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In the last quarter of the nineteenth century, Ludwig Boltzmann explained how irreversible macroscopic laws, in particular the second law of thermodynamics, originate in the time-reversible laws of microscopic physics. Boltzmann's analysis,…

Statistical Mechanics · Physics 2007-05-23 Sheldon Goldstein

Conversion of chemical energy into mechanical work is the fundamental mechanism of several natural phenomena at the nanoscale, like molecular machines and Brownian motors. Quantum mechanical effects are relevant for optimising these…

Quantum Physics · Physics 2025-06-03 Ugo Marzolino

The second law of thermodynamics points to the existence of an `arrow of time', along which entropy only increases. This arises despite the time-reversal symmetry (TRS) of the microscopic laws of nature. Within quantum theory, TRS underpins…

Strongly Correlated Electrons · Physics 2021-04-13 Max McGinley , Nigel R. Cooper

Fundamental laws of physics are symmetric under time reversal ($T$) symmetry, but the $T$ symmetry is strongly broken in the macroscopic world. In this Perspective, I review $T$ symmetry breaking frameworks: \textit{second law of…

Statistical Mechanics · Physics 2024-12-06 Mahendra K. Verma

Machines are only Carnot efficient if they are reversible, but then their power output is vanishingly small. Here we ask, what is the maximum efficiency of an irreversible device with finite power output? We use a nonlinear scattering…

Mesoscale and Nanoscale Physics · Physics 2014-04-23 Robert S. Whitney

We consider the efficiency at maximum power of a quantum Otto engine, which uses a spin or a harmonic system as its working substance and works between two heat reservoirs at constant temperatures $T_h$ and $T_c$ $ (<T_h)$. Although the…

Statistical Mechanics · Physics 2015-06-22 Feilong Wu , Jizhou He , Yongli Ma , Jianhui Wang

We assume that markovian dynamics on a finite graph enjoys a gauge symmetry under local scalings of the probability density, derive the transformation law for the transition rates and interpret the thermodynamic force as a gauge potential.…

Statistical Mechanics · Physics 2015-05-30 Matteo Polettini

We study the thermodynamics of open systems weakly driven out-of-equilibrium by nonconservative and time-dependent forces using the linear regime of stochastic thermodynamics. We make use of conservation laws to identify the potential and…

Statistical Mechanics · Physics 2022-10-13 Danilo Forastiere , Riccardo Rao , Massimiliano Esposito

Finite thermostats are studied in the context of nonequilibrium statistical mechanics. Entropy production rate has been identified with the mechanical quantity expressed by the phase space contraction rate and the currents have been linked…

Statistical Mechanics · Physics 2009-06-15 Giovanni Gallavotti

This paper discusses the thermodynamic irreversibility realized in high-dimensional Hamiltonian systems with a time-dependent parameter. A new quantity, the irreversible information loss, is defined from the Lyapunov analysis so as to…

Statistical Mechanics · Physics 2009-10-31 Shin-ichi Sasa , Teruhisa S. Komatsu

Quantum mechanics still provides new unexpected effects when considering the transport of energy and information. Models of continuous time quantum walks, which implicitly use time-reversal symmetric Hamiltonians, have been intensely used…

Quantum Physics · Physics 2013-08-23 Zoltan Zimboras , Mauro Faccin , Zoltan Kadar , James Whitfield , Ben Lanyon , Jacob Biamonte

The Carnot statement of the second law of thermodynamics poses an upper limit on the efficiency of all heat engines. Recently, it has been studied whether generic quantum features such as coherence and quantum entanglement could allow for…

Statistical Mechanics · Physics 2015-10-14 Bartłomiej Gardas , Sebastian Deffner

Microscopic physical laws are time-symmetric, hence, a priori there exists no preferential temporal direction. However, the second law of thermodynamics allows one to associate the "forward" temporal direction to a positive variation of the…

Quantum Physics · Physics 2021-11-29 Giulia Rubino , Gonzalo Manzano , Časlav Brukner

For thermoelectric power generation in a multi-terminal geometry, strong numerical evidence for a universal bound as a function of the magnetic-field induced asymmetry of the non-diagonal Onsager coefficients is presented. This bound…

Statistical Mechanics · Physics 2015-01-13 Kay Brandner , Udo Seifert

We study the efficiency fluctuations of a stochastic heat engine made of $N$ interacting unicyclic machines and undergoing a phase transition in the macroscopic limit. Depending on $N$ and on the observation time, the machine can explore…

Statistical Mechanics · Physics 2020-07-01 Hadrien Vroylandt , Massimiliano Esposito , Gatien Verley

The relationship between thermodynamics and statistical physics is valid in the thermodynamic limit - when the number of particles becomes very large. Here, we study thermodynamics in the opposite regime - at both the nano scale, and when…

Quantum Physics · Physics 2014-10-28 Michał Horodecki , Jonathan Oppenheim

It is proven, without using the microscopic reversibility argument of Onsager, that lossy reciprocal systems have a hidden time-reversal symmetry. The key idea is that the dissipation channels of lossy dielectrics can be mimicked by a…

Classical Physics · Physics 2019-05-22 Mario G. Silveirinha

Motivated by entropic optimal transport, time reversal of diffusion processes is revisited. An integration by parts formula is derived for the carr\'e du champ of a Markov process in an abstract space. It leads to a time reversal formula…

Probability · Mathematics 2022-09-05 Patrick Cattiaux , Giovanni Conforti , Ivan Gentil , Christian Léonard

Informational dependence between statistical or quantum subsystems can be described with Fisher matrix or Fubini-Study metric obtained from variations of the sample/configuration space coordinates. Using these non-covariant objects as…

High Energy Physics - Theory · Physics 2019-01-30 Vitaly Vanchurin

The efficiency of microscopic heat engines in a thermally heterogenous environment is considered. We show that, as a consequence of the recently discovered entropic anomaly, quasi-static engines, whose efficiency is maximal in a fluid at…

Statistical Mechanics · Physics 2015-06-12 Stefano Bo , Antonio Celani
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