Related papers: Benchmarking spin-state chemistry in starless core…
We investigate how the H$_2$ ortho-to-para ratio (OPR) and dueterium fractionation in star-forming regions are affected by nuclear spin conversion (NSC) on dust grains. Particular focus is placed on the rotational energy difference between…
We use the deuteration of $c$-$\mathrm{C_{3}H_{2}}$ to probe the physical parameters of starless and protostellar cores, related to their evolutionary states, and compare it to the $\mathrm{N_{2}H^{+}}$-deuteration in order to study…
The vertical distribution of trace gases in planetary atmospheres can be obtained with observations of the atmosphere's thermal emission. Inverting radio observations to recover the atmospheric structure, however, is non-trivial, and the…
Calcium abundance in the atmosphere of Am stars is examined as a function of their evolutionary state within the main sequence. New spectroscopic abundances as well as abundances abtained photometrically by Guthrie (1987) are used, since…
Single-dish observations suggest that the abundances of organic species in star-forming regions of the outer Galaxy, characterised by sub-Solar metallicities, are comparable to those found in the local Galaxy. To understand this…
We present the abundance ratios [X/H] of a large set of chemical species with condensation temperatures from 75 to 1600 K in an almost complete set of 105 planet-host stars and in a volume-limited comparison sample of 88 stars without any…
Water exists as two nuclear-spin isomers, para and ortho, determined by the overall spin of its two hydrogen nuclei. For isolated water molecules the conversion between these isomers is forbidden and they act as different molecular species.…
NH$_{3}$(ammonia) plays a critical role in the chemistry of star and planet formation, yet uncertainties in its binding energy (BE) values complicate accurate estimates of its abundances. Recent research suggests a multi-binding energy…
Long-chain hydrocarbon anions CnH- (n=4, 6, 8) have recently been found to be abundant in a variety of interstellar clouds. In order to explain their large abundances in the denser (prestellar/protostellar) environments, new chemical models…
An optimized molecular model for ammonia, which is based on a previous work of Kristoef et al., Mol. Phys. 97 (1999) 1129--1137, is presented. Improvements are achieved by including data on geometry and electrostatics from quantum…
We present preliminary results of a detailed chemical abundance analysis for a sample of solar-type stars known to exhibit excess infrared emission associated with dusty debris disks. Our sample of 28 stars was selected based on results…
The mechanisms responsible for chemical depletion across diverse astrophysical environments are not yet fully understood. In this paper, we investigate chemical depletion in post-AGB/post-RGB binary stars hosting second-generation…
Interstellar chemistry is important for galaxy formation, as it determines the rate at which gas can cool, and enables us to make predictions for observable spectroscopic lines from ions and molecules. We explore two central aspects of…
Almost all planetary atmospheres are affected by disequilibrium chemical processes. In this paper we introduce our recently developed Chemical Kinetic Model (\texttt{ChemKM}). We show that the results of our HD189733b model are in good…
We mapped the kinetic temperature structure of the Orion molecular cloud 1 with para-H2CO(303-202, 322-221, and 321-220) using the APEX 12m telescope. This is compared with the temperatures derived from the ratio of the NH3(2,2)/(1,1)…
The aim of this paper is to provide a new set of branching ratios for interstellar and planetary chemical networks based on a semi empirical model. We applied, instead of zero order theory (i.e. only the most exoergic decaying channel is…
High levels of deuterium fraction in N$_2$H$^+$ are observed in some pre-stellar cores. Single-zone chemical models find that the timescale required to reach observed values ($D_{\rm frac}^{{\rm N}_2{\rm H}^+} \equiv {\rm N}_2{\rm D}^+/{\rm…
Driven by the Beam Energy Scan (BES) program at the RHIC, researches and discussions on the QCD phase diagram have flourished recently. In order to provide a reference from microscopic transport models, we performed a systematic analysis,…
The proposed earlier relativistic mean-field model with hadron masses and coupling constants depending on the $\sigma$-meson field is generalized to finite temperatures. Within this approach we simulate the in-medium behavior of the hadron…
A major motivation of spectroscopic observations of giant exoplanets is to unveil planet formation processes from atmospheric compositions. Several recent studies suggested that atmospheric nitrogen, like carbon and oxygen, can provide…