Related papers: Hybridization of Rydberg electron orbitals by mole…
Rydberg atoms represent a platform underpinning many recent developments in quantum computation, simulation, sensing, and metrology. They further facilitate optical nonlinearity at the single-photon level when coupled to photons propagating…
Interaction between Rydberg atoms can significantly modify Rydberg excitation dynamics. Under a resonant driving field the Rydberg-Rydberg interaction in high-lying states can induce shifts in the atomic resonance such that a secondary…
Cold atomic gases resonantly excited to Rydberg states can exhibit strong optical nonlinearity at the single photon level. We observe that in such samples radiation trapping leads to an additional mechanism for Rydberg excitation.…
Molecular bonds can be divided into four primary types: ionic, covalent, van der Waals and hydrogen bonds. At ultralow temperatures a novel binding type emerges paving the way for novel molecules and ultracold chemistry [1,2]. The…
We report on our recent progress on the manipulation of single rubidium atoms trapped in optical tweezers and the generation of entanglement between two atoms, each individually trapped in neighboring tweezers. To create an entangled state…
We propose a scheme to realize a heavy Rydberg system (HRS), a bound pair of oppositely charged ions, from a gas of ultracold atoms. The intermediate step to achieve large internuclear separations is the creation of a unique class of…
We propose a new approach to excite ion-pair states of ultracold dimers. The central idea is a two-step process where first long-range Rydberg molecules are formed by photoassociation, which are then driven by stimulated emission towards…
We theoretically investigate trapped ions interacting with atoms that are coupled to Rydberg states. The strong polarizabilities of the Rydberg levels increases the interaction strength between atoms and ions by many orders of magnitude, as…
We show that the dipole-dipole interaction between two Rydberg atoms can give rise to long range molecules. The binding potential arises from two states that converge to different separated atom asymptotes. These states interact weakly at…
We report the observation of spin-singlet ultra-long range Rydberg butterfly molecules consisting of a ground-state atom bound to a Rydberg atom by $P$-wave scattering of $^{87}$Rb Rydberg electrons from $^{87}$Rb(5s) atoms. A three-photon…
Rydberg molecules, Rydberg-atom or Rydberg-molecule, are an essential ingredient of cold molecular sciences. However, due to the richness of Rydberg-neutral interactions, new kinds of Rydberg molecules and binding mechanisms are still to be…
We examine topological phases and symmetry-protected electronic edge states in the context of a Rydberg composite: a Rydberg atom interfaced with a structured arrangement of ground-state atoms. The electronic Hamiltonian of such a composite…
Rydberg excited states of molecules pose a challenge for electronic structure calculations because of their highly diffuse electron distribution. Even large and elaborate atomic basis sets tend to underrepresent the long-range tail, overly…
The ability to control and tune interactions in ultracold atomic gases has paved the way towards the realization of new phases of matter. Whereas experiments have so far achieved a high degree of control over short-ranged interactions, the…
Recent experiments have demonstrated the spontaneous evolution of a gas of ultracold Rydberg atoms into an expanding ultracold plasma, as well as the reverse process of plasma recombination into highly excited atomic states. Treating the…
Assemblies of highly excited Rydberg atoms in an ultracold gas can be set into motion by a combination of van-der-Waals and resonant dipole-dipole interactions. Thereby, the collective electronic Rydberg state might change due to…
Spectroscopic measurements of the rotational distribution of $^{84}$Sr and $^{86}$Sr 5sns $^1S_0$ ultralong-range Rydberg molecular dimers created via photoassociation in a cold gas are reported. The dimers are produced by two-photon…
We show that nuclear motion of Rydberg atoms can be induced by resonant dipole-dipole interactions that trigger the energy transfer between two energetically close Rydberg states. How and if the atoms move depends on their initial…
Double-resonant photoexcitation of nitric oxide in a molecular beam creates a dense ensemble of $50f(2)$ Rydberg states, which evolves to form a plasma of free electrons trapped in the potential well of an NO$^+$ spacecharge. The plasma…
We consider dynamics of a Rydberg impurity in a cloud of ultracold bosonic atoms in which the Rydberg electron can undergo spin-changing collisions with surrounding atoms. This system realizes a new type of the quantum impurity problem that…