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We observe and control a molecular vibrational wave packet in an electronically excited state of the neutral hydrogen molecule. In an extreme-ultraviolet (XUV) transient-absorption experiment we launch a vibrational wave packet in the $D…

We investigate theoretically the dissociative ionization of a H2+ molecule using two ultrashort laser (pump-probe) pulses. The pump pulse prepares a dissociating nuclear wave packet on an ungerade surface of H2+. Next, an UV (or XUV) probe…

Quantum Physics · Physics 2013-05-29 Szczepan Chelkowski , André D. Bandrauk

The capability of generating two intense, femtosecond x-ray pulses with controlled time delay opens the possibility of performing time-resolved experiments for x-ray induced phenomena. We have applied this capability to study the…

The ultrafast electronic and nuclear dynamics of H2 laser-induced double ionization is studied using a time-dependent wave packet approach that goes beyond the fixed nuclei approximation. The double ionization pathways are analyzed by…

Quantum Physics · Physics 2011-11-09 Sebastien Saugout , Christian Cornaggia , Annick Suzor-Weiner , Eric Charron

The directional control of molecular dissociation with the laser electric field waveform is a paradigm and was demonstrated for a variety of molecules. In most cases, the directional control occurs via a dissociative ionization pathway. The…

A near-infrared laser generates gain on transitions between the $\text{B}^{\text{2}} \Sigma_{\text{u}}^{\text{+}}$ and $\text{X}^{\text{2}} \Sigma_{\text{g}}^{\text{+}}$ states of the nitrogen molecular cation in part by coupling the…

We demonstrate how dynamic Stark control (DSC) can be achieved on molecular photodissociation in the dipole limit, using single-cycle (FWHM) laser pulses in the terahertz (THz) regime. As the laser-molecule interaction follows the…

Chemical Physics · Physics 2020-03-25 A. Tóth , A. Csehi , G. J. Halász , Á. Vibók

Laser treatment has emerged into a cornerstone of industrial manufacturing. This creates the demand to understand in detail the involved physical processes and their dynamics, to control the process, and to keep guard in-situ the laser…

Optics · Physics 2025-12-16 Jörn Bonse

The use of strong-field (i.e. intensities in excess of 10^13 Wcm-2) few-cycle ultrafast (durations of 10 femtoseconds or less) laser pulses to create, manipulate and image vibrational wavepackets is investigated. Quasi-classical modelling…

Chemical Physics · Physics 2017-02-08 W. A. Bryan , C. R. Calvert , R. B. King , J. B. Greenwood , W. R. Newell , I. D. Williams

We propose a mechanism to produce a superposition of atomic and molecular states by a train of ultrashort laser pulses combined with weak control fields. By adjusting the repetition rate of the pump pulses and the intensity of the coupling…

Atomic Physics · Physics 2014-11-18 Anahit Gogyan , Stephane Guerin , Yuri Malakyan

We investigate molecular dynamics of multiple ionization in N2 through multiple core-level photoabsorption and subsequent Auger decay processes induced by intense, short X-ray free electron laser pulses. The timing dynamics of the…

On the basis of optimal control theory, we numerically study how to optimally manipulate molecular vibrational dynamics by using cycle-averaged polarizability interactions induced by mildly intense non-resonant laser (NR) pulses. As the…

Quantum Physics · Physics 2024-09-05 Reon Ishii , Tomotaro Namba , Hiroyuki Katsuki , Kenji Ohmori , Yukiyoshi Ohtsuki

Electron motion on the (sub-)femtosecond time scale constitutes the fastest response in many natural phenomena such as light-induced phase transitions and chemical reactions. Whereas static electron densities in single molecules can be…

We describe a pump-probe scheme with which the spatial asymmetry of dissociating molecular fragments --- as controlled by the carrier-envelope phase of an intense few-cycle laser pulse --- can be enhanced by an order of magnitude or more.…

Quantum Physics · Physics 2013-07-03 Fatima Anis , B. D. Esry

We present an efficient method for modeling the single and double ionization dynamics of the H$_2$ molecule in ultrashort intense laser fields. This method is based on a semi-analytical approach to calculate the time-dependent single and…

Quantum Physics · Physics 2025-11-04 Jean-Nicolas Vigneau , Thanh-Tung Nguyen Dang , Eric Charron

Ultrafast spectroscopy paved the way for probing transient states of matter produced through photoexcitation. Despite significant advances, the microscopic processes governing the formation of these states remain largely unknown. This study…

Materials Science · Physics 2024-08-23 Francesco Libbi , Anders Johansson , Boris Kozinsky , Lorenzo Monacelli

Short intense laser pulses are routinely used to induce rotational wave packet dynamics of molecules. Ro-vibrational wave packet dynamics has been explored comparatively infrequently, focusing predominantly on extremely light and rigid…

Quantum Gases · Physics 2024-11-12 D. Blume , Q. Guan , J. Kruse , M. Kunitski , R. Doerner

Coherent light pulses of few to hundreds of femtoseconds (fs) duration have prolifically served the field of ultrafast phenomena. While fs pulses address mainly dynamics of nuclear motion in molecules or lattices in the gas, liquid or…

Chemical Physics · Physics 2013-04-26 P. A. Carpeggiani , P. Tzallas , A. Palacios , D. Gray , F. Martín , D. Charalambidis

A quasi-classical model (QCM) of molecular dynamics in intense femtosecond laser fields has been developed, and applied to a study of the effect of an ultrashort `control' pulse on the vibrational motion of a deuterium molecular ion in its…

Quantum Physics · Physics 2010-07-22 W A Bryan , C R Calvert , R B King , G R A J Nemeth , J B Greenwood , I D Williams , W R Newell

Laser cooling of molecules employing broadband optical pumping involves a timescale separation between laser excitation and spontaneous emission. Here, we optimize the optical pumping step using shaped laser pulses. We derive two…

Quantum Physics · Physics 2013-12-24 Daniel M. Reich , Christiane P. Koch
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