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The photo-driven process of singlet fission generates coupled triplet pairs (TT) with fundamentally intriguing and potentially useful properties. The quintet 5TT0 sublevel is particularly interesting for quantum information because it is…

Organic semiconductor crystals stand out as an efficient, cheap and diverse platform for realising optoelectronic applications. The optical response of these crystals is governed by a rich tapestry of exciton physics. So far, little is…

Mesoscale and Nanoscale Physics · Physics 2022-09-13 Joshua J. P. Thompson , Dominik Muth , Sebastian Anhäuser , Daniel Bischof , Marina Gerhard , Gregor Witte , Ermin Malic

We microscopically study the effect of the magnetic field (Zeeman splitting) on the superconducting state in a model for quasi-one-dimensional organic superconductors (TMTSF)$_{2}X$. We investigate the competition between spin singlet and…

Superconductivity · Physics 2015-05-14 Hirohito Aizawa , Kazuhiko Kuroki , Yukio Tanaka

A superconductor (SC) in proximity to a ferromagnetic insulator (FMI) is predicted to exhibit mixed singlet and triplet pair correlations. The magnetic proximity effect of FMI spin-splits the energy of Bogoliubov excitations and leads to a…

Mesoscale and Nanoscale Physics · Physics 2024-07-04 Chen-How Huang , Anastasiia Skurativska , F. Sebastian Bergeret , Miguel A. Cazalilla

The linear magnetoelectric (ME) effect provides a special route for linking magnetic and electric properties. In microwaves, a local ME effect appears due to the dynamical symmetry breakings of magnetic-dipolar modes (MDMs) in a ferrite…

Materials Science · Physics 2015-05-13 E. O. Kamenetskii

A method for improving the efficiency of solar cells is combining a low-bandgap semiconductor with a singlet fission material (which converts one high energy singlet into two low energy triplets following photoexcitation). Here we present a…

Materials Science · Physics 2021-12-07 Alan R. Bowman , Samuel D. Stranks , Bartomeu Monserrat

Dynamics of the singlet-triplet crystalline electric field (CEF) system at finite temperatures is discussed by use of the non-crossing approximation. Even though the Kondo temperature is smaller than excitation energy to the CEF triplet,…

Strongly Correlated Electrons · Physics 2009-11-11 Junya Otsuki , Hiroaki Kusunose , Yoshio Kuramoto

We present an experimental study of electron-electron exchange interaction in self-assembled CdTe/ZnTe quantum dots based on the photoluminescence measurements. The character and strength of this interaction are obtained by simultaneous…

Mesoscale and Nanoscale Physics · Physics 2015-06-15 T. Kazimierczuk , T. Smoleński , J. Kobak , M. Goryca , W. Pacuski , A. Golnik , K. Fronc , Łukasz Kłopotowski , P. Wojnar , P. Kossacki

We present a generic theory of primary photoexcitations in low band gap donor-acceptor conjugated copolymers. Because of the combined effects of strong electron correlations and broken symmetry, there is considerable mixing between a…

Mesoscale and Nanoscale Physics · Physics 2016-01-01 Karan Aryanpour , Tirthankar Dutta , Uyen N. V. Huynh , Zeev Valy Vardeny , Sumit Mazumdar

We studied the dynamics of transfer of photoexcited electronic states in a bilayer of the two-dimensional transition metal dichalcogenide ReS$_2$ and tetracene, with the aim to produce triplets in the latter. This material combination was…

For the theoretical screening of Singlet Fission (SF) rates in molecular aggregates, commonly dimer model systems are employed. However, there is experimental evidence, that the SF process proceeds from the $^{1}$(TT) state via an…

Chemical Physics · Physics 2023-12-22 Anurag Singh , Merle I. S. Röhr

Searching for new functionality in next generation electronic devices is a principal driver of material physics research. Multiferroics simultaneously exhibit electric and magnetic order parameters that may be coupled through…

Materials Science · Physics 2017-06-06 Sae Hwan Chun , Kwang Woo Shin , Kee Hoon Kim , John F. Mitchell , Philip J. Ryan , Jong-Woo Kim

Interlayer excitons (IXs) in hetero-bilayers of transition metal dichalcogenides (TMDs) represent an exciting emergent class of long-lived dipolar composite bosons in an atomically thin, near-ideal two-dimensional (2D) system. The…

Singlet fission (SF) is a multi-exciton generation process that could be harnessed to improve the efficiency of photovoltaic devices. Experimentally, systems derived from the pentacene molecule have been shown to exhibit ultrafast SF with…

Chemical Physics · Physics 2020-06-23 David H. P. Turban , Gilberto Teobaldi , David D. O'Regan , Nicholas D. M. Hine

Kinetics of singlet fission in organic semiconductors, in which the excited singlet state (S_1) spontaneously splits into a pair of triplet (T) excitons, is known to be strongly influenced by back geminate annihilation of TT-pairs. We show…

Materials Science · Physics 2017-05-24 A. I. Shushin

The growing interest in harnessing singlet fission for photovoltaic applications stems from the possibility of generating two excitons from a single photon. Quantum efficiencies above unity have been reported, yet the correlation between…

A ferromagnetic insulator (FI) in contact with a superconductor (S) is known to induce a spin splitting of the BCS density of states at the FI/S interface. This spin splitting causes the Cooper pairs to reduce their singlet-state…

Superconductivity · Physics 2022-05-10 Alberto Hijano , Vitaly N. Golovach , F. Sebastián Bergeret

Triplet excitonic state in the organic molecule may arise from a singlet excitation and the following inter-system crossing. Especially for a spin-bearing molecule, an exchange interaction between the triplet exciton and the original spin…

Quantum Physics · Physics 2014-06-12 Wei Wu

While silicon solar cells dominate global photovoltaic energy production, their continued improvement is hindered by the single junction limit. One potential solution is to use molecular singlet exciton fission to generate two electrons…

It has been shown that the crystal-field interactions can produce a non- magnetic singlet ground state for the highly-correlated d6 system situated in the quasi-octahedral crystal field (CEF) surrounding provided the spin-orbit interactions…

Strongly Correlated Electrons · Physics 2009-10-31 R. J. Radwanski , Z. Ropka