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The structural, electronic and magnetic properties of small ${\rm Fe}_m {\rm Rh}_n$ clusters having $N = m+n \leq 8$ atoms are studied in the framework of a generalized-gradient approximation to density-functional theory. The correlation…

Atomic and Molecular Clusters · Physics 2011-10-13 Junais Habeeb Mokkath , G. M. Pastor

It is well known that the irradiation-induced defects strongly influence the mechanical properties of zirconium (Zr) or its alloys in nuclear reactors. However, how the point defect changes the mechanical properties has been rarely studied.…

Materials Science · Physics 2016-06-14 Xueyan Zhu , Xingyu Gao , Haifeng Song , Guomin Han , De-Ye Lin

This research establishes a systematic, high-throughput computational framework for designing radiation-resistant, dilute ternary copper-based alloys by addition of solutes that bind to vacancies and reduce their mobility, thus promoting…

Materials Science · Physics 2026-03-03 Vaibhav Vasudevan , Thomas Schuler , Pascal Bellon , Robert Averback

Conventional Oxide dispersion strengthened steels are characterized by thermally stable, high density of Y-Ti-O nanoclusters, which are responsible for their high creep strength. Ti plays a major role in obtaining a high density of…

Materials Science · Physics 2021-06-01 Sruthi Mohan , Gurpreet Kaur , B. K. Panigrahi , C. David , G. Amarendra

This work investigates solute transport due to self-interstitial defects and radiation induced segregation tendencies in dilute ferritic alloys, by computing the transport coefficients of each system based on ab initio calculations of…

Materials Science · Physics 2024-08-28 Luca Messina , Thomas Schuler , Maylise Nastar , Mihai-Cosmin Marinica , Pär Olsson

Nitrogen (N) is a key alloying element that enhances the performance of Fe-Ni-Cr austenitic stainless steels, improving austenite stability, corrosion resistance, and yield strength. However, the role of N in modifying chemical ordering,…

Materials Science · Physics 2025-07-08 Tianyu Su , Brian J. Blankenau , Namhoon Kim , Jessica A. Krogstad , Elif Ertekin

ZrCo alloy is promising to substitute uranium for handling hydrogen isotope storage in thermonuclear reactor. The alloying substitution of Zr in ZrCo with Hf or Ti can enhance the ability of anti-disproportionation. In this work,…

Materials Science · Physics 2022-01-19 Gan Ren

Extensive first-principle calculations on embedded clusters containing few O, Y, Ti, and Cr atoms as well as vacancies are performed to obtain interaction parameters to be applied in Metropolis Monte Carlo simulations, within the framework…

Materials Science · Physics 2014-11-05 M. Posselt , D. Murali , B. K. Panigrahi

The non-equilibrium atom-by-atom growth of Cu-rich Cu-Zr thin films has been investigated by a combination of magnetron sputter deposition and molecular dynamics simulations. We focus on the role of Zr in the transition from large solid…

Materials Science · Physics 2024-09-11 Jiri Houska , Mariia Zhadko , Radomir Cerstvy , Deepika Thakur , Petr Zeman

After irradiation of Fe-Cr alloys of low purity (model alloys of F-M steels), minor solute elements as P, Ni and Si have been shown to create solute clusters which significantly contribute to hardening and might be associated with small…

Materials Science · Physics 2022-08-25 P. M. Gueye , B. Gómez-Ferrer , C. Kaden , C. Pareige

In this article, we investigated the effect of Cr substitution in place of Fe on the structural, magnetic and transport properties of $\mathrm{Co_2FeSi}$ alloy. A comprehensive structural analysis is done using X-ray diffraction (XRD) and…

Materials Science · Physics 2018-11-14 Deepika Rani , Jiban Kangsabanik , K. G. Suresh , N. Patra , D. Bhattacharyya , S. N. Jha , Aftab Alam

The structural properties of the simulated $\rm Cu_{\alpha}Zr_{1-\alpha}$ glassy alloys are studied in the wide range of the copper concentration $\alpha$ to clarify the impact of the composition on the number density of the icosahedral…

Materials Science · Physics 2016-11-23 B. A. Klumov , R. E. Ryltsev , N. M. Chtchelkatchev

Cluster expansion (CE) is effective in modeling the stability of metallic alloys, but sometimes cluster expansions fail. Failures are often attributed to atomic relaxation in the DFT-calculated data, but there is no metric for quantifying…

Materials Science · Physics 2017-07-19 Andrew H. Nguyen , Conrad W. Rosenbrock , C. Shane Reese , Gus L. W. Hart

Ab initio simulations carried out in different atomic cluster configurations in bcc Fe matrix containing Zr and Al suggest energetic favorability of Y-Zr-O phase nucleation, preferably with trigonal Y4Zr3O12 structure. Subsequently, the…

Materials Science · Physics 2022-03-03 Sruthi Mohan , Gurpreet Kaur , C. David , R. Vijay , G. Amarendra

Redistribution of Cr atoms in a Fe85Cr15 alloy caused by its irradiation with 250 keV He ions to different doses viz. 5, 10 and 30 dpa was investigated by means of conversion electrons Mossbauer spectroscopy. The redistribution was…

Materials Science · Physics 2014-12-08 Stanislaw M. Dubiel , Jan Zukrowski

We present results of an extensive set of first-principles density functional theory calculations of point defect formation, binding and clustering energies in austenitic Fe with dilute concentrations of Cr and Ni solutes.

Materials Science · Physics 2012-09-13 T. P. C. Klaver , D. J. Hepburn , G. J. Ackland

The stability properties of vacancy clusters in hexagonal close-packed Zr, cavities and dislocation loops, are investigated at the atomic scale, with a modeling approach based on density functional theory and empirical potentials.…

Materials Science · Physics 2014-07-22 Céline Varvenne , Olivier Mackain , Emmanuel Clouet

The effect of He+ ion irradiation on a distribution of Cr atoms in model (EFDA) Fe(100-x)Cr(x) (x=5.8, 10.75, 15.15) was studied by means of conversion electrons Mossbauer spectroscopy. The alloys were irradiated to the dose of 1.2E16 ions…

Materials Science · Physics 2018-07-06 S. M. Dubiel , J. Zukrowski , Y. Serruys

Atomic scale computer simulations using density functional theory were used to investigate the behaviour of tin in the tetragonal phase oxide layer on Zr-based alloys. The $Sn_{Zr}^{\times}$ site defect was shown to be dominant across most…

Materials Science · Physics 2015-02-25 B. D. C. Bell , S. T. Murphy , P. A. Burr , R. W. Grimes , M. R. Wenman

The iron-chromium alloy and its derivatives are widely used for their remarkable resistance to corrosion, which only occurs in a narrow concentration range around 9 to 13 atomic percent chromium. Although known to be due to chromium…

Materials Science · Physics 2013-02-13 Maximilien Levesque