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Two perovskite-derived materials, CaCu3Mn4O12 and CaCu3Ti4O12, have drawn much recent interest due to their magnetoresistive, dielectric, and magnetoelectronic characteristics. Here we present initial theoretical insights into each of these…

Materials Science · Physics 2007-05-23 M. D. Johannes , W. E. Pickett , R. Weht

We study the magnetic properties of single crystals of rutile TiO2 implanted with cobalt for various fluences. The temperature variation of zero field cooled(ZFC) and field cooled (FC) magnetization shows a much higher blocking temperature…

Materials Science · Physics 2017-03-16 Shalik Ram Joshi , B. Padmanabhan , Anupama Chanda , N. Shukla , Vivek Malik , D. Kanjilal , Shikha Varma

A thorough investigation of the dielectric properties of Cu2Ta4O12, a material crystallizing in a pseudo-cubic, perovskite-derived structure is presented. We measured the dielectric constant and conductivity of single crystals in an…

Materials Science · Physics 2009-11-10 B. Renner , P. Lunkenheimer , M. Schetter , A. Loidl , A. Reller , S. G. Ebbinghaus

A method of preparing the nanoparticles of CaCu3Ti4O12 (CCTO) with the crystallite size varying from 30 to 200 nm is optimized at a temperature as low as 680 1C from the exothermic thermal decomposition of an oxalate precursor,…

Materials Science · Physics 2013-01-18 P. Thomas , K. Dwarakanath , K. B. R. Varma , T. R. N. Kutty

We observe the large enhancement in the dielectric response near the percolation threshold in a composite nanoparticle system consisting of metallic RuO$_2$ grains embedded into dielectric CaCu$_3$Ti$_4$O$_1$$_2$ (CCTO) matrix and annealed…

Materials Science · Physics 2015-06-19 Rupam Mukherjee , Gavin Lawes , Boris Nadgorny

The origins of an ultrahigh dielectric constant in polycrystalline CaCu3Ti4O12 (CCTO) was studied using the combination of impedance spectroscopy, electron microscopy, and scanning probe microscopy (SPM). Impedance spectra indicate that the…

Materials Science · Physics 2009-11-10 S. V. Kalinin , J. Shin , G. M. Veith , A. P. Baddorf , M. V. Lobanov , H. Runge , M. Greenblatt

SrTiO$_{3}$, a quantum paraelectric, becomes a metal with a superconducting instability after removal of an extremely small number of oxygen atoms. It turns into a ferroelectric upon substitution of a tiny fraction of strontium atoms with…

The complex perovskite Pb2CoTeO6 (PCTO) has been prepared as polycrystalline powders by solid state reaction route, and the crystal structure and magnetic properties have been investigated using a combination of X-ray and neutron powder…

Materials Science · Physics 2010-12-01 S. A. Ivanov , P. Nordblad , R. Mathieu , R. Tellgren , C. Ritter

Magnetic properties of the transition metal oxide BaCoO$_3$ are analyzed on the basis of the experimental and theoretical literature available via ab inito calculations. These can be explained by assuming the material to be formed by…

Strongly Correlated Electrons · Physics 2009-11-10 V. Pardo , J. Rivas , D. Baldomir , M. Iglesias , P. Blaha , K. Schwarz , J. E. Arias

The copper metaborate CuB_2O_4(CBO) has been studied within the parametric space of magnetic field (B) and temperature (T), showing a series of distinct phases, including commensurate and incommensurate magnetic orders, as well as magnetic…

Strongly Correlated Electrons · Physics 2025-12-30 C. H. Lai , M. -J. Hsieh , N. Puri , Yiing-Rei Chen , J. K. Wang , Y. H. Liang , P. -Y. Chen , Shin-ichiro Yano , C. -W. Wang , C. H. Du , C. L. Huang , J. -Y. Lin

Sc$_{2}$Ga$_{2}$CuO$_{7}$ (SGCO) crystallizes in a hexagonal structure (space group: $P$$6$$_{3}/mmc$),\textcolor{black}{{} which can be seen as an alternating stacking of single and double triangular layers. Combining neutron, x-ray, and…

Strongly Correlated Electrons · Physics 2015-11-25 R. Kumar , P. Khuntia , D. Sheptyakov , P. G. Freeman , H. M. Rønnow , B. Koteswararao , M. Baenitz , M. Jeong , A. V. Mahajan

CaCu3Ti4O12 (CCTO) ceramics which has perovskite structure gained considerable attention due to its giant permittivity. But, it has high tan {\delta} (0.1 at 1kHz) at room temperature, which needs to be minimised to the level of practical…

Materials Science · Physics 2013-01-22 P. Thomas , K. B. R. Varma

Investigation of the oxygen-deficient 112-type ordered oxides of the type LnBaCoMnO5+\delta (Ln = Nd, Eu) evidences certain unusual magnetic behavior at low temperatures, compared to the LnBaCo2O5+\delta cobaltites. One observes that the…

Materials Science · Physics 2015-05-18 Asish K. Kundu , V. Pralong , B. Raveau , V. Caignaert

We prospect magneto-dielectricity in $La_{0.53}Ca_{0.47}MnO_{3}$ across its paramagnetic (PMI) to ferromagnetic (FMM) isostructural transition at $T_{C} \sim 253K$, by magnetic ($(M)$), caloric ($(W)$), dielectric ($(\epsilon')$),…

Materials Science · Physics 2017-07-26 Suchita Pandey , Jitender Kumar , A. M. Awasthi

The origin of room temperature (RT) ferromagneticlike behavior in ZnO-based diluted magnetic semiconductors is still an unclear topic. The present work concentrates on the appearance of RT magnetic moments in just mixed ZnO/Co3O4 mixtures…

We investigate magnetic, thermal, and dielectric properties of SrCuTe2O6, which is isostructural to PbCuTe2O6, a recently found, Cu-based 3D frustrated magnet with a corner sharing triangular spin network having dominant first and second…

Strongly Correlated Electrons · Physics 2016-03-16 B. Koteswararao , S. K. Panda , R. Kumar , Kyongjun Yoo , A. V. Mahajan , I. Dasgupta , B. H. Chen , Kee Hoon Kim , F. C. Chou

The present work reports synthesis, as well as a detailed and careful characterization of structural, magnetic, and dielectric properties of differently tempered undoped and doped CaCu3Ti4O12 (CCTO) ceramics. For this purpose, neutron and…

Materials Science · Physics 2010-01-22 S. Krohns , J. Lu , P. Lunkenheimer , V. Brize , C. Autret-Lambert , M. Gervais , F. Gervais , F. Bouree , F. Porcher , A. Loidl

Magnetic and dielectric studies of SrCu3Ti4O12 carried out over 5-300K confirm antiferromagnetic (AFM) ordering of Cu-spins at TN =23K. Dielectric constant {\epsilon}' measured across 1Hz-1MHz signifies quantum paraelectric character,…

Materials Science · Physics 2017-07-26 Jitender Kumar , Ram Janay Choudhary , A. M. Awasthi

Two families of high temperature superconductors whose critical temperatures are higher than 50K are known. One is the copper oxides and the other is the iron-based superconductors. Comparisons of mechanisms between these two in terms of…

Strongly Correlated Electrons · Physics 2014-12-30 Takahiro Misawa , Masatoshi Imada

The effect of cobalt and nickel substitutions for manganese on the physical properties of the perovskite manganite La1.2Bi0.8Mn2-x(Ni/Co)xO6+d, with x = 0.0-0.8, has been investigated. It is observed that the ferromagnetism is enhanced, TC…

Materials Science · Physics 2008-09-04 Asish K. Kundu , R. Ranjith , V. Pralong , V. Caignaert , B. Raveau
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