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We report on the optical polarizability of microwave-shielded ultracold NaCs molecules in an optical dipole trap. While dressing a pair of rotational states with a microwave field, we observe a marked dependence of the optical…

Quantum Gases · Physics 2025-01-16 Siwei Zhang , Weijun Yuan , Niccolò Bigagli , Claire Warner , Ian Stevenson , Sebastian Will

Ultracold polar molecules trapped on an optical lattice is a many-body system that, under appropriate conditions, may support collective excitations reminiscent of excitons in solid state crystals. Here, we discuss the rotational…

Atomic Physics · Physics 2017-08-23 Marina Litinskaya , Roman V. Krems

We study the translational motions of homonuclear diatomic molecules prepared in their ${}^3\Sigma$ electronic states, deeply bound vibrational states, and rotational states of well-defined parity. The trapping potential arises due to the…

Mathematical Physics · Physics 2026-03-05 Yurij Yaremko , Maria Przybylska , Andrzej J. Maciejewski

Because molecules can have their orientation locked when embedded into a solid rare-gas matrix, their hyperfine structure is strongly perturbed relative to the freely rotating molecule. The addition of an electric field further perturbs the…

Atomic Physics · Physics 2018-10-03 A. C. Vutha , M. Horbatsch , E. A. Hessels

An inhomogeneous electric field is used to study the deflection of a supersonic beam of water molecules. The deflection profiles show strong broadening accompanied by a small net displacement towards higher electric fields. The profiles are…

Chemical Physics · Physics 2009-11-13 Ramiro Moro , Jaap Bulthuis , Jonathon Heinrich , Vitaly V. Kresin

Ultrafast electron diffraction and time-resolved serial crystallography are the basis of the ongoing revolution in capturing at the atomic level of detail the structural dynamics of molecules. However, most experiments employ the classical…

We propose and analyze an electrostatic-optical nano-scale trap for cold diatomic polar molecules. The main ingredient of our proposal is an square-array of ferroelectric nano-rods {with alternating polarization}. We show that, in contrast…

Quantum Gases · Physics 2018-02-21 Omjyoti Dutta , Geza Giedke

A general scheme for rotational cooling of diatomic heteronuclear molecules is proposed. It uses a superconducting microwave cavity to enhance the spontaneous decay via Purcell effect. Rotational cooling can be induced by sequentially…

Quantum Physics · Physics 2009-11-10 C. H. Raymond Ooi

Preparing molecules at rest and in a highly pure quantum state is a long standing dream in chemistry and physics, so far achieved only for a select set of molecules in dedicated experimental setups. Here, a quantum-limited combination of…

Quantum Physics · Physics 2015-05-30 D. Leibfried

We demonstrate a general method for state detection of trapped ions that can be applied to a large class of atomic and molecular species. We couple a "spectroscopy" ion (Al+) to a "control" ion (Mg+) in the same trap and perform state…

Quantum Physics · Physics 2011-12-12 D. B. Hume , C. W. Chou , D. R. Leibrandt , M. J. Thorpe , D. J. Wineland , T. Rosenband

Electrostatic hexapoles are revealed as a powerful tool in the rotational state-selection and alignment of molecules to be utilized in beam experiments on collisional and photoinitiated processes. In the paper, we report results on the…

Inspired by cotunneling spectroscopy of spin-states in a single OPE5-based molecule, we investigate the prospects for electric control of magnetism in purely organic molecules contacted in a three-terminal geometry. Using the gate…

Mesoscale and Nanoscale Physics · Physics 2012-12-21 J. Fock , M. Leijnse , K. Jennum , A. S. Zyazin , J. Paaske , P. Hedegård , M. Brøndsted Nielsen , H. S. J. van der Zant

We demonstrate the mixing of rotational states in the ground electronic state using microwave radiation to enhance optical cycling in the molecule yttrium (II) monoxide (YO). This mixing technique is used in conjunction with a frequency…

The addition of individual quanta of rotational excitation to a molecule has been shown to markedly change its reactivity by significantly modifying the intermolecular interactions. So far, it has only been possible to observe these…

Chemical Physics · Physics 2024-03-06 Jutta Toscano

We use quantum-logic spectroscopy (QLS) and interrogate rotational transitions of a single CaH+ ion with a highly coherent frequency comb, achieving a fractional statistical uncertainty for a transition line center of 4 x 10^-13. We also…

We make use of an inhomogeneous electrostatic dipole field to impart a quantum-state-dependent deflection to a pulsed beam of OCS molecules, and show that those molecules residing in the absolute ground state, $X ^1\Sigma^+$, $\ket{00^00}$,…

Polyatomic molecules provide complex internal structures that are ideal for applications in quantum information science, quantum simulation, and precision searches for physics beyond the Standard Model. A key feature of polyatomic molecules…

We demonstrate experimentally a method of all-optical selective rotational control in gas mixtures. Using an optical centrifuge - an intense laser pulse whose linear polarization rotates at an accelerated rate, we simultaneously excite two…

Chemical Physics · Physics 2024-06-19 P. Amani , A. A. Milner , V. Milner

We analyze in detail the possibility to use charge-dipole interaction between a single polar molecule or a 1D molecular array and a single Rydberg atom to read out rotational populations. The change in the Rydberg electron energy is…

Quantum Physics · Physics 2016-10-05 Elena Kuznetsova , Seth T. Rittenhouse , H. R. Sadeghpour , Susanne F. Yelin

Photoemission orbital tomography (POT) from photoelectron momentum maps (PMMs) has enabled detailed analysis of the shape and energy of molecular orbitals in the adsorbed state. This study proposes a new POT method based on the PhaseLift.…

Materials Science · Physics 2025-06-03 Kaori Niki , Rena Asano , Ryuji Sakanoue , Manabu Hagiwara , Kazushi Mimura