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Dislocations in perovskite oxides have drawn increasing research interest due to their potential of tuning functional properties of electroceramics. Open questions remain regarding the behavior of dislocations concerning their stability…

Materials Science · Physics 2025-12-04 Alexander Frisch , Daniel Isaia , Oliver Preuß , Xufei Fang

In the work the analysis of crystal chemical researches of nickel borocarbides RNi2B2C (R = rare earth) is given. The reasons of representation of dependence of Tc from crystal chemical parameters by two separate curves for magnetic and…

Superconductivity · Physics 2007-05-23 L. M. Volkova , S. A. Polyshchuk , S. A. Magarill , F. E. Herbeck

A series of polycrystalline pyrochlore rare-earth titanate Ho_{2-x}Cr_xTi_2O_7 are synthesized in order to enhance the ferroelectricity of pyrochlore Ho2Ti2O7. For the sample close to the doping level x=0.4, a giant enhancement of…

Materials Science · Physics 2010-07-27 X. W. Dong , S. Dong , K. F. Wang , J. G. Wan , J. -M. Liu

We use ab initio electronic structure calculations within the generalized gradient approximation (GGA+U) to density functional theory (DFT) to determine the microscopic exchange interactions in the series of orthorhombic rare-earth…

Materials Science · Physics 2015-04-22 Natalya S. Fedorova , Claude Ederer , Nicola A. Spaldin , Andrea Scaramucci

We report detailed thermal expansion and magnetostriction experiments on GdCoIn$_5$ and GdRhIn$_5$ single crystal samples that show a sudden change in the dilation at a field B$^\ast$ for temperatures below the N\'eel transition temperature…

Various physical properties of the pyrochlore oxide Y2-xBixIr2O7 have been studied. The magnetizations M measured under the conditions of the zero-field-cooling(ZFC) and the field-cooling(FC) have different values below the temperature…

Strongly Correlated Electrons · Physics 2009-11-10 Natsuki Aito , Minoru Soda , Yoshiaki Kobayashi , Masatoshi Sato

Dynamic magnetic properties of magnetoelectric TmAl3(BO3)4 borate have been investigated by terahertz spectroscopy. Crystal field (CF) transitions within the ground multiplet 3H6 of Tm3+ ions are observed and they are identified as…

Strongly Correlated Electrons · Physics 2017-04-10 A. M. Kuzmenko , A. A. Mukhin , V. Vu. Ivanov , G. A. Komandin , A. Shuvaev , A. Pimenov , V. Dziom , L. N. Bezmaternykh , I. A. Gudim

Using the recently developed method we calculate the crystal field parameters in yttrium and lutetium aluminum garnets doped with seven trivalent Kramers rare-earth ions. We then insert calculated parameters into the atomic-like Hamiltonian…

Strongly Correlated Electrons · Physics 2015-08-06 Eva Mihokova , Pavel Novak , Valentin V. Laguta

Understanding electronic properties of sub-stoichiometric phases of titanium oxide such as Magn\'eli phase Ti4O7 is crucial in designing and modeling resistive switching devices. Here we present our study on Magn\'eli phase Ti4O7 together…

Materials Science · Physics 2015-06-22 Xiaoliang Zhong , Ivan Rungger , Peter Zapol , Olle Heinonen

We present a mean-field theory for magnetic field driven transitions in dipolar coupled gadolinium titanate Gd$_2$Ti$_2$O$_7$ pyrochlore system. Low temperature neutron scattering yields a phase that can be regarded as a 8 sublattice…

Strongly Correlated Electrons · Physics 2009-11-10 Olivier Cepas , B. Sriram Shastry

The magnetic and electronic properties of Eu2Ru2O7 are discussed in terms of the local ruthenium and europium coordinations, electronic band structure calculations and molecular orbital energy levels. A preliminary electronic structure was…

Strongly Correlated Electrons · Physics 2015-06-23 S. Muñoz Pérez , R. Cobas , J. M. Cadogan , J. Albino Aguiar , S. Streltsov , X. Obradors

Neutron scattering and magnetization measurements have been performed on the stuffed pyrochlore system Tb2+xTi2-2xNbxO7. We find that despite the introduction of chemical disorder and increasingly antiferromagnetic interactions, a spin…

Strongly Correlated Electrons · Physics 2010-02-25 B. G. Ueland , J. S. Gardner , A. J. Williams , M. L. Dahlberg , J. G. Kim , Y. Qiu , J. R. D. Copley , P. Schiffer , R. J. Cava

Cubic Y$_{2}$Ti$_{2}$O$_{7}$ single crystals doped with Er$^{3+}$ and Yb$^{3+}$ ions have been studied by the methods of electron spin resonance (ESR) and selective laser spectroscopy. ESR spectra exhibit signals from rare-earth ions that…

We present the results of simulations of the spectral and thermodynamic properties of frustrated $\text{Pr}_2 \text{Zr}_2 \text{O}_7$ crystals using the distribution function of random strains induced by point defects in an elastically…

Strongly Correlated Electrons · Physics 2023-12-18 V. V. Klekovkina , N. M. Abishev

Inelastic neutron scattering was employed to study the crystal-field interaction in the strontium-doped rare-earth compounds R(x)Sr(1-x)CoO(3-z) (R=Pr, Nd, Ho, and Er). Particular emphasis is laid on the effect of oxygen deficiencies which…

Materials Science · Physics 2014-10-27 A. Furrer , A. Podlesnyak , M. Frontzek , I. Sashin , J. P. Embs , E. Mitberg , E. Pomjakushina

We have studied the impact of the magnetic field on the electromagnon excitations in TbMnO3 crystal. Applying magnetic field along the c axis, we show that the electromagnons transform into pure antiferromagnetic modes, losing their polar…

Materials Science · Physics 2011-07-06 P. Rovillain , M. Cazayous , Y. Gallais , M-A. Measson , A. Sacuto , H. Sakata , M. Mochizuki

We present an inelastic neutron scattering study of the crystal electric field levels in the intermetallic ferrimagnets RECo$_{5}$ (RE = Nd and Y). In NdCo$_{5}$, measurements at $5~$K reveal two levels at approximately 28.9 and 52.9 meV.…

Twinning in crystalline materials plays an important role in many transformation and deformation processes, where underlying mechanisms can be strongly influenced by the structural, energetic and kinetic properties of associated twin…

A method to calculate the crystal field parameters {\it ab initio} is proposed and applied to trivalent rare earth impurities in yttrium aluminate and to Tb$^{3+}$ ion in TbAlO$_3$. To determine crystal field parameters local Hamiltonian…

Strongly Correlated Electrons · Physics 2013-06-26 P. Novak , K. Knizek , J. Kunes

We combine two aspects of magnetic frustration, multiferroicity and emergent quasi-particles in spin liquids, by studying magneto-electric monopoles. Spin ice offers to couple these emergent topological defects to external fields, and to…

Strongly Correlated Electrons · Physics 2015-06-24 Ludovic D. C. Jaubert , R. Moessner