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High-performance infrared photodetection underpins various applications spanning surveillance, environmental monitoring, optical communications and biomedical imaging. However, conventional bulk detectors remain limited by poor spectral…

Few-layer black phosphorus (BP), also known as phosphorene, is poised to be the most attractive graphene analogue owing to its high mobility approaching that of graphene, and its thickness- tunable band gap that can be as large as that of…

Materials Science · Physics 2015-03-13 Joon-Seok Kim , Yingnan Liu , Weinan Zhu , Seohee Kim , Di Wu , Li Tao , Ananth Dodabalapur , Keji Lai , Deji Akinwande

Black Phosphorus (BP) is unique among layered materials owing to its homonuclear lattice and strong structural anisotropy. While recent investigations on few layers BP have extensively explored the in-plane (a,c) anisotropy, much less…

Black phosphorus (BP) has recently emerged as an alternative 2D semiconductor owing to its fascinating electronic properties such as tunable bandgap and high charge carrier mobility. The structural investigation of few-layer BP, such as…

Mesoscale and Nanoscale Physics · Physics 2017-02-01 Yangjin Lee , Jun-Yeong Yoon , Declan Scullion , Jeongsu Jang , Elton J G Santos , Hu Young Jeong , Kwanpyo Kim

Black phosphorus is a very promising material for telecommunication due to its direct bandgap and strong resonant absorption in near-infrared wavelength range. However, ultrafast nonlinear photonic applications relying on the ultrafast…

Twisted stacked few layer black phosphorus heterostructures were successfully fabricated in this work. Abnormal blue shifts in their Ag1 and Ag2 Raman peaks and unique optical reflections were observed in these samples. The phonon behavior…

Materials Science · Physics 2018-05-04 Tao Fang , Teren Liu , Zenan Jiang , Rui Yang , Peyman Servati , Guangrui , Xia

Two-dimensional (2D) layered materials with diverse properties have attracted significant interest in the past decade. The layered materials discovered so far have covered a wide, yet discontinuous electromagnetic spectral range from…

We investigate the impact of the encapsulation with hexagonal boron nitride (h-BN) on the Raman spectrum of few layer black phosphorus. The encapsulation results in a significant reduction of the line width of the Raman modes of black…

Mesoscale and Nanoscale Physics · Physics 2017-11-23 J. M. Urban , M. Baranowski , A. Surrente , D. Wlodarczyk , A. Suchocki , G. Long , Y. Wang , L. Klopotowski , N. Wang , D. K. Maude , P. Plochocka

Research on black phosphorus (BP) has been experiencing a renaissance over the last few years, after the demonstration that few-layer BP exhibits high carrier mobility and a thickness-dependent band gap. For a long time, bulk BP is also…

Materials Science · Physics 2017-05-02 Renyan Zhang , John Waters , Andre K. Geim , Irina V. Grigorieva

The interlayer breathing and shear modes in few-layer black phosphorus are investigated for their symmetry and lattice dynamical properties. The symmetry groups for the even-layer and odd-layer few-layer black phosphorus are utilized to…

Materials Science · Physics 2014-12-25 Jin-Wu Jiang , Bing-Shen Wang , Harold S. Park

Black phosphorus (BP) as a promising two-dimensional material with extraordinary optical properties constitutes an excellent building block in multilayer hyperbolic metamaterials. In this work, we design a multilayer structure composed of…

Optics · Physics 2019-11-05 Shuyuan Xiao , Tingting Liu , Le Cheng , Chaobiao Zhou , Xiaoyun Jiang , Zhong Li , Chen Xu

We report high pressure Raman experiments of Black phosphorus up to 24 GPa. The line widths of first order Raman modes A$^1_g$, B$_{2g}$ and A$^2_g$ of the orthorhombic phase show a minimum at 1.1 GPa. Our first-principles density…

Strongly Correlated Electrons · Physics 2017-09-20 Satyendra Nath Gupta , Anjali Singh , Koushik Pal , Biswanath Chakraborti , D. V. S. Muthu , U V Waghmare , A. K. Sood

Tuning band gaps in two-dimensional (2D) materials is of great interest in the fundamental and practical aspects of contemporary material sciences. Recently, black phosphorus (BP) consisting of stacked layers of phosphorene was…

Materials Science · Physics 2017-09-13 Sun-Woo Kim , Hyun Jung , Hyun-Jung Kim , Jin-Ho Choi , Su-Huai Wei , Jun-Hyung Cho

Black phosphorous (BP), a two-dimensional (2D) material, has a direct bandgap, which fills up the bandgap lacuna left by graphene topological insulators and transition-metal dichalcogenides because of its dependence on the layers and…

Materials Science · Physics 2015-05-25 Rui Zhang , Yuxia Zhang , Haohai Yu , Huaijin Zhang , Ruinong Yang , Bingchao Yang , Zhongyuan Liu , Jiyang Wang

Hybrid materials, containing a 2D filler embedded in a polymeric matrix, are an interesting platform for several applications, because of the variety of properties that the filler can impart to the polymer matrix when dispersed at the…

Two-dimensional materials supporting deep-subwavelength plasmonic modes can also exhibit strong magneto-optical responses. Here, we theoretically investigate magnetoplasmons (MPs) in monolayer black phosphorus (BP) structures under moderate…

The attraction between electrons and holes in semiconductors forms excitons, which largely determine the optical properties of the hosting material, and hence the device performance, especially for low-dimensional systems. Mono- and…

Mesoscale and Nanoscale Physics · Physics 2018-03-20 Guowei Zhang , Andrey Chaves , Shenyang Huang , Fanjie Wang , Qiaoxia Xing , Tony Low , Hugen Yan

The discovery of graphene triggered a rapid rise of unexplored two-dimensional materials and heterostructures having optoelectronic and photonics properties that can be tailored on the nanoscale. Among these materials, black phosphorus (BP)…

Applied Physics · Physics 2019-03-18 Leonardo Viti , Antonio Politano , Miriam Serena Vitiello

Preceding the current interest in layered materials for electronic applications, research in the 1960's found that black phosphorus combines high carrier mobility with a fundamental band gap. We introduce its counterpart, dubbed few-layer…

Mesoscale and Nanoscale Physics · Physics 2014-04-25 Han Liu , Adam T. Neal , Zhen Zhu , David Tomanek , Peide D. Ye

Raman spectroscopy is the prime non-destructive characterization tool for graphene and related layered materials. The shear (C) and layer breathing modes (LBMs) are due to relative motions of the planes, either perpendicular or parallel to…