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The two-dimensional graphene-like carbon allotrope, graphyne, has been recently fabricated and exhibits many interesting electronic properties. In this work, we investigate the thermoelectric properties of {\gamma}-graphyne by performing…

Mesoscale and Nanoscale Physics · Physics 2016-08-19 P. H. Jiang , H. J. Liu , L. Cheng , D. D. Fan , J. Zhang , J. Wei , J. H. Liang

We carry out a systematic study of the thermal conductivity of four single-layer transition metal dichalcogenides, MX$_2$ (M = Mo, W; X = S, Se) from first-principles by solving the Boltzmann Transport Equation (BTE). We compare three…

Materials Science · Physics 2019-03-29 Pol Torres , Francesc Xavier Alvarez , Xavier Cartoixà , Riccardo Rurali

Using first-principles calculations based on density functional theory combined with the non-equilibrium Green's function approach, the transport behaviors of a single-molecule junction formed by benzenedithiol connected to gold electrodes…

Materials Science · Physics 2022-09-20 Rigao Wang , Feng Shuang , Xiaowen Shi , Mingyan Chen

It was recently suggested that molecular junctions would be excellent elements for efficient and high-power thermoelectric energy conversion devices. However, experimental measurements of thermoelectric conversion in molecular junctions…

Mesoscale and Nanoscale Physics · Physics 2015-06-09 Elinor Zerah-Harush , Yonatan Dubi

The electronic structure and thermoelectric properties of SnSe are studied by first-principles methods. The inclusion of van der Waals dispersive corrections improves the agreement of structural parameters with experiments. The bands…

Materials Science · Physics 2016-12-20 Robert L. González-Romero , Alex Antonelli , Juan J. Meléndez

The thermoelectric properties of a molecular junction model, appropriate for large molecules such as fullerenes, are studied within a non-equilibrium adiabatic approach in the linear regime at room temperature. A self-consistent calculation…

Mesoscale and Nanoscale Physics · Physics 2014-09-26 C. A. Perroni , D. Ninno , V. Cataudella

The search for new thermoelectric materials aims at improving their power and efficiency, as expressed by thermopower $S$ and figure of merit $ZT$. By considering a very general transport spectral function $W(E)$, expressions for $S$ and…

Materials Science · Physics 2018-04-10 Peter Zahn

We study theoretically the length dependence of both conductance and thermopower in metal-molecule-metal junctions made up of dithiolated oligophenylenes contacted to gold electrodes. We find that while the conductance decays exponentially…

Mesoscale and Nanoscale Physics · Physics 2009-05-24 F. Pauly , J. K. Viljas , J. C. Cuevas

Thermoelectric devices that utilize the Seebeck effect convert heat flow into electrical energy and are highly desirable for the development of portable, solid state, passively-powered electronic systems. The conversion efficiencies of such…

Materials Science · Physics 2015-01-06 Ruixiang Fei , Alireza Faghaninia , Ryan Soklaski , Jia-An Yan , Cynthia Lo , Li Yang

The structural, dynamical, and thermodynamical properties of diamond, graphite and layered derivatives (graphene, rhombohedral graphite) are computed using a combination of density-functional theory (DFT) total-energy calculations and…

Materials Science · Physics 2009-11-10 Nicolas Mounet , Nicola Marzari

The thermoelectric properties of in plane heterostructures made of Graphene and hexagonal Boron Nitride (BN) have been investigated by means of atomistic simulation. The heterostructures consist in armchair graphene nanoribbons to the sides…

Mesoscale and Nanoscale Physics · Physics 2015-08-19 Van-Truong Tran , Jérôme Saint Martin , Philippe Dollfus

A composite material is considered which consists of conducting nanoparticles separated by tunneling dielectric barriers. The influence of the phonon thermal conductivity of dielectric matrix on the thermoelectric figure of merit of this…

Mesoscale and Nanoscale Physics · Physics 2012-09-21 L. P. Bulat , D. Kossakovski , D. A. Pshenay-Severin

A first-principles approach is presented for the thermoelectricity in molecular junctions formed by a single molecule contact. The study investigates the Seebeck coefficient considering the source-drain electrodes with distinct temperatures…

Mesoscale and Nanoscale Physics · Physics 2009-05-07 Yu-Shen Liu , Yu-Chang Chen

In the present work we theoretically analyze thermoelectric transport in single-molecule junctions (SMJ) characterized by strong interactions between electrons on the molecular linkers and phonons in their nuclear environments where…

Mesoscale and Nanoscale Physics · Physics 2024-01-17 Natalya A. Zimbovskaya

Understanding phonon transport at a molecular scale is fundamental to the development of high-performance thermoelectric materials for the conversion of waste heat into electricity. We have studied phonon and electron transport in alkane…

Mesoscale and Nanoscale Physics · Physics 2015-11-13 Hatef Sadeghi , Sara Sangtarash , Colin J. Lambert

Recent discovery of new materials for thermoelectric energy conversion is enabled by efficient prediction of materials' performance from first-principles, without empirically fitted parameters. The novel simplified approach for computing…

Materials Science · Physics 2018-05-02 Georgy Samsonidze , Boris Kozinsky

Motivated by recent experiments, we study the variability of the thermal conductance of single dithiolated alkane molecules of varying length connecting two gold electrodes. For this purpose, we examine (i) the influence of the…

Mesoscale and Nanoscale Physics · Physics 2019-10-08 J. C. Klöckner , F. Pauly

Separating electron and phonon thermal conductivity components is imperative for understanding the principle thermal transport mechanisms in metals and highly desirable in many applications. In this work, we predict the mode-dependent…

Materials Science · Physics 2019-10-23 Zhen Tong , Shouhang Li , Xiulin Ruan , Hua Bao

The rational design of single molecule electrical components requires a deep and predictive understanding of structure-function relationships. Here we explore the relationship between chemical substituents and the conductance of…

We present calculations of the electronic and thermal transport properties of graphene antidot lattices with a finite length along the transport direction. The calculations are based on a single orbital tight-binding model and the Brenner…

Mesoscale and Nanoscale Physics · Physics 2014-03-18 Tue Gunst , Troels Markussen , Antti-Pekka Jauho , Mads Brandbyge