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We report the optimized conditions for growing the high quality single crystals of candidate quantum spin-ice Pr2Hf2O7 using the optical floating-zone method. Large single crystals of Pr2Hf2O7 have been grown under different growth…

Strongly Correlated Electrons · Physics 2019-01-02 V. K. Anand , A. T. M. N. Islam , A. Samartzis , J. Xu , N. Casati , B. Lake

We report the growth of large high quality crystals of the frustrated magnet, Pr2Zr2O7 by the floating zone technique. Several crystals have been produced starting with varying levels of excess of Pr6O11 to compensate for the loss of Pr2O3…

Materials Science · Physics 2016-11-09 M. Ciomaga Hatnean , C. Decorse , M. R. Lees , O. A. Petrenko , D. S. Keeble , G. Balakrishnan

Large single crystals of the pyrochlore Pr2Hf2O7 have been successfully grown by the floating zone technique using an optical furnace equipped with high power Xenon arc lamps. Structural investigations have been carried out by both…

We report the low temperature magnetic properties of the pyrochlore Pr$_2$Hf$_2$O$_7$. Polycrystalline and single-crystal samples are investigated using time-of-flight neutron spectroscopy and macroscopic measurements, respectively. The…

Pyrochlore erbium titanate samples in the form of powders (with nominal compositions of Er2Ti2+xO7) and bulk single crystals were prepared to elucidate the effect of synthesis and growth conditions on their composition, structure, and…

Materials Science · Physics 2018-12-14 Q. Wang , A. Ghasemi , A. Scheie , S. M. Koohpayeh

Recent neutron scattering and specific heat studies on the pyrochlore Yb2Ti2O7 have revealed variations in its magnetic behavior below 265mK. In the best samples, a sharp anomaly in the specific heat is observed at T=265mK. Other samples,…

Strongly Correlated Electrons · Physics 2013-02-01 K. A. Ross , Th. Proffen , H. A. Dabkowska , J. A. Quilliam , L. R. Yaraskavitch , J. B. Kycia , B. D. Gaulin

We report a systematic study on the crystal growth of the rare-earth titanates $R_2$Ti$_2$O$_7$ ($R$ = Gd, Tb, Dy, Ho, Y, Er, Yb and Lu) and Y-doped Tb$_{2-x}$Y$_x$Ti$_2$O$_7$ ($x$ = 0.2 and 1) using an optical floating-zone method.…

Strongly Correlated Electrons · Physics 2013-11-13 Q. J. Li , L. M. Xu , C. Fan , F. B. Zhang , Y. Y. Lv , B. Ni , Z. Y. Zhao , X. F. Sun

Muon spin relaxation measurements on some quantum spin ice candidate materials, the insulating pyrochlores Pr2B2O7 (B = Sn, Zr, Hf), have been performed for temperatures in the range 0.05-280 K. The results are indicative of a static…

Strongly Correlated Electrons · Physics 2015-06-22 F. R. Foronda , F. Lang , J. S. Möller , T. Lancaster , A. T. Boothroyd , F. L. Pratt , S. R. Giblin , D. Prabhakaran , S. J. Blundell

High-quality single crystals are essentially needed for the investigation of the novel bulk properties of unconventional superconductors. The availability of such crystals grown by the floating-zone method has helped to unveil the…

Superconductivity · Physics 2019-01-08 J. S. Bobowski , N. Kikugawa , T. Miyoshi , H. Suwa , S. Yonezawa , D. A. Sokolov , A. P. Mackenzie , Y. Maeno

We have successfully grown cm3-size single crystals of the metallic-ferromagnet Sm2Mo2O7 by the floating-zone method using an infrared-red image furnace. The growth difficulties and the remedies found using a 2-mirror image furnace are…

Strongly Correlated Electrons · Physics 2009-11-13 Surjeet Singh , R. Suryanarayanan , Romuald S. Martin , G. Dhalenne , A. Revcolevschi

Single crystals of PrNiO3 were grown under an oxygen pressure of 295 bar using a unique high-pressure optical-image floating zone furnace. The crystals, with volume in excess of 1 mm3, were characterized structurally using single crystal…

Pyrochlore materials are characterized by their hallmark network of corner-sharing rare-earth tetrahedra, which can produce a wide array of complex magnetic ground states. Ferromagnetic Ising pyrochlores often obey the "two-in-two-out" spin…

We report new heat capacity measurements on single crystal Ce$_2$Zr$_2$O$_7$ down to $\sim$ 0.1 K in a magnetic field along the $[1,\bar{1}, 0]$ direction. These new measurements show that the broad hump in the zero-field heat capacity…

Magnetic pyrochlores with non-Kramers rare-earth ions provide a platform for exploring emergent gauge physics and quantum spin-ice behavior, yet the influence of structural disorder on their ground states remains insufficiently understood.…

We have investigated the effect of synthesis and growth conditions on the magnetic, structural, and compositional properties of pyrochlore oxide holmium titanate and demonstrate a method for growing high quality stoichiometric single…

Materials Science · Physics 2018-09-26 Alireza Ghasemi , Allen Scheie , Jonas Kindervater , Seyed M. Koohpayeh

Neutron time-of-flight spectroscopy has been employed to study the crystal-field splitting of Pr$^{3+}$ in the pyrochlore stannate Pr$_{2}$Sn$_{2}$O$_{7}$. The crystal field has been parameterized from a profile fit to the observed neutron…

Strongly Correlated Electrons · Physics 2013-10-28 A. J. Princep , D. Prabhakaran , A. T. Boothroyd , D. T. Adroja

The availability of large high-quality single crystals is an important prerequisite for many studies in solid-state research. The optical floating-zone technique is an elegant method to grow such crystals, offering potential to prepare…

Mm-sized LiMn$_{1-x}$Fe$_x$PO$_4$ single crystals with $0\leq x \leq 1$ were grown by means of the traveling floating-zone technique at elevated Argon pressure of 30~bar. For the various doping levels, the growth process was optimized with…

Strongly Correlated Electrons · Physics 2017-02-07 Christoph Neef , Hubert Wadepohl , Hans-Peter Meyer , Rüdiger Klingeler

CuLa$_2$Ge$_2$O$_8$ forms a distorted triangular lattice of quantum spin-1/2 Cu$^{2+}$ ions. A crystal growth method was developed using the traveling-solvent floating zone technique resulting in the synthesis of a large single crystal (4…

Strongly Correlated Electrons · Physics 2026-04-17 S. Thamban , C. Aguilar-Maldonado , S. Chillal , R. Feyerherm , K. Prokeš , A. J. Studer , D. Abou-Ras , K. Karmakar , A. T. M. N. Islam , B. Lake

Single crystals of the three-dimensional frustrated magnet and spin liquid candidate compound PbCuTe$_2$O$_6$ were grown using both the Travelling Solvent Floating Zone (TSFZ) and the Top-Seeded Solution Growth (TSSG) techniques. The growth…

Materials Science · Physics 2021-11-25 A. R. N. Hanna , A. T. M. N. Islam , R. Feyerherm , K. Siemensmeyer , K. Karmakar , S. Chillal , B. Lake
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