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In Raman spectroscopy of graphite and graphene, the $D$ band at $\sim 1355$cm$^{-1}$ is used as the indication of the dirtiness of a sample. However, our analysis suggests that the physics behind the $D$ band is closely related to a very…

Mesoscale and Nanoscale Physics · Physics 2013-02-26 Ken-ichi Sasaki , Yasuhiro Tokura , Tetsuomi Sogawa

We present a computational study of the two-phonon Raman spectra of silicene and graphene within a density-functional non-orthogonal tight-binding model. Due to the presence of linear bands close to the Fermi energy in the electronic…

Mesoscale and Nanoscale Physics · Physics 2016-04-29 Valentin N. Popov , Philippe Lambin

Results of room temperature Raman scattering studies of ultrathin graphitic films supported on Si (111)/SiO2 substrates are reported. The results are significantly different from those known for graphite. Spectra were collected using 514 nm…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 Awnish Gupta , Gugang Chen , P. Joshi , S. Tadigadapa , P. C. Eklund

We compare the main feature of the measured Raman scattering spectra from single layer graphene with a bilayer in which the two layers are arbitrarily misoriented. The profiles of the 2D bands are very similar having only one component,…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Philippe Poncharal , Anthony Ayari , Thierry Michel , Jean-Louis Sauvajol

Raman imaging on the edges of single layer micromechanical cleavage graphene (MCG) was carried out. The intensity of disorder-induced Raman feature (D band at ~1350 cm-1) was found to be correlated to the edge chirality: it is stronger at…

Materials Science · Physics 2009-11-13 YuMeng You , ZhenHua Ni , Ting Yu , ZeXiang Shen

We report a comprehensive micro-Raman scattering study of electrochemically-gated graphene field-effect transistors. The geometrical capacitance of the electrochemical top-gates is accurately determined from dual-gated Raman measurements,…

Mesoscale and Nanoscale Physics · Physics 2016-08-08 Guillaume Froehlicher , Stéphane Berciaud

Raman spectroscopy is a fast, non-destructive means to characterize graphene samples. In particular, the Raman spectra show a significant dependence on doping. While the change in position and width of the G peak can be explained by the…

Materials Science · Physics 2015-05-13 D. M. Basko , S. Piscanec , A. C. Ferrari

We demonstrate enhancements of Raman scattering from graphene on two-dimensional photonic crystals using double resonances, which originate from simultaneous enhancements by a localized guided mode and a cavity mode. By adjusting the…

Mesoscale and Nanoscale Physics · Physics 2018-08-24 W. Gomulya , H. Machiya , K. Kashiwa , T. Inoue , S. Chiashi , S. Maruyama , Y. K. Kato

We calculate the probabilities of two- and four-phonon Raman scattering in graphene and show how the relative intensities of the overtone peaks encode information about relative rates of different inelastic processes electrons are subject…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 D. M. Basko

Resonance Raman scattering, which probes electrons, phonons and their interplay in crystals, is extensively used in two-dimensional materials. Here we investigate Raman modes in MoSe$_2$ at different laser excitation energies from 2.33 eV…

Graphene has many unique properties that make it an ideal material for fundamental studies as well as for potential applications. Here we review the recent results on the Raman spectroscopy and imaging of graphene. Raman spectroscopy and…

Materials Science · Physics 2008-10-17 Zhen hua Ni , Ying ying Wang , Ting Yu , Ze xiang Shen

Graphene is an ideal platform to study the coherence of quantum interference pathways by tuning doping or laser excitation energy. The latter produces a Raman excitation profile that provides direct insight into the lifetimes of…

Mesoscale and Nanoscale Physics · Physics 2023-01-24 Xue Chen , Sven Reichardt , Miao-Ling Lin , Yu-Chen Leng , Yan Lu , Heng Wu , Rui Mei , Ludger Wirtz , Xin Zhang , Andrea C. Ferrari , Ping-Heng Tan

Point defects, though atomically small, significantly influence the properties of 2D materials. A general method for characterizing point defect density ($n_{ D }$) in graphenic materials with arbitrary layer number ($n_{ L }$) is currently…

In this work, we study the Raman spectra of twisted bilayer graphene samples as a function of their twist-angles ($\theta$), ranging from 0.03$^\circ$ to 3.40$^\circ$, where local $\theta$ are determined by analysis of their associated…

A theoretical model supported by experimental results explains the dependence of the Raman scattering signal on the evolution of structural parameters along the amorphization trajectory of polycrystalline graphene systems. Four parameters…

We report plasmon-enhanced Raman scattering in graphene coupled to a single plasmonic hotspot measured as a function of laser energy. The enhancement profiles of the G peak show strong enhancement (up to $10^5$) and narrow resonances (30…

Based on a two-band model, we study the electronic Raman scattering intensity in both normal and superconducting states of iron-pnictide superconductors. For the normal state, due to the match or mismatch of the symmetries between band…

Superconductivity · Physics 2015-03-19 C. S. Liu , W. C. Wu

The polarization dependence of the double resonant Raman scattering (2D) band in bilayer graphene (BLG) is studied as a function of the excitation laser energy. It has been known that the complex shape of the 2D band of BLG can be…

Mesoscale and Nanoscale Physics · Physics 2014-03-17 Jae-Ung Lee , Ngor Mbaye Seck , Duhee Yoon , Seon-Myeong Choi , Young-Woo Son , Hyeonsik Cheong

Single-walled carbon nanotubes (SWNTs) with varying degrees of disorder were investigated using multiple-excitation Raman spectroscopy. The lattice disorder was imparted into the nanotubes by the addition of varying amounts of sulfur to the…

Mesoscale and Nanoscale Physics · Physics 2010-12-01 Rahul Rao , Jason Reppert , Xianfeng Zhang , Ramakrishna Podila , Apparao M. Rao , Saikat Talapatra , Benji Maruyama

Surface enhanced Raman scattering (SERS) exploits surface plasmons induced by the incident field in metallic nanostructures to significantly increase the Raman intensity. Graphene provides the ideal prototype two dimensional (2d) test…

Mesoscale and Nanoscale Physics · Physics 2013-04-03 F. Schedin , E. Lidorikis , A. Lombardo , V. G. Kravets , A. K. Geim , A. N. Grigorenko , K. S. Novoselov , A. C. Ferrari