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Systematic ab initio structure prediction was applied for the first time to predict low energy surface reconstructions by employing the minima hopping method on the \alpha-boron (111) surface. Novel reconstruction geometries were identified…

Materials Science · Physics 2013-10-02 Maximilian Amsler , Silvana Botti , Miguel A. L. Marques , Stefan Goedecker

The icosahedra boron chain and three icosahedra sheets (with {\alpha}, {\delta}4, and {\delta}6 symmetries), constructed by the icosahedra B12, have been obtained as new members of boron family using a highly efficient molecular dynamics…

Materials Science · Physics 2014-09-29 C. B. Kah , M. Yu , P. Tandy , C. S. Jayanthi , S. Y. Wu

We have carried out an ab-initio study of $\alpha$-Sn (111), with the aim of predicting and understanding its structure, reconstructions, and electronic states. We consider a variety of structural possibilities, and optimize them by moving…

Condensed Matter · Physics 2009-10-28 Zhong-Yi Lu , Guido L. Chiarotti , S. Scandolo , E. Tosatti

Large-area single-crystal surface structures were successfully prepared on Cu(111) substrate with boron deposition, which is critical for prospective applications. However, the proposed borophene structures do not match the scanning…

Materials Science · Physics 2022-11-22 Xiao-Ji Weng , Jie Bai , Jingyu Hou , Yi Zhu , Li Wang , Penghui Li , Anmin Nie , Bo Xu , Xiang-Feng Zhou , Yongjun Tian

The structures, stability, mechanical and electronic properties of a-boron and its twined brother a*-boron have been studied by first-principles calculations. Both a-boron and a*-boron consist of equivalent icosahedra B12 clusters in…

Materials Science · Physics 2013-02-27 Chaoyu He , Jianxin Zhong

The surface structure of the SrTiO$_3$(110) polar surface is studied by scanning tunneling microscopy and X-ray photoelectron spectroscopy. Monophased reconstructions in (5$\times$1), (4$\times$1), (2$\times$8), and (6$\times$8) are…

Materials Science · Physics 2015-05-20 Zhiming Wang , Fang Yang , Zhiqiang Zhang , Yuanyuan Tang , Jiagui Feng , Kehui Wu , Qinlin Guo , Jiandong Guo

We present ab initio local-density-functional electronic structure calculations for the (111) and (-1-1-1) surfaces of cubic BN. The energetically stable reconstructions, namely the N adatom, N3 triangle models on the (111), the (2x1),…

Materials Science · Physics 2009-10-31 Krisztina Kadas , Georg Kern , Jurgen Hafner

Boron forms compounds with nearly all metals, with notable exception of copper and other group IB and IIB elements. Here, we report an unexpected discovery of ordered copper boride grown epitaxially on Cu(111) under ultrahigh vacuum.…

Boron-doped diamond (BDD) has attracted much attentions in semi-/super-conductor physics and electrochemistry, where the surface structures play crucial roles. Herein, we systematically re-examined the probable surface reconstructions of…

Materials Science · Physics 2020-10-30 Le The Anh , Shota Iizuka , Yasuaki Einaga , Celine Catalan , Yousoo Kim , Yoshitaka Tateyama

By combining first principles transition state location and molecular dynamics simulation, we unambiguously identify a carbon atom approaching induced bridging metal structure formation on Cu (111) surface, which strongly modify the carbon…

Materials Science · Physics 2023-11-21 Ping Wu , Wenhua Zhang , Zhenyu Li , Jinlong Yang , Jian Guo Hou

Rearrangement of atoms due to broken translational symmetries at the surface of SrTiO$_3$ is scarcely debatable in the present day scenario. Actual concern demands to unveil the true structure and precise mechanism responsible for atomic…

Materials Science · Physics 2018-11-08 Adeel Y Abid , Ning Li , Ayaz Arif , Peng Gao

Charge transfer from a metal substrate stabilizes honeycomb borophene, whose electron deficit would otherwise spoil the hexagonal order of a $\pi$-bonded 2D atomic network. However, the coupling between the substrate and the boron overlayer…

Materials Science · Physics 2022-11-30 Mandana Safari , Erik Vesselli , Stefano de Gironcoli , Stefano Baroni

Elementary semiconductors are rare and attractive, especially for low-dimensional materials. Unfortunately, most of boron nanostructures were found to be metallic, despite of their typical semiconducting bulk structure. Herein, we propose a…

Mesoscale and Nanoscale Physics · Physics 2018-11-01 Shao-Gang Xu , Xiao-Tian Li , Yu-Jun Zhao , Wang-Ping Xu , Ji-Hai Liao , Xiu-Wen Zhang , Hu Xu , Xiao-Bao Yang

We present a comprehensive investigation of reconstructions on $\beta$-Ga$_2$O$_3$(001) combining first-principles calculations with experimental observations. Using ab initio atomistic thermodynamics and replica-exchange grand-canonical…

The subcarbides B12C3 and B13C2 known for their abrasive properties, can be structurally considered as carbon inserted rhombohedral alpha-B12 and expressed as B12{C-C-C} and B12(C-B-C). Using density functional theory DFT computations, the…

Materials Science · Physics 2021-04-07 Samir F. Matar

A silicene-like polymorph of the Si111 7x7 surface is proposed that resolves numerous experimental paradoxes and inconsistencies arising over the past 34 years. An analysis of the three established surface state charge densities from atom…

Materials Science · Physics 2019-05-30 J. E. Demuth

The structure of the Fe3O4(110)-(1x3) surface was studied with scanning tunneling microscopy (STM), low-energy electron diffraction (LEED), and reflection high energy electron diffraction (RHEED). The so-called one-dimensional…

Although (103) is a stable nominal orientation for both silicon and germanium, experimental observations revealed that in the case of silicon this surface remains disordered on an atomic scale even after careful annealing. We report here a…

Materials Science · Physics 2009-11-13 C. V. Ciobanu , F. C. Chuang , D. E. Lytle

The metal-insulator transition observed in the In/Si(111)-4x1 reconstruction is studied by means of ab initio calculations of a simplified model of the surface. Different surface bands are identified and classified according to their origin…

Materials Science · Physics 2009-11-11 Sampsa Riikonen , Andres Ayuela , Daniel Sanchez-Portal

The effect of external static charging on borophenes - 2D boron crystals - is investigated by using first principles calculations. The influence of the excess negative charge on the stability of the 2D structures is examined using a very…

Materials Science · Physics 2021-09-21 T. Tarkowski , J. A. Majewski , N. Gonzalez Szwacki
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