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Consider a Hamiltonian system that consists of a slow subsystem S and a fast subsystem F. The autonomous dynamics of S is driven by an effective Hamiltonian, but its thermodynamics is unexpected. We show that a well-defined thermodynamic…

Statistical Mechanics · Physics 2009-11-13 Armen E. Allahverdyan , Dominik Janzing

It is a truth universally acknowledged that all isolated macroscopic systems must be in want of ever greater disorder, with due apologies to Jane Austen for plagiarizing the opening line in her novel {\it Pride and Prejudice}. This common,…

Statistical Mechanics · Physics 2024-10-01 James P. Hurley

We provide a dynamical proof of the second law of thermodynamics, along the lines of an argument of Penrose and Gibbs, making crucial use of the upper semicontinuity of the mean entropy proved by Robinson and Ruelle and Lanford and…

Mathematical Physics · Physics 2019-11-05 Walter F. Wreszinski

Thermodynamics, and in particular its first law, is of fundamental importance to Science, and therefore of great general interest to all physicists. The first law, although undoubtedly true, and believed by everyone to be true because of…

Statistical Mechanics · Physics 2007-05-23 S. Martinez , A. Plastino , B. H. Soffer

The puzzle of the thermodynamic arrow of time reduces to the question of how the universe could have had lower entropy in the past. I show that no special entropy lowering mechanism (or fluctuation) is necessary. As a consequence of…

Statistical Mechanics · Physics 2015-05-13 L. S. Schulman

Two statements by von Neumann and a thought-experiment by Peres prompts a discussion on the notions of one-shot distinguishability, orthogonality, semi-permeable diaphragm, and their thermodynamic implications. In the first part of the…

Quantum Physics · Physics 2007-05-23 P. G. L. Mana , A. Maansson , G. Bjoerk

We proved when random-variable fluctuations obey the central limit theorem the equality of the uncertainty relation corresponds to the thermodynamic equilibrium state. The inequality corresponds to the thermodynamic non-equilibrium state.…

Quantum Physics · Physics 2007-05-23 You-gang Feng

We introduce the notion of an extended moment in time, the duron. This is a region of temporal ambiguity which arises naturally in the nature of process which we take to be basic. We introduce an algebra of process and show how it is…

Quantum Physics · Physics 2013-02-12 Basil J. Hiley

The status of heat and work in nonequilibrium thermodynamics is quite confusing and non-unique at present with conflicting interpretations even after a long history of the first law in terms of exchange heat and work, and is far from…

Chemical Physics · Physics 2012-06-05 P. D. Gujrati

We proved that the uncertainty relation fits in with many-particle system and the equality of the relation corresponds to the thermodynamic equilibrium state, the inequality of the relation corresponds to the thermodynamic non-equilibrium…

Quantum Physics · Physics 2007-05-23 You-gang Feng

Microscopic physical laws are time-symmetric, hence, a priori there exists no preferential temporal direction. However, the second law of thermodynamics allows one to associate the "forward" temporal direction to a positive variation of the…

Quantum Physics · Physics 2021-11-29 Giulia Rubino , Gonzalo Manzano , Časlav Brukner

The adiabatic theorem states that if we prepare a quantum system in one of the instantaneous eigenstates then the quantum number is an adiabatic invariant and the state at a later time is equivalent to the instantaneous eigenstate at that…

Quantum Physics · Physics 2007-05-23 A. K. Pati , A. K. Rajagopal

The thermodynamic uncertainty relation (TUR) describes a trade-off relation between nonequilibrium currents and entropy production and serves as a fundamental principle of nonequilibrium thermodynamics. However, currently known TURs…

Statistical Mechanics · Physics 2020-09-30 Kangqiao Liu , Zongping Gong , Masahito Ueda

We initially prepare a quantum linear oscillator weakly coupled to a bath in equilibrium at an arbitrary temperature. We disturb this system by varying a Hamiltonian parameter of the coupled oscillator, namely, either its spring constant or…

Statistical Mechanics · Physics 2015-05-27 Ilki Kim

The arrow of time dilemma: the laws of physics are invariant for time inversion, whereas the familiar phenomena we see everyday are not (i.e. entropy increases). I show that, within a quantum mechanical framework, all phenomena which leave…

Quantum Physics · Physics 2010-04-22 Lorenzo Maccone

There is evidence that taking the time average of the work performed by a thermally isolated system effectively "transforms" the adiabatic process into an isothermal one. This approach allows inherent quantities of adiabatic processes to be…

Statistical Mechanics · Physics 2025-10-03 Pierre Nazé

The limits of the Second Law of Thermodynamics, which reigns undisputed in the macroscopic world, are investigated at the mesoscopic level, corresponding to spatial dimensions of a few microns. An extremely simple isolated system, modeled…

Classical Physics · Physics 2007-05-23 Bruno Crosignani , Paolo Di Porto , Claudio Conti

The Kelvin-Planck statement of the Second Law of Thermodynamics is a stricture on the nature of heat receipt by any body suffering a cyclic process. It makes no mention of temperature or of entropy. Beginning with a Kelvin-Planck statement…

Mathematical Physics · Physics 2023-08-28 Martin Feinberg , Richard B. Lavine

Although the third law of thermodynamics was established almost a century ago, it is not yet universally considered to be a fundamental law of physics. A major problem is that there are many materials having residual entropy. Amorphous…

Statistical Mechanics · Physics 2018-12-24 Koun Shirai

This paper is a non-technical, informal presentation of our theory of the second law of thermodynamics as a law that is independent of statistical mechanics and that is derivable solely from certain simple assumptions about adiabatic…

Mathematical Physics · Physics 2009-10-31 Elliott H. Lieb , Jakob Yngvason