend on the…

Materials Science · Physics 2015-05-18 Yang Bai , Guang-Ping Zheng , San-Qiang Shi

While it is well established that elevated temperatures can induce surface roughening of metal surfaces, the effect of a high electric field on the atomic structure at ambient temperature has not been investigated in detail. Here we show…

Experimental and theoretical studies of unusual polar, dielectric and magnetic properties of room temperature multiferroics, such as perovskites Pb(Fe$_{1/2}$Nb$_{1/2}$)O$_3$ (PFN) and Pb(Fe$_{1/2}$Ta$_{1/2}$)O$_3$ (PFT), are very…

In ferroelectric materials, an electric field has been shown to change the phonon dispersion sufficiently to alter the lattice thermal conductivity, opening the possibility that a heat gradient could drive a polarization flux, and…

Materials Science · Physics 2025-01-08 Delaram Rashadfar , Brandi L. Wooten , Joseph P. Heremans
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