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We report a confocal Raman study on edges of single layer graphene. It is found that edge orientations could be identified by G mode besides D mode. We observe that G mode at edges of single layer graphene exhibits polar behaviors and…

Materials Science · Physics 2010-08-03 Chunxiao Cong , Ting Yu , Haomin Wang

The graphene-enhanced Raman scattering of Rhodamine 6G molecules on pristine, fluorinated and 4-nitrophenyl functionalized graphene substrates was studied. The uniformity of the Raman signal enhancement was studied by making large Raman…

Polarization resolved micro-Raman spectroscopy was carried out at the edges of bilayer graphene. We find strong dependence of the intensity of the G band on the incident laser polarization, with its intensity dependence being 90 degrees out…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 Milan Begliarbekov , Onejae Sul , Sokratis Kalliakos , Eui-Hyeok Yang , Stefan Strauf

We investigate the evolution of the Raman spectrum of defected graphene as a function of doping. Polymer electrolyte gating allows us to move the Fermi level up to 0.7eV, as monitored by \textit{in-situ} Hall-effect measurements. For a…

Materials Science · Physics 2014-10-14 M. Bruna , A. K. Ott , M. Ijas , D. Yoon , U. Sassi , A. C. Ferrari

Non-dispersive, inter-layer interaction induced Raman peaks (I bands) -- in the region of the D band -- have been observed recently for bilayer graphene, when the two layers were rotated with respect to each other. Here, similar…

Mesoscale and Nanoscale Physics · Physics 2015-06-22 Bálint Gyimesi , János Koltai , Viktor Zólyomi , Jenő Kürti

Few-layer graphene possesses low-energy carriers which behave as massive fermions, exhibiting intriguing properties in both transport and light scattering experiments. Lowering the excitation energy of resonance Raman spectroscopy down to…

In this work we study the behavior of the optical phonon modes in bilayer graphene devices by applying top gate voltage, using Raman scattering. We observe the splitting of the Raman G band as we tune the Fermi level of the sample, which is…

Mesoscale and Nanoscale Physics · Physics 2012-06-07 D. L. Mafra , P. Gava , L. M. Malard , R. S. Borges , G. G. Silva , J. A. Leon , F. Plentz , F. Mauri , M. A. Pimenta

The pseudo-magnetic field generated by mechanical strain in graphene can have dramatic consequences on the behavior of electrons and holes. Here we show that pseudo-magnetic field fluctuations present in crumpled graphene can induce…

The impact of the environment on graphene's properties such as strain, charge density, and dielectric environment can be evaluated by Raman spectroscopy. These environmental interactions are not trivial to determine, since they affect the…

Machine Learning · Computer Science 2022-10-12 Zhuofa Chen , Yousif Khaireddin , Anna K. Swan

Raman spectroscopy is a powerful tool for characterizing the local properties of graphene. Here, we introduce a method for evaluating unknown strain configurations and simultaneous doping. It relies on separating the effects of hydrostatic…

The scattering of lattice excitations (phonons) with the photoexcited charge carriers is of a major concern in optoelectronic devices. Here, the resonant Raman scattering will be utilized to study an exciton-phonon interaction in GaN…

We have studied, both experimentally and theoretically, the change of the so-called 2D band of the Raman scattering spectrum of graphene (the two-phonon peak near 2700 cm-1) in an external magnetic field applied perpendicular to the…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 C. Faugeras , P. Kossacki , D. M. Basko , M. Amado , M. Sprinkle , C. Berger , W. A. de Heer , M. Potemski

We show that graphene deposited on a substrate has a non-negligible density of atomic scale defects. This is evidenced by a previously unnoticed D peak in the Raman spectra with intensity of about 1% with respect to the G peak. We evaluated…

Mesoscale and Nanoscale Physics · Physics 2010-10-15 Z. H. Ni , L. A. Ponomarenko , R. R. Nair , R. Yang , S. Anissimova , I. V. Grigorieva , F. Schedin , Z. X. Shen , E. H. Hill , K. S. Novoselov , A. K. Geim

We present a systematic study of the Raman spectra of optical phonons in graphene monolayers under tunable uniaxial tensile stress. Both the G and 2D bands exhibit significant red shifts. The G band splits into two distinct sub-bands (G+,…

Materials Science · Physics 2008-12-15 Mingyuan Huang , Hugen Yan , Changyao Chen , Daohua Song , Tony F. Heinz , James Hone

The selection rules for dipole and Raman activity can be relaxed due to local distortion of a crystalline structure. In this situation a dipole-inactive mode can become simultaneously active in Raman scattering and in dipole interaction…

Disordered Systems and Neural Networks · Physics 2009-09-25 Lev I. Deych , M. Erementchouk , V. A. Ignatchenko

The paper presents a cooperative consideration of Raman spectra of $^2$ amorphous carbons as well as the nature and type of their amorphicity. The latter was attributed to the amorphization of a new type named as enforced fragmentation. The…

Materials Science · Physics 2020-07-16 E. F. Sheka , Ye. A. Golubev , N. A. Popova

Surface enhanced Raman spectroscopy, is a technique of fundamental importance to analytical science and technology where the amplified Raman spectrum of analytes is used for chemical fingerprinting. Here, we showcase an engineered…

Applied Physics · Physics 2021-06-08 K N Prajapati , Anoop A Nair , S Ravi P Silva , J Mitra

Inelastic light (Raman) scattering has been used to study electronic excitations and phonon anomalies in detwinned, slightly overdoped YBa$_2$Cu$_3$O$_{6.95}$ and moderately overdoped Y$_{0.85}$Ca$_{0.15}$Ba$_2$Cu$_3$O$_{6.95}$ single…

Superconductivity · Physics 2015-05-13 M. Bakr , A. P. Schnyder , L. Klam , D. Manske , C. T. Lin , B. Keimer , M. Cardona , C. Ulrich

Though graphene has been intensively studied by Raman spectroscopy, in this letter, we report a study of second-order overtone and combinational Raman modes in an unexplored range of 1690-2150 cm-1 in nonsuspended commensurate (AB-stacked),…

Materials Science · Physics 2010-10-19 Chunxiao Cong , Ting Yu , Riichiro Saito

We present an analysis of deep-UV Raman measurements of graphite, graphene and carbon nanotubes. For excitation energies above the strong optical absorption peak at the $M$ point in the Brillouin zone ($\approx 4.7\,\text{eV}$), we…

Materials Science · Physics 2015-08-03 Christoph Tyborski , Felix Herziger , Roland Gillen , Janina Maultzsch
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