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Related papers: Raman spectra and electron-phonon coupling in diso…

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We present a new way to tune the electron-phonon coupling (EPC) in graphene by changing the deformation potential with electron/hole doping. We show the EPC for highest optical branch at the high symmetry point K, acquires a strong…

Materials Science · Physics 2011-05-03 Claudio Attaccalite , Ludger Wirtz , Michele Lazzeri , Francesco Mauri , Angel Rubio

Avoiding charge density variations and impurities in graphene is vital for high-quality graphene-based devices. Here, we demonstrate an optical method using Raman 2D peak-split to monitor charge density variations in the range 1-25e10 cm-2.…

Applied Physics · Physics 2020-05-12 Zhuofa Chen , Nathan Ullberg , Mounika Vutukuru , David Barton , Anna K Swan

Since lattice strain and charge density affect various material properties of graphene, a reliable and efficient method is required for quantification of the two variables. While Raman spectroscopy is sensitive and non-destructive, its…

Mesoscale and Nanoscale Physics · Physics 2020-08-10 Gwanghyen Ahn , Sunmin Ryu

Raman spectroscopy of graphene is reviewed from a theoretical perspective. After an introduction of the building blocks (electronic band structure, phonon dispersion, electron-phonon interaction, electron-light coupling), Raman intensities…

Mesoscale and Nanoscale Physics · Physics 2017-03-23 Sven Reichardt , Ludger Wirtz

We perform Raman scattering experiments on natural graphite in magnetic fields up to 45 T, observing a series of peaks due to interband electronic excitations over a much broader magnetic field range than previously reported. We also…

Mesoscale and Nanoscale Physics · Physics 2012-03-14 Y. Kim , Y. Ma , A. Imambekov , N. G. Kalugin , A. Lombardo , A. C. Ferrari , J. Kono , D. Smirnov

In this work we study the behavior of the optical phonon modes in bilayer graphene devices by applying top gate voltage, using Raman scattering. We observe the splitting of the Raman G band as we tune the Fermi level of the sample, which is…

Mesoscale and Nanoscale Physics · Physics 2012-06-07 D. L. Mafra , P. Gava , L. M. Malard , R. S. Borges , G. G. Silva , J. A. Leon , F. Plentz , F. Mauri , M. A. Pimenta

The Raman peak position and linewidth provide insight into phonon anharmonicity and electron-phonon interactions (EPI) in materials. For monolayer graphene, prior first-principles calculations have yielded decreasing linewidth with…

Materials Science · Physics 2022-01-27 Zherui Han , Xiaolong Yang , Sean E. Sullivan , Tianli Feng , Li Shi , Wu Li , Xiulin Ruan

We show the evolution of Raman spectra with number of graphene layers on different substrates, SiO$_{2}$/Si and conducting indium tin oxide (ITO) plate. The G mode peak position and the intensity ratio of G and 2D bands depend on the…

Materials Science · Physics 2007-10-24 Anindya Das , Biswanath Chakraborty , A. K. Sood

We report the observation of an intense anomalous peak at 1608 cm$^{-1}$ in the Raman spectrum of graphene associated to the presence of chromium nanoparticles in contact with graphene. Bombardment with an electron beam demonstrates that…

Twisted bilayer graphene (tBLG) devices with ion gel gate dielectrics are studied using Raman spectroscopy in the twist angle regime where a resonantly enhanced G band can be observed. We observe prominent splitting and intensity quenching…

Mesoscale and Nanoscale Physics · Physics 2015-02-18 Ting-Fung Chung , Rui He , Tai-Lung Wu , Yong P. Chen

We use first-principles density-functional calculations to determine the frequency shift of the A$'_1$-${\bf K}$ phonon (Raman D band) in monolayer graphene, as a function of the charge doping. A detailed DFT study on the electron-phonon…

Materials Science · Physics 2007-05-23 Srijan Kumar Saha , U. V. Waghmare , H. R. Krishnamurthy , A. K. Sood

An analytical study is presented of the double resonant Raman scattering process in graphene, responsible for the D and D$^{\prime}$ features in the Raman spectra. This work yields analytical expressions for the D and D$^{\prime}$…

Mesoscale and Nanoscale Physics · Physics 2015-01-29 J. F. Rodriguez-Nieva , E. B. Barros , R. Saito , M. S. Dresselhaus

Accurate and simple local strain assessment in graphene is one of the crucial tasks in device characterization. Raman spectroscopy is often used for that purpose through monitoring of the G and 2D modes. However, the shifts of those two…

Materials Science · Physics 2018-04-27 Elena del Corro , Ladislav Kavan , Martin Kalbac , Otakar Frank

We have performed scanning gate microscopy (SGM) on graphene field effect transistors (GFET), using a biased metallic nanowire coated with a dielectric layer as a contact mode tip and local top gate. Electrical transport through graphene at…

We calculate the double resonant (DR) Raman spectrum of graphene, and determine the lines associated to both phonon-defect processes, and two-phonons ones. Phonon and electronic dispersions reproduce calculations based on density functional…

Mesoscale and Nanoscale Physics · Physics 2011-07-26 Pedro Venezuela , Michele Lazzeri , Francesco Mauri

As the synthesis of graphene on copper became one of the primary preparation methods for both fundamental research and industrial application, Raman spectra of graphene/Cu systems need to be quantitatively understood regarding how their…

Materials Science · Physics 2020-08-07 Jieun Choi , Seonghyun Koo , Myeongin Song , Daeyool Jung , Sungyool Choi , Sunmin Ryu

We investigated Raman spectra of single-layer and multi-layer graphene under ultraviolet laser excitation at the wavelength of 325 nm. It was found that while the G peak of graphene remains pronounced in UV Raman spectra, the 2D band…

Materials Science · Physics 2015-05-13 Irene Calizo , Igor Bejenari , Muhammad Rahman , Guanxiong Liu , Alexander A. Balandin

We compute, from first-principles, the frequency of the E2g, Gamma phonon (Raman G-band) of graphene, as a function of the charge doping. Calculations are done using i) the adiabatic Born-Oppenheimer approximation and ii) time-dependent…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Michele Lazzeri , Francesco Mauri

The experimental Raman spectra of graphene exhibit a few intense two-phonon bands, which are enhanced through double-resonant scattering processes. Though there are many theoretical papers on this topic, none of them predicts the spectra…

Mesoscale and Nanoscale Physics · Physics 2014-12-17 Valentin N. Popov , Philippe Lambin

Electrostatic gating offers elegant ways to simultaneously strain and dope atomically thin membranes. Here, we report on a detailed \textit{in situ} Raman scattering study on graphene, suspended over a Si/SiO$_2$ substrate. In such a…

Mesoscale and Nanoscale Physics · Physics 2017-01-30 Dominik Metten , Guillaume Froehlicher , Stéphane Berciaud