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We investigated the behavior of lead titanate (PbTiO3) up to 100 GPa, both at room temperature and upon laser heating, using synchrotron X ray diffraction combined with density functional theory (DFT) computations. At the high pressure…

We present a Raman scattering study of Ca$_2$RuO$_4$, in which we investigate the temperature-dependence of the lattice dynamics and the electron-phonon interaction below the metal-insulator transition temperature ({\it T}$_{\rm MI}$).…

Strongly Correlated Electrons · Physics 2009-11-11 H. Rho , S. L. Cooper , S. Nakatsuji , H. Fukazawa , Y. Maeno

Strain is prominent in fabricated samples of two-dimensional semiconductors and it also serves as an exploitable tool for engineering their properties. However, quantifying strain and characterizing its spatially inhomogeneous distribution…

Materials Science · Physics 2014-09-01 Ruixiang Fei , Li Yang

Polarized Raman scattering measurements have been performed on Na0.5CoO2 single crystal from 8 to 305 K. Both the A1g and E1g phonon modes show a softening below Tc1 ~ 83 K. Additionally, the A1g phonon mode, which is forbidden in the…

Strongly Correlated Electrons · Physics 2008-02-07 Q. M. Zhang , M. an , S. K. Yuan , Y. Wu , D. Wu , J. L. Luo , N. L. Wang , W. Bao , Y. N. Wang

Nanostructured orthorhombic FeSb2 and an amorphous phase were formed by mechanical alloying starting from a mixture of high purity elemental Fe and Sb powders. The effects of high pressures on structural and optical properties were studied…

We have measured near normal incidence far infrared (FIR) reflectivity spectra of a single crystal of TbMnO3 from 10K to 300K in the spectral range of 50 cm$^{-1}$ to 700 cm$^{-1}$. Fifteen transverse optic (TO) and longitudinal optic (LO)…

Materials Science · Physics 2015-05-13 Pradeep Kumar , Surajit Saha , C. R. Serrao , A. K. Sood , C. N. R. Rao

Raman spectroscopy is a widely used experimental technique to study the vibrational properties of solids. Atomic scale simulations can be used to predict such spectra, but trustworthy studies at finite temperatures are challenging, mainly…

Materials Science · Physics 2025-09-03 Petter Rosander , Erik Fransson , Nicklas Österbacka , Paul Erhart , Göran Wahnström

We use Raman spectroscopy in tandem with transmission electron microscopy and DFT simulations to show that extreme (GPa) pressure converts the phase of silicon nanowires from cubic (Si-I) to hexagonal (Si-IV) while preserving the nanowire's…

Materials Science · Physics 2016-11-06 Bennett E. Smith , Xuezhe Zhou , Paden B. Roder , Evan H. Abramson , Peter J. Pauzauskie

A detailed high pressure study is carried out on 1T$^\prime$ MoTe$_{2}$ using X-ray diffraction(XRD) and Raman spectroscopy measurements upto about 30.5 GPa. High pressure XRD measurements show no structural transition. All the lattice…

Materials Science · Physics 2020-01-07 Bishnupada Ghosh , Pinku Saha , Goutam Dev Mukherjee

The exceptional ability of carbon to form sp2 and sp3 bonding states leads to a great structural and chemical diversity of carbon-bearing phases at non-ambient conditions. Here we use laser-heated diamond anvil cells combined with…

In this study, we performed comprehensive investigations on the Raman active phonon modes in cubic bixbyite In$_2$O$_3$, an important oxide based, wide-bandgap semiconductor. Fundamental insights into the lattice dynamics are revealed, by…

The temperature and pressure dependent electrical resistivity rho(T,P) studies have been performed on BaMn2As2 single crystal in the 4.2 to 300 K range upto of 8.2 GPa to investigate the evolution of its ground state properties. The rho(T)…

Strongly Correlated Electrons · Physics 2015-05-30 A. T. Satya , Awadhesh Mani , A. Arulraj , N. V. Chandra Shekar , K. Vinod , C. S. Sundar , A. Bharathi

Atomic layers of Black Phosphorus (BP) present unique opto-electronic properties dominated by a direct tunable bandgap in a wide spectral range from visible to mid-infrared. In this work, we investigate the infrared photoluminescence of BP…

Mesoscale and Nanoscale Physics · Physics 2021-01-13 Etienne Carré , Lorenzo Sponza , Alain Lusson , Ingrid Stenger , Etienne Gaufrès , Annick Loiseau , Julien Barjon

We present results of our study of polarized Raman scattering and infrared reflectivity of rhombohedral ceramic La_1-ySr_yMn_1-xM_xO_3 manganites in the temperature range between 77 and 320K. In our samples, a part of the Mn atoms is…

Strongly Correlated Electrons · Physics 2009-11-11 A. Dubroka , J. Humlicek , M. V. Abrashev , Z. V. Popovic , F. Sapina , A. Cantarero

We have studied single crystals of $C_{70}$ by Raman scattering and photoluminescence in the pressure range from 0 to 31.1 GPa. The Raman spectrum at 31.1 GPa shows only a broad band similar to that of the amorphous carbon without any trace…

Condensed Matter · Physics 2009-10-22 N. Chandrabhas , Ajay K. Sood , D. V. S. Muthu , C. S. Sundar , A. Bharathi , Y. Hariharan , C. N. R. Rao

The pressure dependence of the bulk modulus of glassy polystyrene (PS) was measured in the relatively high-pressure regime, up to 6 GPa, at ambient temperature. For the measurements, PS microbeads were immersed in a pressure medium…

Soft Condensed Matter · Physics 2025-07-09 Haruto Moriguchi , Ken Niwa , Masashi Hasegawa , Yusuke Koide , Takato Ishida , Takashi Uneyama , Yuichi Masubuchi

We report on the investigation of vibrational and electronic properties of the Pb doped dichalcogenide PbxTaSe2 using Raman scattering experiments. We observe a marked variation of the main vibrational modes with Pb concentration x. The…

Strongly Correlated Electrons · Physics 2022-06-08 Azat Sharafeev , Raman Sankar , Alexander Glamazda , Kwang-Yong Choi , Robert Bohle , Peter Lemmens , Fangcheng Chou

We calculate the parallel (VV) and perpendicular (VH) polarized Raman spectra of amorphous silica. Model SiO2 glasses, uncompressed and compressed, were generated by a combination of classical and ab initio molecular-dynamics simulations…

Disordered Systems and Neural Networks · Physics 2009-11-10 Abdelali Rahmani , Magali Benoit , Claude Benoit

Boron is an element of fascinating chemical complexity. Controversies have shrouded this element since its discovery was announced in 1808: the new 'element' turned out to be a compound containing less than 60-70 percent of boron, and it…

We show the evolution of Raman spectra with number of graphene layers on different substrates, SiO$_{2}$/Si and conducting indium tin oxide (ITO) plate. The G mode peak position and the intensity ratio of G and 2D bands depend on the…

Materials Science · Physics 2007-10-24 Anindya Das , Biswanath Chakraborty , A. K. Sood
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