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Single- and few-layer MoS2 has recently gained attention as an interesting new material system for opto-electronics. Here, we report on scanning Raman measurements on few-layer MoS2 flakes prepared by exfoliation. We observe a Raman mode…

Materials Science · Physics 2012-09-19 G. Plechinger , S. Heydrich , J. Eroms , D. Weiss , Schüller , T. Korn

Black phosphorus stands out from the family of two-dimensional materials as a semiconductor with a direct, layer-dependent bandgap in energy corresponding to the spectral range from the visible to the mid-infrared (mid-IR), as well as many…

Optics · Physics 2017-10-10 Ruoming Peng , Kaveh Khaliji , Nathan Youngblood , Roberto Grassi , Tony Low , Mo Li

Black phosphorus has been revisited recently as a new two-dimensional material showing potential applications in electronics and optoelectronics. Here we report the anisotropic in-plane thermal conductivity of suspended few-layer black…

Mesoscale and Nanoscale Physics · Physics 2015-10-20 Zhe Luo , Jesse Maassen , Yexin Deng , Yuchen Du , Richard P. Garrelts , Mark S. Lundstrom , Peide D. Ye , Xianfan Xu

Conventional Raman spectroscopy faces inherent limitations in detecting interlayer layer breathing (LB) vibrations with inherently weak electron-phonon coupling or Raman inactivity in two-dimensional materials, hindering insights into…

Anisotropy refers to the property of a material exhibiting directionally dependent features. In this paper, we introduce black phosphorous (BP), the most stable allotrope of phosphorus in layered orthorhombic structure with a bandgap of 0.3…

Mesoscale and Nanoscale Physics · Physics 2014-07-30 Fengnian Xia , Han Wang , Yichen Jia

We review the basic optical, electronic, optoelectronic, thermoelectric and mechanical properties of few-layer black phosphorus (BP), a layered semiconductor that can be exfoliated from bulk BP, the most stable allotrope of phosphorus. The…

Mesoscale and Nanoscale Physics · Physics 2017-10-17 Andrey Chaves , W. Ji , J. Maassen , T. Dumitrica , T. Low

Black phosphorus (BP) has recently emerged as an alternative 2D semiconductor owing to its fascinating electronic properties such as tunable bandgap and high charge carrier mobility. The structural investigation of few-layer BP, such as…

Mesoscale and Nanoscale Physics · Physics 2017-02-01 Yangjin Lee , Jun-Yeong Yoon , Declan Scullion , Jeongsu Jang , Elton J G Santos , Hu Young Jeong , Kwanpyo Kim

We investigated polarization dependence of the Raman modes in black phosphorus (BP) using five different excitation wavelengths. The crystallographic orientation was determined by comparing polarized optical microscopy with high-resolution…

Mesoscale and Nanoscale Physics · Physics 2015-11-10 Jungcheol Kim , Jae-Ung Lee , Jinhwan Lee , Hyo Ju Park , Zonghoon Lee , Changgu Lee , Hyeonsik Cheong

Phosphorene, a monolayer of black phosphorus (BP), is an elemental two-dimensional material with interesting physical properties, such as high charge carrier mobility and exotic anisotropic in-plane properties. To fundamentally understand…

Mesoscale and Nanoscale Physics · Physics 2019-12-04 Yangjin Lee , Sol Lee , Jun-Yoeong Yoon , Jinwoo Cheon , Hu Young Jeong , Kwanpyo Kim

We report high pressure Raman experiments of Black phosphorus up to 24 GPa. The line widths of first order Raman modes A$^1_g$, B$_{2g}$ and A$^2_g$ of the orthorhombic phase show a minimum at 1.1 GPa. Our first-principles density…

Strongly Correlated Electrons · Physics 2017-09-20 Satyendra Nath Gupta , Anjali Singh , Koushik Pal , Biswanath Chakraborti , D. V. S. Muthu , U V Waghmare , A. K. Sood

Few-layer black phosphorus was recently rediscovered as a narrow-bandgap atomically thin semiconductor and has already attracted unprecedented attention due to its interesting properties. One feature of this material that sets it apart from…

Mesoscale and Nanoscale Physics · Physics 2017-04-04 Artem Mishchenko , Yang Cao , Geliang Yu , Colin R. Woods , Roman V. Gorbachev , Kostya S. Novoselov , Andre K. Geim , Leonid S. Levitov

Within the past few years, atomically thin black phosphorus (BP) has been demonstrated as a fascinating new 2D material that is promising for novel nanoelectronics and nanophotonics applications, due to its many unique properties such as…

Applied Physics · Physics 2019-08-06 Zi-Yu Chen , Rui Qin

We report the observation of layer breathing mode (LBM) vibrations in few-layer graphene (FLG) samples of thickness from 2 to 6 layers, exhibiting both Bernal (AB) and rhombohedral (ABC) stacking order. The LBM vibrations are identified…

Mesoscale and Nanoscale Physics · Physics 2012-11-15 Chun Hung Lui , Leandro M. Malard , SukHyun Kim , Gabriel Lantz , François E. Laverge , Riichiro Saito , Tony F. Heinz

Black phosphorus (BP) offers considerable promise for infrared and visible photonics. Efficient tuning of the bandgap and higher subbands in BP by modulation of the Fermi level or application of vertical electric fields has been previously…

Two-dimensional materials supporting deep-subwavelength plasmonic modes can also exhibit strong magneto-optical responses. Here, we theoretically investigate magnetoplasmons (MPs) in monolayer black phosphorus (BP) structures under moderate…

Recently, it was demonstrated that a graphene/dielectric/metal configuration can support acoustic plasmons, which exhibit extreme plasmon confinement an order of magnitude higher than that of conventional graphene plasmons. Here, we…

Mesoscale and Nanoscale Physics · Physics 2018-06-22 In-Ho Lee , Luis Martin-Moreno , Daniel A. Mohr , Kaveh Khaliji , Tony Low , Sang-Hyun Oh

We investigated 10 to 200 nm thick black phosphorus flakes on SiO2/Si and polyimide substrates by Angle-resolved Polarized Raman spectra (ARPRS) using 442 nm excitation wavelength. The results revealed that ARPRS with 442 nm excitation can…

Materials Science · Physics 2016-10-12 Weijun Luo , Qian Song , Guangnan Zhou , David Tuschel , Guangrui Xia

The symmetry group analysis is applied to classify the phonon modes of $N$-stacked graphene layers (NSGL's) with AB- and AA-stacking, particularly their infra-red and Raman properties. The dispersions of various phonon modes are calculated…

Materials Science · Physics 2008-06-30 Jin-Wu Jiang , Hui Tang , Bing-Shen Wang , Zhao-Bin Su

We report Raman forbidden layer-breathing modes (LBMs) in layered semiconductor materials (LSMs). The intensity distribution of all observed LBMs depends on layer number, incident light wavelength and refractive index mismatch between LSM…

Phonon polaritons (PhPs) are hybrid photon-phonon waves which enable strong light-matter interactions and subdiffractional confinement, potentially empowering applications in sensing, nonlinear optics and nanoscale energy manipulation. In…