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Important recent advances in transmission electron microscopy instrumentation and capabilities have made it indispensable for atomic-scale materials characterization. At the same time, the availability of two-dimensional materials has…

Materials Science · Physics 2021-05-04 Toma Susi , Jannik C. Meyer , Jani Kotakoski

Electronic properties of transition metal oxides at interfaces are influenced by strain, electric polarization and oxygen diffusion. Linear dichroism (LD) x-ray absorption, diffraction, transport and magnetization on thin La0.7Sr0.3MnO3…

Understanding the role of defects in oxide heterostructures is crucial for future materials control and functionalization. We hence study the impact of oxygen vacancies (OVs) at variable concentrations on orbital- and spin exchange in the…

Materials Science · Physics 2015-10-13 Malte Behrmann , Frank Lechermann

We report on ultrafast optical experiments in which femtosecond mid-infrared radiation is used to excite the lattice of complex oxide heterostructures. By tuning the excitation energy to a vibrational mode of the substrate, a long-lived…

Transition metal oxides hold great potential for the development of new device paradigms because of the field-tunable functionalities driven by their strong electronic correlations, combined with their earth abundance and environmental…

The application of modern layer-by-layer growth techniques to transition-metal oxide materials raises the possibility of creating new classes of materials with rationally designed correlated electron properties. An important step toward…

Materials Science · Physics 2010-10-07 Myung Joon Han , Chris A. Marianetti , Andrew J. Millis

We report on the near edge X-ray absorption fine structure (NEXAFS) spectroscopy of hybrid organic-inorganic resists. These materials are nonchemically amplified systems based on Si, Zr, and Ti oxides, synthesized from organically modified…

Operando synchrotron X-ray techniques have become essential tools for investigating rechargeable batteries as they provide real-time insights into electrochemical processes. However, the high brilliance of synchrotron radiation can alter…

We used x-ray absorption spectroscopy to study the orbital symmetry and the energy band splitting of (111) LaAlO${_3}$/SrTiO${_3}$ and LaAlO${_3}$/EuTiO${_3}$/SrTiO${_3}$ heterostructures, hosting a quasi two-dimensional electron system…

A 2D electron gas system in an oxide heterostructure serves as an important playground for novel phenomena. Here, we show that, by using fractional delta-doping to control the interface's composition in LaxSr1-xTiO3/SrTiO3 artificial oxide…

Strongly Correlated Electrons · Physics 2012-09-28 Woo Seok Choi , Suyoun Lee , Valentino R. Cooper , Ho Nyung Lee

At interfaces between conventional materials, band bending and alignment are classically controlled by differences in electrochemical potential. Applying this concept to oxides in which interfaces can be polar and cations may adopt a mixed…

Key technologies in energy conversion and storage, sensing and chemical synthesis rely on a detailed knowledge about charge transfer processes at electrified solid-liquid interfaces. However, these interfaces continuously evolve as a…

Materials Science · Physics 2022-12-12 Reshma R. Rao , Iris C. G. van den Bosch , Christoph Baeumer

Carrier density and disorder are two crucial parameters that control the properties of correlated two-dimensional electron systems. In order to disentangle their individual contributions to quantum phenomena, independent tuning of these two…

Strongly Correlated Electrons · Physics 2018-07-24 Zhuoyu Chen , Hongtao Yuan , Yanwu Xie , Di Lu , Hisashi Inoue , Yasuyuki Hikita , Christopher Bell , Harold Y. Hwang

Control of structural couplings at the complex-oxide interfaces is a powerful platform for creating new ultrathin layers with electronic and magnetic properties unattainable in the bulk. However, with the capability to design and control…

LaAlO3/SrTiO3 ad LaTiO3/SrTiO3 interfaces are known to host a strongly inhomogeneous (nearly) two-dimensional electron gas (2DEG). In this work we present three unconventional electronic mechanisms of electronic phase separation (EPS) in a…

Mesoscale and Nanoscale Physics · Physics 2015-05-08 N. Bovenzi , F. Finocchiaro , N. Scopigno , D. Bucheli , S. Caprara , G. Seibold , M. Grilli

Strontium titanate, SrTiO3, a widely used substrate material for electronic oxide thin film devices, has provided many interesting features. In a combination with a similar oxide material, LaAlO3, it has recently received great interest. It…

Materials Science · Physics 2013-05-29 Alexey S. Kalabukhov , Robert Gunnarsson , Johan Borjesson , Eva Olsson , Tord Claeson , Dag Winkler

The interface between the polar LaAlO$_3$ and nonpolar SrTiO$_3$ layers has been shown to exhibit various electronic and magnetic phases such as two dimensional electron gas, superconductivity, magnetism and electronic phase separation.…

Strongly Correlated Electrons · Physics 2012-08-31 A. Annadi , A. Putra , Z. Q. Liu , X. Wang , K. Gopinadhan , Z. Huang , S. Dhar , T. Venkatesan , Ariando

The electronic reconstruction at the interface between two insulating oxides can give rise to a highly-conductive interface. In analogy to this remarkable interface-induced conductivity we show how, additionally, magnetism can be induced at…

Strongly Correlated Electrons · Physics 2007-06-13 A. Brinkman , M. Huijben , M. van Zalk , J. Huijben , U. Zeitler , J. C. Maan , W. G. van der Wiel , G. Rijnders , D. H. A. Blank , H. Hilgenkamp

Recent advances in scanning transmission electron microscopy (STEM) instrumentation have made it possible to focus electron beams with sub-atomic precision and to identify the chemical structure of materials at the level of individual…

Materials Science · Physics 2017-03-08 T. Susi , J. C. Meyer , J. Kotakoski

Due to the coexistence of many emergent phenomena, including 2D superconductivity and a large Rashba spin-orbit coupling, 5d transition metal oxides based two-dimensional electron systems (2DESs) have been prospected as one of the potential…

Materials Science · Physics 2022-10-24 H. Yan , S. W. Zeng , K. Rubi , G. J. Omar , Z. T. Zhang , M. Goiran , W. Escoffier , A. Ariando