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The electronic structure of few-layer(FL) black phosphorus(BP) sensitively depends on the sample thickness, strain and doping. In this paper, we show that it is also vulnerable to air-exposure. The oxidation of BP caused by air-exposure…

Mesoscale and Nanoscale Physics · Physics 2019-03-27 Fanjie Wang , Guowei Zhang , Shenyang Huang , Chaoyu Song , Chong Wang , Qiaoxia Xing , Yuchen Lei , Hugen Yan

Black phosphorous (BP) is is recently unveiled as a promising two-dimensional direct bandgap semiconducting material. Here, we report the ambipolar field effect transistor behavior of multilayers of BP with ferromagnetic tunnel contacts. We…

Mesoscale and Nanoscale Physics · Physics 2014-07-07 M. Venkata Kamalakar , B. N Madhushankar , André Dankert , Saroj P. Dash

Anisotropy refers to the property of a material exhibiting directionally dependent features. In this paper, we introduce black phosphorous (BP), the most stable allotrope of phosphorus in layered orthorhombic structure with a bandgap of 0.3…

Mesoscale and Nanoscale Physics · Physics 2014-07-30 Fengnian Xia , Han Wang , Yichen Jia

Revived attention in black phosphorus (bP) has been tremendous in the past decade. While many photoinitiated experiments have been conducted, a cross-examination of bP's photocarrier and structural dynamics is still lacking. In this report,…

Materials Science · Physics 2023-05-24 Mazhar Chebl , Xing He , Ding-Shyue Yang

Isolation and characterization of mechanically exfoliated black phosphorus flakes with a thickness down to two single-layers is presented. A modification of the mechanical exfoliation method, which provides higher yield of atomically thin…

Few-layer black phosphorus (BP), as the most alluring graphene analogue owing to its similar structure as graphene and thickness dependent direct band-gap, has now triggered a new wave of research on two-dimensional (2D) materials based…

Black phosphorus (bP) is the second known elemental allotrope with a layered crystal structure that can be mechanically exfoliated down to atomic layer thickness. We have fabricated bP naked quantum wells in a back-gated field effect…

Mesoscale and Nanoscale Physics · Physics 2015-09-04 V. Tayari , N. Hemsworth , I. Fakih , A. Favron , E. Gaufrès , G. Gervais , R. Martel , T. Szkopek

To date, the intrinsic thermal conductivity tensor of bulk black phosphorus (BP), an important 2D material, is still unknown, since recent studies focus on BP flakes not on bulk BP. Here we report the anisotropic thermal conductivity tensor…

Materials Science · Physics 2016-11-22 Bo Sun , Xiaokun Gu , Qingsheng Zeng , Xi Huang , Yuexiang Yan , Zheng Liu , Ronggui Yang , Yee Kan Koh

Black Phosphorus (BP) is unique among layered materials owing to its homonuclear lattice and strong structural anisotropy. While recent investigations on few layers BP have extensively explored the in-plane (a,c) anisotropy, much less…

In this letter, a new approach to chemically dope black phosphorus (BP) is presented, which significantly enhances the device performance of BP field-effect transistors for an initial period of 18 h, before degrading to previously reported…

Materials Science · Physics 2016-07-21 Yuchen Du , Lingming Yang , Hong Zhou , Peide D. Ye

Violet phosphorus (VP) has garnered attention for its appealing physical properties and potential applications in optoelectronics. We present a comprehensive investigation of the photo-degradation and thermal effects of exfoliated VP on…

Due to its corrugated hexagonal lattice structure, Black phosphorus (BP) has unique anisotropic physical properties, which provides an additional freedom for designing devices. Many body interactions, including interactions with phonon, is…

Chemical Physics · Physics 2019-07-23 Shengjie Meng , Hongyan Shi , Hu Jiang , Xiudong Sun , Bo Gao

Black phosphorus has recently emerged as a promising material for high performance electronic and optoelectronic device for its high mobility, tunable mid-infrared bandgap and anisotropic electronic properties. Dynamical evolution of photo…

Black phosphorus (bP) has been recently investigated for next generation nanoelectronic multifunctional devices. However, the intrinsic instability of exfoliated bP (the bP nanoflakes) towards both moisture and air has so far overshadowed…

Thin layers of black phosphorus have recently raised interest for their two-dimensional (2D) semiconducting properties, such as tunable direct bandgap and high carrier mobilities. This lamellar crystal of P atoms stacked together by weak…

Mesoscale and Nanoscale Physics · Physics 2014-08-22 A. Favron , E. Gaufrès , F. Fossard , P. L. Lévesque , A-L. Phaneuf-L'Heureux , N. Y-W. Tang , A. Loiseau , R. Leonelli , S. Francoeur , R. Martel

We report the fabrication, characterization, and modeling of photoconductive antennas using 40 nm thin-film flakes of black phosphorus (BP) as the photoconductor and hexagonal boron nitride (hBN) as a capping layer to prevent oxidation of…

Layered and two-dimensional (2D) materials such as graphene, boron nitride, transition metal dichalcogenides(TMDCs), and black phosphorus (BP) have intriguing fundamental physical properties and bear promise of numerous important…

Mesoscale and Nanoscale Physics · Physics 2018-10-04 Yohannes Abate , Sampath Gamage , Li Zhen , Stephen B. Cronin , Han Wang , Viktoriia Babicheva , Mohammad H. Javani , Mark I. Stockman

Black phosphorous (BP) is a layered semiconductor with high carrier mobility, anisotropic optical response and wide bandgap tunability. In view of its application in optoelectronic devices, understanding transient photo-induced effects is…

Mesoscale and Nanoscale Physics · Physics 2022-09-07 H. Hedayat , A. Ceraso , G. Soavi , S. Akhavan , A. Cadore , C. Dallera , G. Cerullo , A. C. Ferrari , E. Carpene

As an emerging single elemental layered material with a low symmetry in-plane crystal lattice, black phosphorus (BP) has attracted significant research interest owing to its unique electronic and optoelectronic properties, including its…

Black Phosphorus (bP) has emerged as an interesting addition to the category of two-dimensional materials. Surface-science studies on this material are of great interest, but they are hampered by bP's high reactivity to oxygen and water, a…

Mesoscale and Nanoscale Physics · Physics 2018-10-24 Abhishek Kumar , F. Telesio , S. Forti , A. Al-Temimy , C. Coletti , M. Serrano-Ruiz , M. Caporali , M. Peruzzini , F. Beltram , S. Heun