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The recently discovered lithium-rich antiperovskites (Li$_2$Fe)SeO and (Li$_2$Fe)SO host lithium and iron ions on the same atomic position which octahedrally coordinates to central oxygens. In a cubic antiperovskite these sites form Kagome…

Using the first-principles density functional approach, we investigate a material Pr$_2$MgIrO$_6$ (PMIO) of double perovskite structure synthesized recently. According to the calculations, PMIO is a magnetic Mott-Hubbard insulator…

Materials Science · Physics 2016-04-29 Madhav P. Ghimire , Long-Hua Wu , Xiao Hu

The metal-organic-framework (MOF) compound Cu$_3$(HOTP)$_2$, a.k.a. Cu$_3$(HHTP)$_2$, is a small-gap semiconductor containing a kagome lattice of antiferromagnetically coupled $S$=1/2 Cu$^\mathrm{II}$ spins with intra-layer nearest-neighbor…

Strongly Correlated Electrons · Physics 2024-11-28 F. L. Pratt , D. Lopez-Alcala , V. Garcia-Lopez , M. Clemente-Leon , J. J. Baldovi , E. Coronado

Employing complementary torque magnetometry and electron spin resonance on single crystals of herbertsmithite, the closest realization to date of a quantum kagome antiferromagnet featuring a spin-liquid ground state, we provide novel…

Strongly Correlated Electrons · Physics 2017-01-06 A. Zorko , M. Herak , M. Gomilšek , J. van Tol , M. Velázquez , P. Khuntia , F. Bert , P. Mendels

The kagome lattice sits at the crossroad of present research efforts in quantum spin liquids, chiral phases, emergent skyrmion excitations and anomalous Hall effects to name but a few. In light of this diversity, our goal in this paper is…

Strongly Correlated Electrons · Physics 2016-02-17 K. Essafi , Owen Benton , Ludovic D. C. Jaubert

The Zn-paratacamite family, Zn$_{x}$Cu$_{4-x}$(OH)$_{6}$Cl$_{2}$ for $x \, \geq$ 0.33, is an ideal system for studying spin-1/2 frustrated magnetism in the form of antiferromagnetic Cu$^{2+}$ kagome planes. Here we report a new synthesis…

Spangolite (Cu$_6$Al(SO$_4$)(OH)$_{12}$Cl$\cdot$3H$_2$O) is a hydroxy-hydrated copper sulfate mineral with a one-seventh depleted triangular lattice of Cu$^{2+}$ ions in each layer. Experimental measurements revealed a non-magnetic ground…

Strongly Correlated Electrons · Physics 2025-08-18 Philipp Schmoll , Harald O. Jeschke , Yasir Iqbal

ZnCu$_{3}$(OH)$_{6}$Cl$_{2}$ ($S=1/2$) is a promising new candidate for an ideal Kagom\'e Heisenberg antiferromagnet, because there is no magnetic phase transition down to $\sim$50 mK. We investigated its local magnetic and lattice…

Strongly Correlated Electrons · Physics 2008-10-03 T. Imai , E. A. Nytko , B. M. Bartlett , M. P. Shores , D. G. Nocera

A recently discovered kagome antiferromagnet $\rm{Y}_3\rm{Cu}_9(\rm{OH})_{19}\rm{Cl}_8$ has attracted significant interest due to its unique kagome lattice structure and magnetic properties. The kagome lattice has three types of exchange…

Strongly Correlated Electrons · Physics 2024-09-27 Kazu Bodaiji , Katsuhiro Morita , Yoshiyuki Fukumoto

High-resolution time-of-flight powder neutron diffraction and high-field magnetization were measured to investigate the magnetic structure and existence of a field-induced magnetic phase transition in the distorted kagome antiferromagnet…

Spin-1/2 kagome materials have recently attracted a resurgence of interest as they are considered an ideal host of the quantum spin liquid (QSL) state, which can underpin functionality such as superconductivity. Here we report the first…

Strongly Correlated Electrons · Physics 2023-06-27 M. Georgopoulou , D. Boldrin , B. Fåk , P. Manuel , A. Gibbs , J. Ollivier , E. Suard , A. S. Wills

Several Cu$^{2+}$ hydroxide minerals have recently been identified as candidate realizations of the $S=1/2$ kagome Heisenberg model. In this context, we have studied the distorted system KCu$_3$As$_2$O$_7$(OD)$_3$ using neutron scattering…

We investigated the magnetic properties of the ilmenite-type iridate CdIrO$_3$ with a honeycomb lattice formed by Ir$^{4+}$ ions prepared via a solid-state metathesis. The magnetization measurements with using the powder sample reveal a…

Strongly Correlated Electrons · Physics 2020-04-20 Yuya Haraguchi , Hiroko Aruga Katori

The spin-1/2 Cu2+ ions in beta-Cu3V2O8 occupy the sites of a Kagome-staircase lattice, an anisotropic variant of the Kagome net: buckled layers and imbedded plaquettes of three edge-shared CuO4 squares break the ideal Kagome symmetry.…

Condensed Matter · Physics 2012-08-16 N. Rogado , M. K. Haas , G. Lawes , D. A. Huse , A. P. Ramirez , R. J. Cava

Using density functional calculations, we find that the newly synthesized Ca$_2$FeOsO$_6$ has the high-spin Fe$^{3+}$ ($3d^5$)-Os$^{5+}$ ($5d^3$) state. The octahedral Os$^{5+}$ ion has a large intrinsic exchange splitting, and its…

Strongly Correlated Electrons · Physics 2014-08-13 Hongbo Wang , Shasha Zhu , Xuedong Ou , Hua Wu

We report an experimental and computational study of magnetic and electronic properties of the layered Ru(V) oxide SrRu2O6 (hexagonal, P-3 1m), which shows antiferromagnetic order with a N\'eel temperature of 563(2) K, among the highest for…

We present a novel multiferroic double perovskite compound, CaZnFeOsO$_6$ (CZFOO), exhibiting combined ferroelectric and ferrimagnetic properties. Through ab initio density functional theory calculations, we predict CZFOO as a unique…

Materials Science · Physics 2024-08-22 Deepti Rajpoot , Paresh C. Rout , Nikita Acharya , Varadharajan Srinivasan

Using muon spin resonance we examine the organometallic hybrid compound Cu(1,3-benzenedicarboxylate) [Cu(1,3-bdc)], which has structurally perfect spin 1/2 copper kagome planes separated by pure organic linkers. This compound has…

Strongly Correlated Electrons · Physics 2019-10-29 Lital Marcipar , Oren Ofer , Amit Keren , Emily A. Nytko , Daniel G. Nocera , Young S. Lee , Joel S. Helton , Chris Baines

We report through 17O NMR, an unambiguous local determination of the intrinsic kagome lattice spin susceptibility as well as that created around non-magnetic defects issued from natural Zn/ Cu exchange in the S=1/2 (Cu2+) herbertsmithite…

Strongly Correlated Electrons · Physics 2009-11-13 A. Olariu , P. Mendels , F. Bert , F. Duc , J. C. Trombe , M. A. de Vries , A. Harrisson

Neutron scattering measurements have been performed on deuterated powder samples of claringbullite and Zn-doped claringbullite (Zn$_x$Cu$_{4-x}$(OD)$_{6}$FCl). At low temperatures, claringbullite Cu$_4$(OD)$_{6}$FCl forms a distorted…

Strongly Correlated Electrons · Physics 2023-01-26 M. Georgopoulou , B. Fåk , D. Boldrin , J. R. Stewart , C. Ritter , E. Suard , J. Ollivier , A. S. Wills
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