Related papers: Infrared-active phonon modes in monoclinic multife…
Temperature dependence of longitudinal optical phonons with oxygen character was measured in La1-xSrxMnO3 (x=0.2, 0.3) by inelastic neutron scattering in the (1 0 0) cubic direction. The zone center mode intensity is consistent with the…
We have carried out temperature-dependent x-ray diffraction and Raman scattering experiments on powder $Cs_3Bi_2Br_9$. Trigonal to monoclinic structural transition at around 95 K is discussed and shown to be driven by the softening of the…
We report on the study of phonon properties and electron-phonon coupling in thin NbTiN films, which are intensively exploited in superconducting devices. Studied NbTiN films with thicknesses less than 10~nm are disordered with respect to…
The phonon mode parameters and anisotropic mid-infrared dielectric function tensor components of high- Al-content Al$_x$Ga$_{1-x}$N alloys in dependence of the Al content $x$ are precisely determined from mid-infrared spectroscopic…
We have studied the dielectric properties of the ferromagnetic spinel CdCr$_2$S$_4$ from first principles. Zone-center phonons and Born effective charges were calculated by frozen-phonon and Berry phase techniques within LSDA+U. We find…
We derive a dielectric function tensor model approach to render the optical response of monoclinic and triclinic symmetry materials with multiple uncoupled infrared and farinfrared active modes. We apply our model approach to monoclinic…
A crack free and high structural quality Sr2Nb2O7 single crystals were grown by the optical float zone method using optimized growth parameters. Laue pattern confirms single crystalline nature of the grown crystal. Temperature dependent…
The Raman spectra of CaFe2O4 were measured with several exact scattering configurations between 20 and 520K and the symmetry of all observed Raman lines was determined. The Ag and B2g lines were assigned to definite phonon modes by…
We have investigated crystal field and phonon dynamics of the multiferroic orthoferrite DyFeO$_3$ via polarized infrared spectroscopy. Reflectance of single crystals was measured in the far- to mid-infrared spectral range at range of…
We report a comprehensive investigation of the lattice dynamics of URu$_2$Si$_2$ as a function of temperature using Raman scattering, optical conductivity and inelastic neutron scattering measurements as well as theoretical {\it ab initio}…
In this work we study phonon-phonon coupling in bismuth vanadate (BiVO4), known for its second-order transition involving a variety of coupling mechanisms. Using Raman spectroscopy as a probe, we identify two optical coupled phonon modes of…
We report ab-inito density functional theory calculation of phonons in cubic phase of ZrW2O8 in the entire Brillouin zone and identify specific anharmonic phonons that are responsible for large negative thermal expansion (NTE) in terms of…
Infrared reflectivity and time-domain terahertz transmission spectra of EuTiO3 ceramics revealed a polar optic phonon at 6 - 300K, whose softening is fully responsible for the recently observed quantum paraelectric behaviour. Even if our…
We investigated the infrared reflectivity of several Mg- and Si-substituted CuGeO3 single crystals. The temperature dependent b-axis and c-axis optical response is reported. For T<Tsp we detected the activation of zone-boundary phonons…
We report on the temperature dependence of the dielectric tensor elements of $n$-type conductive $\beta$-Ga$_2$O$_3$ from 22$^\circ$C-500$^\circ$C in the spectral range of 1.5~eV--6.4~eV. We present the temperature dependence of the…
A combined generalized spectroscopic ellipsometry measurement and density functional theory calculation analysis is performed to obtain the complete set of infrared active phonon modes in Lu$_{2}$SiO$_{5}$ with monoclinic crystal structure.…
The quadruple Calcium manganite (CaMn7O12) is a multiferroic material that exhibits a giant magnetically-induced ferroelectric polarization which makes it very interesting for magnetoelectric applications. Here, we report the Raman…
We report the first principles investigations on the phonons of three polytypes of BaTiO3 (BTO): paraelectric (PE) cubic Pm-3m and two ferroelectric (FE) phases, tetragonal P4mm and rhombohedral R3m. The phonon frequencies calculated using…
The detailed optical properties of BaFe2As2 have been determined over a wide frequency range above and below the structural and magnetic transition at T_N = 138 K. A prominent in-plane infrared-active mode is observed at 253 cm^{-1} (31.4…
The ab-plane reflectance of a Pr2CuO4 single crystal has been measured over a wide frequency range at a variety of temperatures, and the optical properties determined from a Kramers-Kronig analysis. Above ~ 250 K, the low frequency…