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After the justification of the maximum entropy approach for equilibrium thermodynamic system, and of a maximum path entropy algorithm for nonequilibrium thermodynamic systems by virtue of the principle of virtual work, we present in this…

Statistical Mechanics · Physics 2007-12-18 Qiuping A. Wang

Entropy in nonequilibrium statistical mechanics is investigated theoretically so as to extend the well-established equilibrium framework to open nonequilibrium systems. We first derive a microscopic expression of nonequilibrium entropy for…

Statistical Mechanics · Physics 2007-06-13 Takafumi Kita

It is possible to extract work from a quantum-mechanical system whose dynamics is governed by a time-dependent cyclic Hamiltonian. An energy bath is required to operate such a quantum engine in place of the heat bath used to run a…

Quantum Physics · Physics 2009-11-07 C. M. Bender , D. C. Brody , B. K. Meister

We present a scheme to evaluate thermodynamic variables for a system coupled to a heat bath under a time-dependent external force using the quasi-static Helmholtz energy from the numerically "exact" hierarchical equations of motion (HEOM).…

Statistical Mechanics · Physics 2020-12-18 Souichi Sakamoto , Yoshitaka Tanimura

For systems in an externally controllable time-dependent potential, the optimal protocol minimizes the mean work spent in a finite-time transition between two given equilibrium states. For overdamped dynamics which ignores inertia effects,…

Statistical Mechanics · Physics 2008-07-23 Alex Gomez-Marin , Tim Schmiedl , Udo Seifert

The complete physical understanding of the optimization of the thermodynamic work still is an important open problem in stochastic thermodynamics. We address this issue using the Hamiltonian approach of linear response theory in finite time…

Statistical Mechanics · Physics 2022-08-18 Pierre Nazé , Sebastian Deffner , Marcus V. S. Bonança

We propose a new form of the Second Law inequality that defines a tight bound for extractable work from the non-equilibrium quantum state. In classical thermodynamics, the optimal work is given by the difference of free energy, what…

Quantum Physics · Physics 2023-02-14 Marcin Łobejko

We derive universal bounds for the finite-time survival probability of the stochastic work extracted in steady-state heat engines and the stochastic heat dissipated to the environment. We also find estimates for the time-dependent…

Statistical Mechanics · Physics 2022-02-23 Gonzalo Manzano , Édgar Roldán

Physical systems driven away from equilibrium by an external controller dissipate heat to the environment; the excess entropy production in the thermal reservoir can be interpreted as a "cost" to transform the system in a finite time. The…

Statistical Mechanics · Physics 2024-12-31 Jérémie Klinger , Grant M. Rotskoff

The second law of thermodynamics sets a lower bound on the work required to drive a system between thermal equilibrium states, with equality attained in the quasistatic limit. For finite-time processes, part of the extractable work is…

Quantum Physics · Physics 2025-11-20 Masaaki Tokieda

We consider irreversible and coupled reversible-irreversible nonlinear port-Hamiltonian systems and the respective sets of thermodynamic equilibria. In particular, we are concerned with optimal state transitions and output stabilization on…

Optimization and Control · Mathematics 2024-10-08 Friedrich Philipp , Manuel Schaller , Karl Worthmann , Timm Faulwasser , Bernhard Maschke

The paradigm of extracting work from isolated quantum system through a cyclic Hamiltonian process is a topic of immense research interest. The optimal work extracted under such process is termed as ergotropy [Europhys. Lett., 67 (4),…

Quantum Physics · Physics 2016-06-08 Amit Mukherjee , Arup Roy , Some Sankar Bhattacharya , Manik Banik

Thermodynamics teaches that if a system initially off-equilibrium is coupled to work sources, the maximum work that it may yield is governed by its energy and entropy. For finite systems this bound is usually not reachable. The maximum…

Statistical Mechanics · Physics 2009-11-10 A. E. Allahverdyan , R. Balian , Th. M. Nieuwenhuizen

Work fluctuation and total entropy production play crucial roles in small thermodynamic systems subject to large thermal fluctuations. We investigate a trade-off relation between them in a nonequilibrium situation in which a system starts…

Statistical Mechanics · Physics 2016-12-15 Ken Funo , Tomohiro Shitara , Masahito Ueda

This work presents a general unifying theoretical framework for quantum non-equilibrium systems. It is based on a re-statement of the dynamical problem as one of inferring the distribution of collision events that move a system toward…

Quantum Physics · Physics 2015-03-30 David M. Rogers

We consider optimization of the average entropy production in inhomogeneous temperature environments within the framework of stochastic thermodynamics. For systems modeled by Langevin equations (e.g. a colloidal particle in a heat bath) it…

Statistical Mechanics · Physics 2013-03-14 Stefano Bo , Erik Aurell , Ralf Eichhorn , Antonio Celani

The work content of non-equilibrium systems in relation to a heat bath is often analyzed in terms of expectation values of an underlying random work variable. However, we show that when optimizing the expectation value of the extracted…

Quantum Physics · Physics 2015-03-19 Johan Aberg

Optimal (reversible) processes in thermodynamics can be modelled as step-by-step processes, where the system is successively thermalized with respect to different Hamiltonians by an external thermal bath. However, in practice interactions…

We introduce the Markovian matrix product density operator, which is a special subclass of the matrix product density operator. We show that the von Neumann entropy of such ansatz can be computed efficiently on a classical computer. This is…

Quantum Physics · Physics 2017-09-28 Isaac H. Kim

We consider overdamped physical systems evolving under a feedback-controlled fluctuating potential and in contact with a thermal bath at temperature $T$. A Markovian description of the dynamics, which keeps only the last value of the…

Statistical Mechanics · Physics 2026-02-12 Natalia Ruiz-Pino , Antonio Prados
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