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Controlling interfaces of phase separating fluid mixtures is key to creating diverse functional soft materials. Traditionally, this is accomplished with surface-modifying chemical agents. Using experiment and theory, we study how mechanical…

Soft Condensed Matter · Physics 2022-08-15 Raymond Adkins , Itamar Kolvin , Zhihong You , Sven Witthaus , M. Cristina Marchetti , Zvonimir Dogic

Interfaces are a most common motif in complex systems. To understand how the presence of interfaces affect hydrophobic phenomena, we use molecular simulations and theory to study hydration of solutes at interfaces. The solutes range in size…

Soft Condensed Matter · Physics 2014-09-05 Amish J. Patel , Patrick Varilly , Sumanth N. Jamadagni , Hari Acharya , Shekhar Garde , David Chandler

A hydrodynamic mechanism of interactions of colloidal particles is considered. The mechanism is based on the assumption of tiny background flows in the experimental cells during measurements by Grier at al. [1-6]. Both trivial (shear flow)…

Soft Condensed Matter · Physics 2007-05-23 Yuri O. Popov

The interaction between boundary layer turbulence and a porous layer is the cornerstone to the interface engineering. In this study, the spatial resolved transfer entropy is used to assess the asymmetry of the causal interaction next to a…

Fluid Dynamics · Physics 2023-12-04 Xu Chu , Wenkang Wang , Bernhard Weigand

This work is devoted to analyze the relation between the thermodynamic properties of a confined fluid and the shape of its confining vessel. Recently, new insights in this topic were found through the study of cluster integrals for…

Statistical Mechanics · Physics 2016-03-09 Ignacio Urrutia

Particles embedded in a fluctuating interface experience forces and torques mediated by the deformations and by the thermal fluctuations of the medium. Considering a system of two cylinders bound to a fluid membrane we show that the…

Soft Condensed Matter · Physics 2011-05-31 Pierre Gosselin , Hervé Mohrbach , Martin Michael Müller

Adsorption of small amphiphilic molecules occurs in various biological and technological processes, sometimes desired, the other times unwanted (e.g., contamination). Surface-active molecules preferentially bind to interfaces and affect…

Soft Condensed Matter · Physics 2022-11-24 Fabio Staniscia , Horacio V. Guzman , Matej Kanduč

Microdrop impact and spreading phenomena are explored as an interface formation process using a recently developed computational framework. The accuracy of the results obtained from this framework for the simulation of high deformation…

Fluid Dynamics · Physics 2015-06-04 J. E. Sprittles , Y. D. Shikhmurzaev

A mean-field density-functional model for three-phase equilibria in fluids (or other soft condensed matter) with two spatially varying densities is analyzed analytically and numerically. The interfacial tension between any two out of three…

Statistical Mechanics · Physics 2019-08-14 Kenichiro Koga , Joseph O. Indekeu

In many physical and biological systems, particles and microorganisms move in the proximity of an interface. Understanding the dynamics of a particle suspended close to an interface is not only important conceptually but is crucial for…

Soft Condensed Matter · Physics 2022-05-18 Mehdi Shaffei Aporvari , Agnese Callegari , Emine Ulku Saritas

The adhesive contact between elastic solids with randomly rough, self affine fractal surfaces is studied by molecular dynamics (MD) simulations. The interfacial binding energy obtained from the simulations of nominally flat and curved…

Soft Condensed Matter · Physics 2011-12-23 N. Mulakaluri , B. N. J. Persson

The curvature dependence of interfacial free energy, which is crucial in quantitatively predicting nucleation kinetics and the stability of bubbles and droplets, can be described in terms of the Tolman length {\delta}. For solid-liquid…

Statistical Mechanics · Physics 2018-08-01 Bingqing Cheng , Michele Ceriotti

An accurate description of the structure and dynamics of interfacial water is essential for phospholipid membranes, since it determines their function and their interaction with other molecules. Here we consider water confined in stacked…

Soft Condensed Matter · Physics 2018-11-16 Sotiris Samatas , Carles Calero , Fausto Martelli , Giancarlo Franzese

The structural characterization of microgels at interfaces is fundamental to understand both their 2D phase behavior and their role as stabilizers that enable emulsions to be broken on demand. However, this characterization is usually…

Surface effects are generally prevailing in confined colloidal systems. Here we report on dispersed nanoparticles close to a fluid membrane. Exact results regarding the static organization are derived for a dilute solution of non-adhesive…

Statistical Mechanics · Physics 2009-11-10 Thomas Bickel , Mabrouk Benhamou , Hamid Kaidi

We consider near-critical two-dimensional statistical systems at phase coexistence on the half plane with boundary conditions leading to the formation of a droplet separating coexisting phases. General low-energy properties of…

Statistical Mechanics · Physics 2022-12-02 Alessio Squarcini , Antonio Tinti

Boundary conditions for the solid-liquid interface of the solidifying pure melt have been derived. In the derivation the model of Gibbs interface is used. The boundary conditions include both the state quantities of bulk phases are taken at…

Materials Science · Physics 2016-11-02 Gennady Buchbinder , Peter Galenko

We study the interface between a solid trapped within a bath of liquid by a suitably shaped non-uniform external potential. Such a potential may be constructed using lasers, external electric or magnetic fields or a surface template. We…

Soft Condensed Matter · Physics 2009-11-13 Abhishek Chaudhuri , Debasish Chaudhuri , Surajit Sengupta

Colloidal particles that are confined to an interface such as the air-water interface are an example of a two-dimensional fluid. Such dispersions have been observed to spontaneously form cluster and stripe morphologies in certain systems…

Soft Condensed Matter · Physics 2008-09-17 A. J. Archer

We revisit the sharp-interface continuum thermodynamics of two-phase multicomponent fluid systems with interfacial mass. Since the published work is not fully consistent, we provide a rigorous derivation of the local balance equations and…

Fluid Dynamics · Physics 2022-08-15 Dieter Bothe