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Molecular ions can be held in a chain of laser-cooled atomic ions by sympathetic cooling. This system is ideal for performing high-precision molecular spectroscopy with applications in astrochemistry and fundamental physics. Here we show…

Atomic Physics · Physics 2015-08-20 Ncamiso B. Khanyile , Gang Shu , Kenneth R. Brown

Based on a combined quantum-classical treatment, a complete study of the strong field dynamics of H2+, i.e. including all nuclear and electronic DOF as well as dissociation and ionization, is presented. We find that the ro-vibrational…

Atomic and Molecular Clusters · Physics 2011-08-09 J. Handt , S. M. Krause , J. M. Rost , M. Fischer , F. Grossmann , R. Schmidt

We study the dissociation of H$_2$$^+$ in uv laser pulses by solving the non-Born-Oppenheimer time-dependent Schr\"{o}dinger equation as a function of the photon energy $\omega$ of the pulse. Significant enhancements of the dissociation…

Atomic and Molecular Clusters · Physics 2014-07-22 Kunlong Liu , Qianguang Li , Pengfei Lan , Peixiang Lu

Quantum coherent control of ultrafast bond making and the subsequent molecular dynamics is crucial for the realization of a new photochemistry, where a shaped laser field is actively driving the chemical system in a coherent way from the…

Atomic Physics · Physics 2021-09-03 Liat Levin , Daniel M. Reich , Moran Geva , Ronnie Kosloff , Christiane P. Koch , Zohar Amitay

In this work, we apply the Monte Carlo wave packet method to study the ultrafast nuclear dynamics following inner-shell photoionization of N2 exposed to an ultrashort intense X-ray pulse. The photon energy of the X-ray pulse is large enough…

Atomic Physics · Physics 2022-10-12 Qingli Jing , Hong Qian , Peng Xu

We study the breakup of $\text{H}_2^+$ exposed to super-intense, femtosecond laser pulses with frequencies greater than that corresponding to the ionization potential. By solving the time-dependent Schr\"odinger equation in an extensive…

Atomic Physics · Physics 2016-04-12 Lun Yue , Lars Bojer Madsen

New features of molecular wires can be observed when they are irradiated by laser fields. These effects can be achieved by periodically oscillating fields but also by short laser pulses. The theoretical foundation used for these…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Sven Welack , Michael Schreiber , Ulrich Kleinekathoefer

The last decade has witnessed a rapid advancement in laser technology, enabling the direct monitoring and control of electronic motion on its natural attosecond to sub-femtosecond timescales. Ultrafast processes are conventionally studied…

Chemical Physics · Physics 2026-05-27 Torsha Moitra

Irradiation of isolated water molecules by few-cycle pulses of intense infrared laser light can give rise to ultrafast rearrangement resulting in formation of the H2+ ion. Such unimolecular reactions occur on the potential energy surface of…

Chemical Physics · Physics 2015-06-03 Manish Garg , Ashwani K. Tiwari , Deepak Mathur

We present some approaches to the computation of ultra-fast laser pulses capable of selectively breaking molecular bonds. The calculations are based on a mixed quantum-classical description: The electrons are treated quantum mechanically…

Atomic and Molecular Clusters · Physics 2015-05-27 Kevin Krieger , Alberto Castro , E. K. U. Gross

We describe a method to compute photon-matter interaction and atomic dynamics with X-ray lasers using a hybrid code based on classical molecular dynamics and collisional-radiative calculations. The forces between the atoms are dynamically…

With a specific choice of laser parameters resulting into a so-called exceptional point in the wavelength-intensity plane, it is possible to produce the coalescence of two Floquet resonances describing the photodissociation of the molecule…

Quantum Physics · Physics 2010-11-12 Osman Atabek , Roland Lefebvre , M. Lepers , Amine Jaouadi , Olivier Dulieu , V. Kokoouline

Conventional approaches to probing ultrafast molecular dynamics rely on the use of synchronized laser pulses with a well-defined time delay. Typically, a pump pulse excites a wavepacket in the molecule. A subsequent probe pulse can then…

Mesoscale and Nanoscale Physics · Physics 2020-03-27 R. E. F. Silva , Javier del Pino , Francisco J. García-Vidal , Johannes Feist

We theoretically investigate the laser wavelength dependence of asymmetric dissociation of H$_2^+$. It is found that the electron localization in molecular dissociation is significantly manipulated by varying the wavelength of the driving…

Atomic and Molecular Clusters · Physics 2015-06-03 Kunlong Liu , Weiyi Hong , Qingbin Zhang , Peixiang Lu

We analyze two-center interference effects in the yields of ionization of a dissociating hydrogen molecular ion by an ultrashort VUV laser pulse. To this end, we performed numerical simulations of the time-dependent Schr\"odinger equation…

Quantum Physics · Physics 2015-05-27 A. Picón , A. Bahabad , H. C. Kapteyn , M. M. Murnane , A. Becker

Ultrafast electronic dynamics are typically studied using pulsed lasers. We demonstrate a complementary experimental approach: quantum simulation of ultrafast dynamics using trapped ultracold atoms. Counter-intuitively, this technique…

We demonstrate pump-probe techniques, namely the Doppler spectrometry and the reflectometry in detail, which directly capture the time-resolved ultrafast evolution of high intensity femtosecond laser-driven hot, dense plasma. These…

Laser pulses with stable electric field waveforms establish the opportunity to achieve coherent control on attosecond timescales. We present experimental and theoretical results on the steering of electronic motion in a multi-electron…

A new perspective on how to manipulate molecules by means of very strong laser pulses is emerging with insights from the so-called light-induced potentials, which are the adiabatic potential energy surfaces of molecules severely distorted…

Chemical Physics · Physics 2016-03-03 Bo Y. Chang , Ignacio R. Sola , Seokmin Shin

The dissociative ionization of H2+ interacting with intense, femtosecond extreme-ultraviolet laser pulses is investigated theoretically. This is done by numerical propagation of the time-dependent Schr\"{o}dinger equation for a colinear…

Atomic Physics · Physics 2015-02-25 Lun Yue , Lars Bojer Madsen