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It is known that the equilibrium properties of open classical systems that are strongly coupled to a heat bath are described by a set of thermodynamic potentials related to the system's Hamiltonian of mean force. By adapting this framework…

Statistical Mechanics · Physics 2017-06-28 Harry J. D. Miller , Janet Anders

Statistical formulations of thermodynamic entropy, such as those by Boltzmann and Gibbs, were originally developed for classical systems and are well understood in that context. However, the foundational aspects of quantum statistical…

Quantum Physics · Physics 2025-10-08 Smitarani Mishra , Shaon Sahoo

An operator equality on the entropy production for general quantum Markovian master equations is derived without resorting quantum stochastic trajectory and priori quantum definition of entropy production. We find that, the equality can be…

Statistical Mechanics · Physics 2012-10-23 Fei Liu

A novel formalism, called H-theory, is applied to the problem of statistical equilibrium of a hierarchical complex system with multiple time and length scales. In this approach, the system is formally treated as being composed of a small…

Statistical Mechanics · Physics 2019-05-06 Giovani L. Vasconcelos , Domingos S. P. Salazar , A. M. S. Macêdo

The maximum entropy principle from statistical mechanics states that a closed system attains an equilibrium distribution that maximizes its entropy. We first show that for graphs with fixed number of edges one can define a stochastic edge…

Disordered Systems and Neural Networks · Physics 2007-05-23 Jesse S. A. Bridgewater , P. Oscar Boykin , Vwani P. Roychowdhury

The thermal-equilibrium canonical distribution is currently obtained by maximizing the Boltzmann-Gibbs-von Neumann-Shannon entropy $S_{BG}(p)=k\sum^{W}_{i=1}p_{i}\ln 1/p_{i}$ constrained to $\sum^{W}_{i=1}p_{i}=1$ and…

Statistical Mechanics · Physics 2026-05-12 Leandro Lyra Braga Dognini , Constantino Tsallis

Applying the theory of self-adjoint extensions of Hermitian operators to Koopman von Neumann classical mechanics, the most general set of probability distributions is found for which entropy is conserved by Hamiltonian evolution. A new…

Statistical Mechanics · Physics 2019-06-24 Gerard McCaul , Alexander Pechen , Denys I. Bondar

We propose an extension of the principle of virtual work of mechanics to random dynamics of mechanical systems. The total virtual work of the interacting forces and inertial forces on every particle of the system is calculated by…

Statistical Mechanics · Physics 2008-01-28 Qiuping A. Wang

The positivity conditions of the relative entropy between two thermal equilibrium states $\hat{\rho}_1$ and $\hat{\rho}_2$ are used to obtain upper and lower bounds for the subtraction of their entropies, the Helmholtz potential and the…

The performance of endoreversible thermal machines operating at finite power constitutes one of the main challenges of nonequilibrium classical and quantum thermodynamics, engineering and others. We introduce the idea of adjusting the…

Statistical Mechanics · Physics 2021-06-16 Pedro E. Harunari , Fernando S. Filho , Carlos E. Fiore , Alexandre Rosas

Stochastic thermodynamics is the field of study relating fluctuations in stochastic systems to thermodynamic quantities. The total entropy production (EP), is central to the thermodynamic classification of systems. Non-equilibrium systems…

Statistical Mechanics · Physics 2025-08-05 Lars Torbjørn Stutzer

We investigate the existence of solutions of reversible and irreversible port-Hamiltonian systems. To this end, we utilize the associated exergy, a function that is composed of the system's Hamiltonian and entropy, to prove global existence…

Optimization and Control · Mathematics 2024-10-25 Willem Esterhuizen , Bernhard Maschke , Till Preuster , Manuel Schaller , Karl Worthmann

The maximum entropy principle (MEP) apparently allows us to derive, or justify, fundamental results of equilibrium statistical mechanics. Because of this, a school of thought considers the MEP as a powerful and elegant way to make…

Statistical Mechanics · Physics 2015-12-09 Gennaro Auletta , Lamberto Rondoni , Angelo Vulpiani

In this article we want to demonstrate that the time-scale constraints for a thermodynamic system imply the new concept of {\it equipartition of energy bound} (EEB) or, more generally, a thermodynamical bound for the {\it partition} of…

General Physics · Physics 2015-10-14 Nicolo' Masi

In the real world, one almost never knows the parameters of a thermodynamic process to infinite precision. Reflecting this, here we investigate how to extend stochastic thermodynamics to systems with uncertain parameters, including…

Statistical Mechanics · Physics 2021-03-17 Jan Korbel , David H. Wolpert

The infinitesimal transition probability operator for a continuous-time discrete-state Markov process, $\mathcal{Q}$, can be decomposed into a symmetric and a skew-symmetric parts. As recently shown for the case of diffusion processes,…

Mathematical Physics · Physics 2013-04-09 Hong Qian

This survey has been written in occasion of the School and Workshop about Optimal Transport on Quantum Structures at Erd\"os Center in September 2022. We discuss some recent results on noncommutative entropic optimal transport problems and…

Mathematical Physics · Physics 2023-10-17 Lorenzo Portinale

In this theoretical study, we determine the maximum amount of work extractable in finite time by a demon performing continuous measurements on a quadratic Hamiltonian system subjected to thermal fluctuations, in terms of the information…

Statistical Mechanics · Physics 2014-10-21 Henrik Sandberg , Jean-Charles Delvenne , Nigel J. Newton , Sanjoy K. Mitter

In the paradigm of thermodynamic computing, instead of behaving deterministically, hardware undergoes a stochastic process in order to sample from a distribution of interest. While it has been hypothesized that thermodynamic computers may…

We compute statistical properties of the stochastic entropy production associated with the nonstationary transport of heat through a system coupled to a time dependent nonisothermal heat bath. We study the 1-d stochastic evolution of a…

Statistical Mechanics · Physics 2015-10-14 Ian J. Ford , Zachary P. L. Laker , Henry J. Charlesworth