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Tight-binding models provide great insight and are a low-cost alternative to \emph{ab initio} methods for calculation of a material's electronic structure. These models are used to calculate optical responses, including nonlinear optical…

Materials Science · Physics 2025-09-29 Andreas Ghosh , Aaron M. Schankler , Andrew M. Rappe

The large variety of complex electronic structure materials and their alloys, offer highly promising directions for improvements in thermoelectric (TE) power factors (PF). Their electronic structure contains rich features, referred to as…

Materials Science · Physics 2023-11-08 Patrizio Graziosi , Neophytos Neophytou

We observe anharmonic decay of the photoexcited coherent A1g phonon in bismuth to points in the Brillouin zone where conservation of momentum and energy are satisfied for three-phonon scattering. The decay of a coherent phonon can be…

One- and two-dimensional bilayer systems are examples of ultra-tunable quantum materials that are considered as the basis for the new generation of electronic and photonic devices. Here we develop a general theory of the electron band…

Mesoscale and Nanoscale Physics · Physics 2022-06-22 D. V. Chalin , D. I. Levshov , A. E. Myasnikova , S. B. Rochal

Phonons crucially impact a variety of properties of organic semiconductor materials. For instance, charge- and heat transport depend on low-frequency phonons, while for other properties, such as the free energy, especially high-frequency…

Based on a successful description of II-VI ternary alloys, which introduces an empirical bowing parameter to the widely used virtual crystal approximation, we set up a tight-binding Hamiltonian to describe the Zn_{1-y}Cd_ySe_{1-x}Te_x and…

Materials Science · Physics 2019-08-15 A. E. Garcia , A. Zepeda-Navratil , A. Camacho , D. Olguin , R. Baquero

We formulate an ab initio downfolding scheme for electron-phonon coupled systems. In this scheme, we calculate partially renormalized phonon frequencies and electron-phonon coupling, which include the screening effects of high-energy…

Strongly Correlated Electrons · Physics 2015-12-10 Yusuke Nomura , Ryotaro Arita

The electronic properties in a solid depend on the specific form of the wave-functions that represent the electronic states in the Brillouin zone. Since the discovery of topological insulators, much attention has been paid to the…

Mesoscale and Nanoscale Physics · Physics 2020-07-15 Luis Elcoro , Zhida Song , B. Andrei Bernevig

We develop a first-principles scheme to calculate adiabatic and non-adiabatic phonon frequencies in the full Brillouin zone. The method relies on the variational properties of a force-constants functional with respect to the first-order…

Materials Science · Physics 2015-05-19 Matteo Calandra , Gianni Profeta , Francesco Mauri

An algorithm for mapping the true phonon modes of a film, which are defined by a two-dimensional (2D) Brillouin zone, to the modes of the corresponding bulk material, which are defined by a three-dimensional (3D) Brillouin zone, is…

Mesoscale and Nanoscale Physics · Physics 2020-01-08 Hyun-Young Kim , Kevin D. Parish , Alan J. H. McGaughey

We investigate the electric response of chiral phonons on the low-buckled group-IVA monolayers by performing first-principles calculations. The vertical electric field breaks the degeneracy of phonon modes at high-symmetry $\pm K$ points of…

Materials Science · Physics 2021-07-07 Hanyu Wang , Zhichao Zhou , Hao Chen , Chongqun Xia , Lifa Zhang , Xiao Li

First principles computational methods can predict the superconducting critical temperature $T_{\mathrm{c}}$ of conventional superconductors through the electron-phonon spectral function. Full convergence of this quantity requires Brillouin…

Superconductivity · Physics 2025-08-27 Kieran Bozier , Kang Wang , Bartomeu Monserrat , Chris J. Pickard

We develop a computational framework, based on the Boltzmann transport equation, with the ability to compute the thermal transport in nanostructured materials of any geometry using as the only input the bulk thermal conductivity…

Mesoscale and Nanoscale Physics · Physics 2014-10-20 Giuseppe Romano , Jeffrey C. Grossman

A scattering method is used to calculate the surface band structure of Al(111) from 8.6 eV below the Fermi level to 9 eV above it. This method has rarely been implemented previously. The complete complex bulk and surface band structure is…

Materials Science · Physics 2011-04-07 M. N. Read

A simple bulk model of electron-phonon coupling in metals has been surprisingly successful in explaining experiments on metal films that actually involve surface- or other low-dimensional phonons. However, by an exact application of this…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 S. -X. Qu , A. N. Cleland , M. R. Geller

We calculate the contribution to the doping ($n$) and temperature ($T$) dependence of the electrical resistivity of twisted bilayer graphene (TBLG) due to scattering by acoustic phonons. Our calculation retains the full Bistritzer-MacDonald…

Materials Science · Physics 2023-07-12 Seth M. Davis , Fengcheng Wu , Sankar Das Sarma

In this paper, we develop an accurate and efficient framework for computing subwavelength guided modes in high-contrast periodic media with line defects, based on a tight-binding approximation. The physical problem is formulated as an…

Mathematical Physics · Physics 2026-01-21 Habib Ammari , Erik Orvehed Hiltunen , Ping Liu , Borui Miao , Yi Zhu

The phonon-assisted interband optical absorption spectrum of silicon is calculated at the quasiparticle level entirely from first principles. We make use of the Wannier interpolation formalism to determine the quasiparticle energies, as…

We introduce a program named KPROJ that unfolds the electronic and phononic band structure of materials modeled by supercells. The program is based on the $\textit{k}$-projection method, which projects the wavefunction of the supercell onto…

Materials Science · Physics 2025-04-17 Jiaxin Chen , M. Weinert , Mingxing Chen

We consider methods for optimizing the bandgap calculation of 3D materials, considering 340 sample materials. Examined are the effects of the choice of the pseudopotential to describe core electrons, the plane-wave basis set cutoff energy,…

Materials Science · Physics 2025-11-14 Chenxi Lu , Musen Li , Michael J. Ford , Rika Kobayashi , Roger Amos , Jeffrey R. Reimers