Related papers: Benchmarking spin-state chemistry in starless core…
Spin degrees of freedom of water molecule in gas and liquid state were investigated in order to provide a reasonable answer about the unsolved problem of a long-term behavior of water spin isomers. The approach used involves an assumption…
Condensation models describe the equilibrium distribution of elements between coexisting mineral solid solutions, silicate liquid, and vapor in a closed chemical system, vapor phase always present, using equations of state of the phases…
(Abridged) We aim to determine the degrees of CO depletion, deuterium fractionation, and ionisation in a sample of seven massive clumps associated with IRDCs. The APEX telescope was used to observe the C17O(2-1), H13CO+(3-2), DCO+(3-2),…
We use FIRE-2 simulations to examine 3-D variations of gas-phase elemental abundances of [O/H], [Fe/H], and [N/H] in 11 Milky Way (MW) and M31-mass galaxies across their formation histories at $z \leq 1.5$ ($t_{\rm lookback} \leq 9.4$ Gyr),…
A new, more comprehensive model of gas-grain chemistry in hot molecular cores is presented, in which nondiffusive reaction processes on dust-grain surfaces and in ice mantles are implemented alongside traditional diffusive surface/bulk-ice…
Molecular oxygen has been the subject of many observational searches as chemical models predicted it to be a reservoir of oxygen. Although it has been detected in two regions of the interstellar medium, its rarity is a challenge for…
Measurements of deuterium in the local interstellar medium have revealed large variations in D/H along different lines of sight. Moreover, recent {\it Far Ultraviolet Spectroscopic Explorer} (FUSE) measurements find D/H to be anticorrelated…
Gas phase Elemental abundances in molecular CloudS (GEMS) is an IRAM 30m large program aimed at determining the elemental abundances of carbon (C), oxygen (O), nitrogen (N), and sulfur (S) in a selected set of prototypical star-forming…
We report the first detection of the ground transition of the deuterated water at 464 GHz in the young proto-planetary disk surrounding the solar type protostar DM Tau. The line is observed in absorption against the continuum from the cold…
We report a detailed attempt to model the ortho-to-para abundance ratio of c-C3H2 so as to reproduce observed values in the cores of the well-known source TMC-1. According to observations, the ortho-to-para ratios vary, within large…
Methanol is a key species in astrochemistry since it is the most abundant organic molecule in the ISM and is thought to be the mother molecule of many complex organic species. Estimating the deuteration of methanol around young protostars…
We study the time evolution of the reduced density matrix of a system of spin-1/2 particles interacting with an environment of spin-1/2 particles. The initial state of the composite system is taken to be a product state of a pure state of…
We have used the Odin submillimetre-wave satellite telescope to observe the ground state transitions of ortho-ammonia and ortho-water, including their 15N, 18O, and 17O isotopologues, towards Sgr B2. The extensive simultaneous velocity…
Although deuterium (D) on Mars has received substantial attention, the deuterated ionosphere remains relatively unstudied. This means that we also know very little about non-thermal D escape from Mars, since it is primarily driven by excess…
Results from a large set of hydrodynamical SPH simulations of galaxy clusters in a flat LCDM cosmology are used to investigate the metal enrichment and heating of the ICM. The physical modeling of the gas includes radiative cooling, star…
In simulations of binary neutron star mergers, the dense matter equation of state (EOS) is required over wide ranges of density and temperature as well as under conditions in which neutrinos are trapped, and the effects of magnetic fields…
Our goal is to take an inventory of complex molecules in three well-known high-mass protostars for which disks or toroids have been claimed and to study the similarities and differences with a sample of massive YSOs without evidence of such…
We present a survey of the ortho-H2D+(1_{1,0}-1_{1,1}) line toward a sample of 10 starless cores and 6 protostellar cores, carried out at the Caltech Submillimeter Observatory. The high diagnostic power of this line is revealed for the…
(Abridged) The water deuterium fractionation (HDO/H$_2$O abundance ratio) has traditionally been used to infer the amount of water brought to Earth by comets. Measuring this ratio in deeply-embedded low-mass protostars makes it possible to…
Water exists in two forms, para and ortho, that have nuclear spin states with different symmetries. Here we report the conversion of fullerene-encapsulated para-water to ortho-water. The enrichment of para-water at low temperatures is…