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Low-frequency Raman scattering spectra are presented for gold nanocrystals with diameters 3.5 and 13 nm. The frequencies of the Raman peaks but also their number are shown to vary with the nanocrystal size. These results are analyzed using…

Mesoscale and Nanoscale Physics · Physics 2012-02-09 Lucien Saviot , Nicolas Combe , Adnen Mlayah

Ground-based optical astronomical observations supported by or in the vicinity of laser guide-star systems can be contaminated by Raman-scattered laser photons. Anticipating, alleviating, and correcting for the impact of this self-inflicted…

Instrumentation and Methods for Astrophysics · Physics 2023-04-28 F. P. A. Vogt , A. Mehner , P. Figueira , S. Yu , F. Kerber , T. Pfrommer , W. Hackenberg , D. Bonaccini Calia

In this article, we address the optomechanical effects in surface-enhanced resonant Raman scattering (SERRS) from a single molecule in a nano-particle on mirror (NPoM) nanocavity by developing a quantum master equation theory, which…

Hydrogen detection is of great importance in chemical and energy industries. Optical fiber hydrogen sensors show flexibility and compactness and have the potential for distributed analysis. However, traditional fiber sensors encounter a…

Optics · Physics 2019-05-16 F. Yang , Y. Zhao , Y. Qi , Y. Z. Tan , H. L. Ho , W. Jin

The Raman shifts of nanocrystalline GaSb excited by an Ar+ ion laser of wavelengths 514.5, 496.5, 488.0, 476.5, and 457.9 nm are studied by experiment and explained by phonon confinement, tensile stress, resonance Raman scattering and…

We report a high-pressure Raman spectroscopy study of a graphite-water mixture using water as the pressure-transmitting medium up to 9.9 GPa. In the graphite-rich region, three characteristic Raman features-the $E_{2g}^{(1)}$ shear mode,…

Materials Science · Physics 2025-09-03 K. Perry , A. T. Roy , A. R. Parmenter , Y. J. Ryu , V. B. Prakapenka , J. Lim

Surface enhanced Raman spectra from molecules (bipyridyl ethylene) adsorbed on gold dumbells are observed to become increasingly asymmetric (Fano-like) at higher incident light intensity. The electronic temperature (inferred from the…

Mesoscale and Nanoscale Physics · Physics 2016-01-12 S. Dey , M. Banik , E. Hulkko , K. Rodriguez , V. A. Apkarian , M. Galperin , A. Nitzan

For most silicates, controlling the crystallization - through the nucleation, growth, and stabilization of distinct crystalline phase - is critical to achieving the desired physical properties in the final glass-ceramic product. In this…

We report a study of long-range MoS2-substrate interaction using resonant Raman imaging. We observed a strong thickness-dependent peak shift of a Raman-forbidden mode that can be used as a new method of determining the thickness of…

Materials Science · Physics 2016-12-13 Hongyuan Li , Dmitri V. Voronine

Raman spectroscopy is a precious tool for the characterization of van der Waals materials, e.g. for the determination of the layer number in thin exfoliated flakes. For sensitive materials, however, this method can be dramatically invasive.…

We demonstrate enhancements of Raman scattering from graphene on two-dimensional photonic crystals using double resonances, which originate from simultaneous enhancements by a localized guided mode and a cavity mode. By adjusting the…

Mesoscale and Nanoscale Physics · Physics 2018-08-24 W. Gomulya , H. Machiya , K. Kashiwa , T. Inoue , S. Chiashi , S. Maruyama , Y. K. Kato

The intensity ratio between two major Raman bands in graphene is one of the most important information for physics of graphene and has been believed to represent various intrinsic properties of graphene without critical assessment of…

We performed a Raman scattering study of Na$_2$Ti$_2$As$_2$O. We identified a symmetry breaking structural transition at around $T_s = 150$ K, which matches a large bump in the electrical resistivity. Several new peaks are detected below…

Superconductivity · Physics 2016-04-13 D. Chen , T. T. Zhang , Z. -D. Song , H. Li , W. -L. Zhang , T. Qian , J. -L. Luo , Y. -G. Shi , Z. Fang , P. Richard , H. Ding

The purpose of this work is to calculate the vibrational modes of an elastically anisotropic sphere embedded in an isotropic matrix. This has important application to understanding the spectra of low-frequency Raman scattering from…

Mesoscale and Nanoscale Physics · Physics 2010-09-29 L. Saviot , D. B. Murray , E. Duval , A. Mermet , S. Sirotkin , M. C. Marco de Lucas

We propose a full-vectorial numerical study of far field radiation patterns in coherent anti-Stokes Raman scattering (CARS) microscopy. We emphasis the particular role of the Raman depolarisation ratio of the observed medium and show how it…

Optics · Physics 2009-11-13 D. Gachet , N. Sandeau , H. Rigneault

Being able to predict the failure of materials based on structural information is a fundamental issue with enormous practical and industrial relevance for the monitoring of devices and components. Thanks to recent advances in deep learning,…

The effects of plasticization of poly(methyl methacrylate) glass on the boson peaks observed by Raman and neutron scattering are compared. In plasticized glass the cohesion heterogeneities are responsible for the neutron boson peak and…

Condensed Matter · Physics 2007-05-23 E. Duval , L. Saviot , A. Mermet , L. David , S. Etienne , V. Bershtein , A. J. Dianoux

The effect of oscillatory shear strain on nonaffine rearrangements of individual particles in a three-dimensional binary glass is investigated using molecular dynamics simulations. The amorphous material is represented by the Kob-Andersen…

Soft Condensed Matter · Physics 2016-01-12 Nikolai V. Priezjev

We propose and demonstrate a novel technique that combines Raman scattering and optical cycling in molecules with diagonal Franck-Condon factors. This resonance Raman optical cycling manipulates molecules to behave like efficient…

Atomic Physics · Physics 2021-08-26 J. C. Shaw , J. C. Schnaubelt , D. J. McCarron

The effect of small-amplitude periodic shear on annealing of a shear band in binary glasses is investigated using molecular dynamics simulations. The shear band is first introduced in stable glasses via large-amplitude periodic shear, and…

Soft Condensed Matter · Physics 2021-05-11 Nikolai V. Priezjev