Related papers: Van der Waals interactions between excited atoms i…
Using the general expressions for level shifts obtained from the master equation for a small system interacting with a large one considered as a reservoir, we calculate the dispersive potentials between an atom and a wall in the dipole…
Accurate modeling of warm and hot dense matter is challenging in part due to the multitude of excited states that must be considered. In thermal density functional theory, these excited states are averaged over to produce a single,…
It is demonstrated that the general theory of Casimir and van der Waals forces describes the interaction-induced equilibrium thermodynamic potentials of the damped harmonic oscillator bilinearly coupled to the environment. An extended model…
We determine the energy-level shift experienced by a neutral atom due the quantum electromagnetic interaction with a layered dielectric body. We use the technique of normal-mode expansion to quantize the electromagnetic field in the…
We present an approach for computing long-range van der Waals (vdW) interactions between complex molecular systems and arbitrarily shaped macroscopic bodies, melding atomistic treatments of electronic fluctuations based on density…
By means of quantum mechanics and quantum electrodynamics applied to coupled harmonic Drude oscillators, we study the interaction between two neutral atoms or molecules subject to a uniform static electric field. Our focus is to understand…
It is known that, when an excited atom spontaneously emits one photon, two effects are produced. First, the atom's internal and external states are entangled with the states of the emitted photon. Second, the atom receives a momentum…
Zero-point quantum fluctuations of the electromagnetic vacuum create the widely known London-van der Waals attractive force between two atoms. Recently, there was a revived interest in the interaction of rotating matter with the quantum…
We consider a slowly varying time dependent d-level atom interacting with a photon field. Restricted to the single excitation atom-field sector, the model is a time-dependent generalization of the Wigner-Weisskopf model describing…
Alkaline-earth-like transition-metal atoms such as Zn and Cd are promising candidates for precision measurements and quantum many-body physics experiments. Here, we theoretically investigate the properties of diatomic molecules containing…
We present analysis of a system of three two-level atoms interacting with each other through the dipole-dipole interaction. The interaction manifests between excited state of one of the atoms and the ground state of its nearest neighbour.…
Assemblies of Rydberg atoms subject to resonant dipole-dipole interactions form Frenkel excitons. We show that van-der-Waals shifts can significantly modify the exciton wave function, whenever atoms approach each other closely. As a result,…
The theory of the long-range interaction of metastable excited atomic states with ground-state atoms is analyzed. We show that the long-range interaction is essentially modified when quasi-degenerate states are available for virtual…
The mechanical action on matter of the electromagnetic field emitted by a fluctuating source is governed by its statistics. In particular, thermal sources and vacuum fluctuations exert on bodies those well-known Casimir (C) and Van der…
The Lifshitz theory of the van der Waals force is extended for the case of an atom (molecule) interacting with a plane surface of an uniaxial crystal or with a long solid cylinder or cylindrical shell made of isotropic material or uniaxial…
This contribution briefly reviews some recent work demonstrating the partial breakdown of the colloidal fluid <--> atomic fluid analogy. The success of liquid state theory for atomic fluids stems in part from the van der Waals picture,…
We investigate the influence of the appearance of excitonic states on van der Waals interactions among two Rydberg atoms. The atoms are assumed to be in different Rydberg states, e.g., in the $|ns\rangle$ and $|np\rangle$ states. The…
The structure and stability of atomic and molecular systems with van der Waals (vdW) bonding are often determined by the interplay between attractive dispersion interactions and repulsive interactions caused by electron confinement. Arising…
A simple model of an atom interacting with the quantized electromagnetic field is studied. The atom has a finite mass $m$, finitely many excited states and an electric dipole moment, $\vec{d}_0 = -\lambda_{0} \vec{d}$, where $\| d^{i}\| =…
The universal aspects of atom-dimer elastic collisions are investigated within the framework of Faddeev equations. The two-body interactions between the neutral atoms are approximated by the separable potential approach. Our analysis…