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Constitutive equations are derived for the viscoelastic response of rubbery polymers at finite strains. A polymer is thought of as a network of long chains connected to temporary junctions. At a random time, a chain detaches from a…

Soft Condensed Matter · Physics 2007-05-23 Aleksey D. Drozdov , Al Dorfmann

We study the propulsion of a one-dimensional (1D) polymer chain under sinusoidal external forces in the overdamped (low Reynolds number) regime. We show that, when hydrodynamical interactions are included, the polymer presents directional…

Soft Condensed Matter · Physics 2012-09-25 Daniel Santos-Oliván , Alessandro Fiasconaro , Fernando Falo

The non-equilibrium structural and dynamical properties of flexible polymers confined in a square microchannel and exposed to a Poiseuille flow are investigated by mesoscale simulations. The chain length and the flow strength are…

Soft Condensed Matter · Physics 2009-11-13 L. Cannavacciuolo , R. G. Winkler , G. Gompper

We analyze the free energy for translocation of a polymer from the outside of a spherical vesicle to the inside. The process is assumed to be driven by the adsorption of the polymer on the inner surface of the vesicle. We argue that in the…

Soft Condensed Matter · Physics 2009-10-31 K. Kiran Kumar , K. L. Sebastian

Polymers in a turbulent flow are subject to intense strain, which can cause their scission and thereby limit the experimental study and application of phenomena such as turbulent drag reduction and elastic turbulence. In this paper, we…

Fluid Dynamics · Physics 2021-02-17 Dario Vincenzi , Takeshi Watanabe , Samriddhi Sankar Ray , Jason R. Picardo

I develop a kinetic mechanism to explain chain folding in polymer crystallization which is based on the competition between the formation of stems, which is due to frequent occupations of trans states along the chains in the supercooled…

Soft Condensed Matter · Physics 2014-09-23 S. Stepanow

We present a mean-field dynamical theory for single semiflexible polymers which can precisely capture, without fitting parameters, recent fluorescence correlation spectroscopy results on single monomer kinetics of DNA strands in solution.…

Soft Condensed Matter · Physics 2009-10-19 Michael Hinczewski , Roland R. Netz

We present an analysis of a partially directed walk model of a polymer which at one end is tethered to a sticky surface and at the other end is subjected to a pulling force at fixed angle away from the point of tethering. Using the kernel…

Soft Condensed Matter · Physics 2015-05-19 Judy-anne Osborn , Thomas Prellberg

We analyze the nonequilibrium dynamics of single inextensible semiflexible biopolymers as stretching forces are applied at the ends. Based on different (contradicting) heuristic arguments, various scaling laws have been proposed for the…

Soft Condensed Matter · Physics 2007-09-17 B. Obermayer , O. Hallatschek , E. Frey , K. Kroy

The dynamics of flexible polymers in dilute solutions is studied taking into account the hydrodynamic memory, as a consequence of fluid inertia. As distinct from the Rouse-Zimm (RZ) theory, the Boussinesq friction force acts on the monomers…

Soft Condensed Matter · Physics 2009-11-10 V. Lisy , J. Tothova , A. V. Zatovsky

The research is important for a molecular theory of liquid and has a wide interest as an example solving the problem when dynamic parameters of systems can be indirectly connected with their equilibrium properties. In frameworks of the…

Statistical Mechanics · Physics 2007-05-23 Andrei N. Yakunin

The competition between reptation and Rouse Dynamics is incorporated in the Rubinstein-Duke model for polymer motion by extending it with sideways motions, which cross barriers and create or annihilate hernias. Using the Density-Matrix…

Statistical Mechanics · Physics 2009-11-13 Andrzej Drzewinski , J. M. J. van Leeuwen

We investigate dynamics of a self-propelled deformable particle under external field in two dimensions based on the model equations for the center of mass and a tensor variable characterizing deformations. We consider two kinds of external…

Soft Condensed Matter · Physics 2013-07-09 Mitsusuke Tarama , Takao Ohta

The interaction of polymers with small-scale velocity gradients can trigger a coil-stretch transition in the polymers. We analyze this transition within a direct numerical simulation of shear turbulence with an Oldroyd-B model for the…

Chaotic Dynamics · Physics 2009-11-07 Bruno Eckhardt , Jochen Kronjaeger , Joerg Schumacher

We analyze the motion of individual beads of a polymer chain using a discrete version of De Gennes' reptation model that describes the motion of a polymer through an ordered lattice of obstacles. The motion within the tube can be evaluated…

Soft Condensed Matter · Physics 2016-08-15 U. Ebert , L. Schäfer , A. Baumgärtner

We consider the drift of a polymer chain in a disordered medium, which is caused by a constant force applied to the one end of the polymer, under neglecting the thermal fluctuations. In the lowest order of the perturbation theory we have…

Soft Condensed Matter · Physics 2009-10-31 Semjon Stepanow , Michael Schulz

We study the thermodynamic properties of a semiflexible polymer confined inside strips of widths L<=9 defined on a square lattice. The polymer is modeled as a self-avoiding walk and a short range interaction between the monomers and the…

Statistical Mechanics · Physics 2007-05-23 Jurgen F. Stilck

We investigate polymer translocation through a nanopore under a pulling force using Langevin dynamics simulations. We concentrate on the influence of the chain length $N$ and the pulling force $F$ on the translocation time $\tau$. The…

Soft Condensed Matter · Physics 2007-06-27 Ilkka Huopaniemi , Kaifu luo , Tapio Ala-Nissila , See-Chen Ying

We study the diffusion process through an ideal polymer network, using numerical methods. Polymers are modeled by random walks on the bonds of a two-dimensional square lattice. Molecules occupy the lattice cells and may jump to the…

Statistical Mechanics · Physics 2007-05-23 Yong Wu , B Schmittmann , R K P Zia

Forced detachment of a single polymer chain, strongly-adsorbed on a solid substrate, is investigated by two complementary methods: a coarse-grained analytical dynamical model, based on the Onsager stochastic equation, and Molecular Dynamics…

Soft Condensed Matter · Physics 2014-03-27 J. Paturej , J. L. A. Dubbeldam , V. G. Rostiashvili , A. Milchev , T. A. Vilgis