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The structure of polymers at solid interfaces evolves over time, but the corresponding changes in their rheological properties remain poorly understood. Here, using a home-built quartz tuning fork atomic force microscope-based…

Fluid Dynamics · Physics 2025-08-22 Jaewon Shim , Manhee Lee , Wonho Jhe

We experimentally determine the lattice dynamics of black phosphorus layered crystals through a combination of x-ray diffuse scattering and inelastic x-ray scattering, and we rationalize our experimental findings using $\textit{ab initio}$…

Nominally-pure black phosphorus (BP) is commonly found to be a p-type semiconductor, suggesting the ubiquitious presence of impurity species or intrinsic, charged defects. Moreover, scanning tunnelling microscopy (STM) images of black…

We report high pressure Raman experiments of Black phosphorus up to 24 GPa. The line widths of first order Raman modes A$^1_g$, B$_{2g}$ and A$^2_g$ of the orthorhombic phase show a minimum at 1.1 GPa. Our first-principles density…

Strongly Correlated Electrons · Physics 2017-09-20 Satyendra Nath Gupta , Anjali Singh , Koushik Pal , Biswanath Chakraborti , D. V. S. Muthu , U V Waghmare , A. K. Sood

Vertical integration of two-dimensional materials has recently emerged as an exciting method for the design of novel electronic and optoelectronic devices. Using density functional theory, we investigatethe structural and electronic…

Materials Science · Physics 2015-06-25 Yongqing Cai , Gang Zhang , Yong-Wei Zhang

Thin layers of black phosphorus have recently raised interest for their two-dimensional (2D) semiconducting properties, such as tunable direct bandgap and high carrier mobilities. This lamellar crystal of P atoms stacked together by weak…

Mesoscale and Nanoscale Physics · Physics 2014-08-22 A. Favron , E. Gaufrès , F. Fossard , P. L. Lévesque , A-L. Phaneuf-L'Heureux , N. Y-W. Tang , A. Loiseau , R. Leonelli , S. Francoeur , R. Martel

Measurements of the superconducting transition temperature, T_c, under hydrostatic pressure via bulk AC susceptibility were carried out on several concentrations of phosphorous substitution in BaFe_2(As_{1-x}P_x)_2. The pressure dependence…

Amorphous/crystalline multilayer structures of Fe-P alloys were deposited electrochemically using the single bath technique. Hall-Petch behavior of microhardness with respect to sublayer thickness was observed down to a sublayer thickness…

Materials Science · Physics 2018-12-14 Timo Mueller , Andrea Bachmaier , Ruth Konetschnik , Thomas Schoeberl , Reinhard Pippan

The recent renaissance of black phosphorus (BP) as a two-dimensional 2D layered material has generated tremendous interest in its tunable electronic band gap and highly anisotropic transport properties that offer new opportunities for…

Mesoscale and Nanoscale Physics · Physics 2016-03-08 Shan Dong , Anmin Zhang , Kai Liu , Jianting Ji , Y. G. Ye , X. G. Luo , X. H. Chen , Xiaoli Ma , Yinghao Jie , Changfeng Chen , Xiaoqun Wang , Qingming Zhang

The intrinsic instability of underdoped copper oxides towards inhomogeneous states is one of the central puzzles of the physics of correlated materials. The influence of the Mott physics on the doping-temperature phase diagram of copper…

We directly correlate the local (20-nm scale) and global electronic properties of a device containing mono-, bi- and tri-layer epitaxial graphene (EG) domains on 6H-SiC(0001) by simultaneously performing local surface potential measurements…

We report a study of the structural phase transitions induced by pressure in bulk black phosphorus by using both synchrotron x-ray diffraction for pressures up to 12.2 GPa and Raman spectroscopy up to 18.2 GPa. Very recently black…

Materials Science · Physics 2018-11-21 B. Joseph , S. Caramazza , F. Capitani , T. Clarté , F. Ripanti , P. Lotti , A. Lausi , D. Di Castro , P. Postorino , P. Dore

We report about the energy and momentum resolved optical response of black phosphorus (BP) in its bulk form. Along the armchair direction of the puckered layers we find a highly dispersive mode that is trongly suppressed in the…

Mesoscale and Nanoscale Physics · Physics 2015-03-10 R. Schuster , J. Trinckauf , M. Knupfer , B. Büchner

Two-dimensional crystals are emerging materials for nanoelectronics. Development of the field requires candidate systems with both a high carrier mobility and, in contrast to graphene, a sufficiently large electronic bandgap. Here we…

Materials Science · Physics 2014-07-08 Jingsi Qiao , Xianghua Kong , Zhi-Xin Hu , Feng Yang , Wei Ji

We demonstrate the large scale exfoliation of bulk black phosphorus into few-layers black phosphorus. We use wet-jet mill (WJM) as an industrially scalable exfoliation technique. In order to avoid the degradation by oxidation of the…

The air-water interface is a highly prevalent phase boundary with a far-reaching impact on natural and industrial processes. Water molecules behave differently at the interface compared to the bulk, exhibiting anisotropic orientational…

One prominent structural feature of ionic liquids near surfaces is formation of alternating layers of anions and cations. However, how this layering responds to applied potential is poorly understood. We focus on the structure of…

We demonstrate that encapsulation of atomically thin black phosphorus (BP) by hexagonal boron nitride (h-BN) sheets is very effective for minimizing the interface impurities induced during fabrication of BP channel material for quantum…

Mesoscale and Nanoscale Physics · Physics 2016-07-12 Gen Long , Shuigang Xu , Junying Shen , Jianqiang Hou , Zefei Wu , Tianyi Han , Jiangxiazi Lin , Wing Ki Wong , Yuan Cai , Rolf Lortz , Ning Wang

Thermal conductivity of single layer black phosphorus (BP) is investigated by combining density functional calculations and Peierls-Boltzmann transport equation. Differing from isotropic and divergent thermal conductivities in…

Materials Science · Physics 2015-02-06 Liyan Zhu , Gang Zhang , Baowen Li

The study investigated the effects of atmospheric plasma on various dielectric materials (FR-4, PTFE, Al$_2$O$_3$) and electrode materials (copper, silver, gold-plated copper) used in surface micro-discharge plasma sources. XPS and laser…

Plasma Physics · Physics 2024-10-23 Jonathan Gail , Alisa Schmidt , Markus H. Thoma
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