Related papers: Benchmarking spin-state chemistry in starless core…
Aims. We aim to develop a chemical model that contains a consistent description of spin-state chemistry in reactions involving chemical species with multiple deuterons. We apply the model to the specific case of deuterated ammonia, to…
Ammonia and its deuterated isotopologues probe physical conditions in dense molecular cloud cores. With the aim of testing the current understanding of the spin-state chemistry of these molecules, we observed spectral lines of NH3, NH2D,…
We determine the ortho/para ratios of NH2D and NHD2 in two dense, starless cores, where their formation is supposed to be dominated by gas-phase reactions, which, in turn, is predicted to result in deviations from the statistical spin…
We constructed two new models for deuterium and spin-state chemistry for the purpose of modeling the low-temperature environment prevailing in starless and pre-stellar cores. The fundamental difference between the two models is in the…
Aims: We aim to investigate the abundances of light deuterium-bearing species such as HD, H2D+ and D2H+ in a gas-grain chemical model including an extensive description of deuterium and spin state chemistry, in physical conditions…
Aims: We aim to simulate radial profiles of molecular abundances and the gas temperature in cold and heavily shielded starless cores by combining chemical and radiative transfer models. Methods: A determination of the dust temperature in a…
The present survey represents a continuation of our study of high mass star forming regions in the lines of deuterated molecules, the first results of which were published in Trofimova et al. (2020). This paper presents the results of…
Observations of deuterated species are useful in probing the temperature, ionization level, evolutionary stage, chemistry, and thermal history of astrophysical environments. The analysis of data from ALMA and other new telescopes requires…
The nuclear-spin chemistry of interstellar water is investigated using the University of Grenoble Alpes Astrochemical Network (UGAN). This network includes reactions involving the different nuclear-spin states of the hydrides of carbon,…
Aims. We aim to investigate whether a multilayer ice model can be as successful as a bulk ice model in reproducing the observed abundances of various deuterated gas-phase species toward starless cores. Methods. We calculate abundances for…
The deuterium fraction [N$_2$D$^+$]/[N$_2$H$^+$], may provide information about the ages of dense, cold gas structures, important to compare with dynamical models of cloud core formation and evolution. Here we introduce a complete chemical…
The standard interstellar ratio of deuterium to hydrogen (D/H) atoms is $\sim 1.5 \times 10^{-5}$. However, the deuterium fractionation is in fact found to be enhanced, to different degrees, in cold, dark cores, hot cores around massive…
We investigate the water deuteration ratio and ortho-to-para nuclear spin ratio of H2 (OPR(H2)) during the formation and early evolution of a molecular cloud, following the scenario that accretion flows sweep and accumulate HI gas to form…
We use spectra and maps of NH2D, ND2H, and ND3, obtained with the CSO, IRAM 30m and Arecibo telescopes, to study deuteration processes in dense cores. The data include the first detection of the hyperfine structure of ND2H. The emission of…
We determined the ortho/para (o/p) ratios of NH2D and NHD2 in the archetypical pre-stellar core L1544. The core was observed in the two lowest rotational lines of ortho- and para-NH2D using the APEX and the IRAM 30 m telescopes. The…
We present a new gas-grain chemical model for the combined isotopic fractionation of carbon and nitrogen in molecular clouds, in which the isotope chemistry of carbon and nitrogen is coupled with a time-dependent description of spin-state…
We quantify if the chemical abundance gradients given by a dynamical model of core collapse including time-dependent changes in density and temperature differ greatly from abundances derived from static models, where the density and…
We carried out a parameter-space exploration of the ammonia abundance in the pre-stellar core L1544, where it has been observed to increase toward the center of the core with no signs of freeze-out onto grain surfaces. We considered static…
The deuterium fractionation of gas-phase molecules in hot cores is believed to reflect the composition of interstellar ices. The deuteration of methanol is a major puzzle, however, because the isotopologue ratio [CH2DOH]/[CH3OD], which is…
Recent observations of the HDO/H$_2$O ratio toward protostars in isolated and clustered environments show an apparent dichotomy, where isolated sources show higher D/H ratios than clustered counterparts. Establishing which physical and…