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The selection of an equilibrium state by maximising the entropy of a system, subject to certain constraints, is often powerfully motivated as an exercise in logical inference, a procedure where conclusions are reached on the basis of…

Statistical Mechanics · Physics 2015-12-03 Ian J. Ford

The optimal efficiency of quantum (or classical) heat engines whose heat baths are $n$-particle systems is given by the information geometry and the strong large deviation. We give the optimal work extraction process as a concrete…

Quantum Physics · Physics 2017-07-19 Hiroyasu Tajima , Masahito Hayashi

In a macroscopic (quantum or classical) Hamiltonian system, we prove the second law of thermodynamics in the forms of the minimum work principle and the law of entropy increase, under the assumption that the initial state is described by a…

Statistical Mechanics · Physics 2007-05-23 Hal Tasaki

Constraints on work extraction are fundamental to our operational understanding of the thermodynamics of both classical and quantum systems. In the quantum setting, finite-time control operations typically generate coherence in the…

The efficiency of microscopic heat engines in a thermally heterogenous environment is considered. We show that, as a consequence of the recently discovered entropic anomaly, quasi-static engines, whose efficiency is maximal in a fluid at…

Statistical Mechanics · Physics 2015-06-12 Stefano Bo , Antonio Celani

Extracting useful work from quantum systems is a fundamental problem in quantum thermodynamics. In scenarios where rapid protocols are desired -- whether due to practical constraints or deliberate design choices -- a fundamental trade-off…

Quantum Physics · Physics 2026-04-23 Shoki Sugimoto , Takahiro Sagawa , Ryusuke Hamazaki

Progress in miniaturized technology allows us to control physical systems at nanoscale with remarkable precision. Experimental advancements have sparked interest in control problems in stochastic thermodynamics, typically concerning a…

Statistical Mechanics · Physics 2025-03-26 Julia Sanders , Marco Baldovin , Paolo Muratore-Ginanneschi

We consider the problem of minimizing the entropy, energy, or exergy production for state transitions of irreversible port-Hamiltonian systems subject to control constraints. Via a dissipativity-based analysis we show that optimal solutions…

Optimization and Control · Mathematics 2022-02-21 Bernhard Maschke , Friedrich Philipp , Manuel Schaller , Karl Worthmann , Timm Faulwasser

The nonequilibrium thermodynamics feature of a Brownian motor is investigated by obtaining exact time-dependent solutions. This in turn enables us to investigate not only the long time property (steady-state) but also the short time the…

Statistical Mechanics · Physics 2022-05-23 Mesfin Taye

We consider the problem of finding the energy minimum of a complex quantum Hamiltonian by employing a non-Markovian bath prepared in a low energy state. The energy minimization problem is thus turned into a thermodynamic cooling protocol in…

Quantum Physics · Physics 2024-03-29 Alberto Imparato , Nicholas Chancellor , Gabriele De Chiara

We apply Pontryagin's principle to drive rapidly a trapped overdamped Brownian particle in contact with a thermal bath between two equilibrium states corresponding to different trap stiffness $\kappa$. We work out the optimal time…

Statistical Mechanics · Physics 2019-01-30 Carlos A. Plata , David Guéry-Odelin , E. Trizac , A. Prados

A Hamiltonian-based model of many harmonically interacting massive particles that are subject to linear friction and coupled to heat baths at different temperatures is used to study the dynamic approach to equilibrium and non-equilibrium…

Statistical Mechanics · Physics 2020-09-17 Roland R. Netz

For a small system like a colloidal particle or a single biomolecule embedded in a heat bath, the optimal protocol of an external control parameter minimizes the mean work required to drive the system from one given equilibrium state to…

Statistical Mechanics · Physics 2009-11-13 Tim Schmiedl , Udo Seifert

A quantum statistical expression for the entropy of a nonequilibrium system is defined so as to be consistent with Gibbs' relation, and is shown to corresponds to dynamical variable by introducing analogous to the Heisenberg picture in…

Statistical Mechanics · Physics 2013-05-29 Hiroki Majima , Akira Suzuki

We derive universal thermodynamic inequalities that bound from below the moments of first-passage times of stochastic currents in nonequilibrium stationary states of Markov jump processes in the limit where the thresholds that define the…

Statistical Mechanics · Physics 2025-02-03 Izaak Neri

In the previous papers (Kui\'{c} et al. in Found Phys 42:319-339, 2012; Kui\'{c} in arXiv:1506.02622, 2015), it was demonstrated that applying the principle of maximum information entropy by maximizing the conditional information entropy,…

Statistical Mechanics · Physics 2016-06-14 Domagoj Kuic

We derive the optimal estimates of the free energies of an arbitrary number of thermodynamic states from nonequilibrium work measurements; the work data are collected from forward and reverse switching processes and obey a fluctuation…

Statistical Mechanics · Physics 2009-11-11 Paul Maragakis , Martin Spichty , Martin Karplus

We consider an isolated system in an arbitrary state and provide a general formulation using first principles for an additive and non-negative statistical quantity that is shown to reproduce the equilibrium thermodynamic entropy of the…

Chemical Physics · Physics 2013-04-18 P. D. Gujrati

For systems in an externally controllable time-dependent potential, the optimal protocol minimizes the mean work spent in a finite-time transition between given initial and final values of a control parameter. For an initially thermalized…

Statistical Mechanics · Physics 2015-05-13 Tim Schmiedl , Eckhard Dieterich , Peter-Simon Dieterich , Udo Seifert

Entropy production plays a fundamental role in nonequilibrium thermodynamics to quantify the irreversibility of open systems. Its positivity can be ensured for a wide class of setups, but the entropy production rate can become negative…

Statistical Mechanics · Physics 2019-01-23 Philipp Strasberg , Massimiliano Esposito