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Bloch-Boltzmann transport theory fails to describe the carrier diffusion in current crystalline organic semiconductors, where the presence of large-amplitude thermal molecular motions causes substantial dynamical disorder. The charge…

Materials Science · Physics 2020-01-08 S. Fratini , S. Ciuchi

We analyze a model that accounts for the inherently large thermal lattice fluctuations associated to the weak van der Waals inter-molecular bonding in crystalline organic semiconductors. In these materials the charge mobility generally…

Materials Science · Physics 2010-01-08 S. Fratini , S. Ciuchi

We explore the charge transport mechanism in organic semiconductors based on a model that accounts for the thermal intermolecular disorder at work in pure crystalline compounds, as well as extrinsic sources of disorder that are present in…

Materials Science · Physics 2012-12-10 S. Ciuchi , S. Fratini

We provide a phenomenological formula which describes the low-frequency optical absorption of charge carriers in disordered systems with localization. This allows to extract, from experimental data on the optical conductivity, the relevant…

Materials Science · Physics 2015-06-19 Simone Fratini , Sergio Ciuchi , Didier Mayou

Charge transport in organic semiconductors is notoriously extremely sensitive to the presence of disorder, both internal and external (i.e. related to the interactions with the dielectric layer), especially for n-type materials. Internal…

Charge transport in organic semiconductors is notoriously extremely sensitive to the presence of disorder, both intrinsic and extrinsic, especially for n-type materials. Intrinsic dynamic disorder stems from large thermal fluctuations both…

We have investigated the charge carrier transport in organic molecular semiconductors. It has been found that mobility is a function of electric field and temperature due to hopping conduction. Several theoretical models for charge…

Materials Science · Physics 2007-05-23 Ajit Kumar Mahapatro , Subhasis Ghosh

Thermoelectric materials convert a temperature gradient into a voltage. This phenomenon is relatively well understood for inorganic materials, but much less so for organic semiconductors (OSs). These materials present a challenge because…

The present paper gives an elaborate theoretical description of a new molecular charge transport mechanism applying to a single molecule trapped between two macroscopic electrodes in a solid state device. It is shown by a Hubbard type model…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Per Hedegard , Thomas Bjornholm

We use first-principle Quantum Monte-Carlo (QMC) simulations and numerical exact diagonalization to analyze the low-frequency charge carrier mobility within a simple tight-binding model of molecular organic semiconductors on a…

Materials Science · Physics 2025-07-23 Pavel Buividovich , Johann Ostmeyer , Alessandro Troisi

One of the basic assumptions in organic field-effect transistors, the most fundamental device unit in organic electronics, is that charge transport occurs two-dimensionally in the first few molecular layers near the dielectric interface.…

Mesoscale and Nanoscale Physics · Physics 2016-01-11 Yuhan Zhang , Jingsi Qiao , Si Gao , Fengrui Hu , Daowei He , Bing Wu , Ziyi Yang , Bingchen Xu , Yun Li , Yi Shi , Wei Ji , Peng Wang , Xiaoyong Wang , Min Xiao , Hangxun Xu , Jian-Bin Xu , Xinran Wang

A relation derived from the Kubo formula shows that optical conductivity measurements below the gap frequency in doped semiconductors can be used to probe directly the time-dependent quantum dynamics of charge carriers. This allows to…

Materials Science · Physics 2015-03-17 S. Ciuchi , S. Fratini , D. Mayou

We present a model of charge transport in organic molecular semiconductors based on the effects of lattice fluctuations on the quantum coherence of the electronic state of the charge carrier. Thermal intermolecular phonons and librations…

Other Condensed Matter · Physics 2009-11-11 J. -D. Picon , M. N. Bussac , L. Zuppiroli

Transport of charge carriers in mechanically soft semiconductors is mainly limited by their interaction with slow intermolecular phonons. Carrier motion exhibits a crossover from superdiffusive to subdiffusive, producing a distinct…

Strongly Correlated Electrons · Physics 2025-07-08 Veljko Janković

We carefully revisit the electron-boson scattering problem, going beyond popular semi-classical treatments. By providing numerically exact results valid at finite temperatures, we demonstrate the existence of a regime of electron-boson…

Strongly Correlated Electrons · Physics 2025-08-26 H. Rammal , A. Ralko , S. Ciuchi , S. Fratini

The nonlocal electron-phonon couplings in organic semiconductors responsible for the fluctuation of intermolecular transfer integrals has been the center of interest recently. Several irreconcilable scenarios coexist for the description of…

Materials Science · Physics 2021-08-04 Weitang Li , Jiajun Ren , Zhigang Shuai

General properties of the transport of charge carriers (electrons and holes) in disordered organic materials are discussed. It was demonstrated that the dominant part of the total energetic disorder in organic material is usually provided…

Materials Science · Physics 2013-03-20 S. V. Novikov

Organic semiconductors are indispensable for today's display technologies in form of organic light emitting diodes (OLEDs) and further optoelectronic applications. However, organic materials do not reach the same charge carrier mobility as…

Soft Condensed Matter · Physics 2023-10-12 Patrick Reiser , Manuel Konrad , Artem Fediai , Salvador Léon , Wolfgang Wenzel , Pascal Friederich

Two-dimensional (2D) van der Waals semiconductors represent the thinnest, air stable semiconducting materials known. Their unique optical, electronic and mechanical properties hold great potential for harnessing them as key components in…

Mesoscale and Nanoscale Physics · Physics 2016-02-10 Song-Lin Li , Kazihito Tsukagoshi , Emanuele Orgiu , Paolo Samorì

There is compelling evidence that charge carriers in organic semiconductors (OSs) self-localize in nano-scale space because of dynamic disorder. Yet, some OSs, in particular recently emerged high-mobility organic molecular crystals, feature…

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