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Trapping macromolecules is impoartant for the study of their conformations, interactions, dynamics and kinetic processes. Here, we develop a variational approach which self-consistently introduces a mean force that controls the…

Soft Condensed Matter · Physics 2024-04-23 Luofu Liu , Chao Duan , Rui Wang

Laser cycling of resonances can remove entropy from a system via spontaneously emitted photons, with electronic resonances providing the fastest cooling timescales because of their rapid relaxation rates. Although atoms are routinely laser…

We analyze theoretically the interplay between the torsional and the rotational motion of an aligned biphenyl-like molecule. To do so, we consider a transition between two electronic states with different internal torsional potentials,…

Chemical Physics · Physics 2017-02-08 Juan J. Omiste , Lars Bojer Madsen

When circularly polarized light is scattered from a rotating target, a rotational Doppler shift (RDS) emerges from an exchange of angular momentum between the spinning object and the electromagnetic field. Here, we used coherently spinning…

Relying on the quantization rule of Raab and Friedrich [Phys. Rev. A (2009) in press], we derive simple and accurate formulae for the number of rotational states supported by a weakly bound vibrational level of a diatomic molecular ion. We…

Atomic Physics · Physics 2010-04-02 Mikhail Lemeshko , Bretislav Friedrich

Polar polyatomic molecules provide an ideal but largely unexplored platform to encode qubits in rotational states. Here, we trap cold (100-600 mK) formaldehyde (H$_2$CO) inside an electric box and perform a Ramsey-type experiment to observe…

Atomic Physics · Physics 2025-04-01 Maximilian Löw , Martin Ibrügger , Gerhard Rempe , Martin Zeppenfeld

Rotational spectroscopy is the most accurate method for determining structures of molecules in the gas phase. It is often assumed that a rotational spectrum is a unique "fingerprint" of a molecule. The availability of large molecular…

We present a quantum logic scheme to detect atomic and molecular ions in different states of angular momentum based on their magnetic $g$-factors. The state-dependent magnetic $g$-factors mean that electronic, rotational or hyperfine states…

Atomic Physics · Physics 2016-10-17 Huanqian Loh , Shiqian Ding , Roland Hablutzel , Gleb Maslennikov , Dzmitry Matsukevich

We study a simple model consisting of an atomic ion and a polar molecule trapped in a single setup, taking into consideration their electrostatic interaction. We determine analytically their collective modes of excitation as a function of…

Atomic Physics · Physics 2016-08-11 Jordi Mur-Petit , Juan José García-Ripoll

Polyatomic molecules are projected to be powerful tools in searches for physics beyond the Standard Model (BSM), including new CP-violating (CPV) interactions and ultralight dark matter (UDM) particles. Certain degrees of freedom present in…

In this letter, atom optic techniques are proposed to control the excitation of a Bose-Einstein condensate in an atomic trap. We show that by employing the dipole potential induced by four highly detuned travelling-wave laser beams with…

Statistical Mechanics · Physics 2009-10-30 Karl-Peter Marzlin , Weiping Zhang

We consider the use of pulse-shaped broadband femtosecond lasers to optically cool rotational and vibrational degrees of freedom of molecules. Since this approach relies on cooling rotational and vibrational quanta by exciting an electronic…

Atomic Physics · Physics 2017-09-13 Chien-Yu Lien , Scott R. Williams , Brian Odom

The interaction between vortex beam (VB) and molecule has drawn much attention in recent years, but the lack of theoretical method somehow limits its further analysis, especially when the molecular rotational degree of freedom is involved…

Optics · Physics 2021-05-04 Guanming Lao

In a cold atom gas subject to a 2D spin-dependent optical lattice potential with hexagonal symmetry, trapped atoms undergo orbital motion around the potential minima. Such atoms are elementary quantum rotors. We develop the theory of such…

Quantum Physics · Physics 2019-10-14 I. Kuzmenko , T. Kuzmenko , Y. Avishai , Y. B. Band

Quantum process tomography is used to fully characterize the evolution of the quantum vibrational state of atoms. Rubidium atoms are trapped in a shallow optical lattice supporting only two vibrational states, which we charcterize by…

Quantum Physics · Physics 2007-05-23 S. H. Myrskog , J. K. Fox , M. W. Mitchell , A. M. Steinberg

We propose and analyze a scheme for sympathetic cooling of the translational motion of polar molecules in an optical lattice, interacting one by one with laser-cooled ions in a radio-frequency trap. The energy gap between the excitation…

Atomic Physics · Physics 2015-05-19 Zbigniew Idziaszek , Tommaso Calarco , Peter Zoller

We propose the implementation of selective interactions of atom-motion subspaces in trapped ions. These interactions yield resonant exchange of population inside a selected subspace, leaving the others in a highly dispersive regime.…

Quantum Physics · Physics 2009-11-10 E. Solano

Ultracold molecules trapped in optical tweezers show great promise for the implementation of quantum technologies and precision measurements. We study a prototypical scenario where two interacting polar molecules placed in separate traps…

Molecules with an odd number of electrons typically display paramagnetic behaviour in a uniform magnetic field. Single-molecule toroics -- a family of open shell lanthanide complexes -- instead display an unprecedented vanishing…

Mesoscale and Nanoscale Physics · Physics 2025-09-09 Kieran Hymas , Alessandro Soncini

Precision searches for time-reversal symmetry violating interactions in polar molecules are extremely sensitive probes of high energy physics beyond the Standard Model. To extend the reach of these probes into the PeV regime, long coherence…

Atomic Physics · Physics 2017-10-03 Ivan Kozyryev , Nicholas R. Hutzler
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