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The radiative recombination, Shokley-Read recombination, frontal-surface and rear-surface recombination and the recombination at the heterojunction boundaries and the recombination in the space charge region are considered in the…

Materials Science · Physics 2013-07-04 A. V. Sachenko , V. P. Kostylyov , N. P. Kulish , I. O. Sokolovskyi , A. I. Shkrebtii

Since the photoconversion efficiency $\eta$ of the silicon-based solar cells (SCs) under laboratory conditions is approaching the theoretical fundamental limit, further improvement of their performance requires theoretical modeling and/or…

Materials Science · Physics 2024-09-04 V. P. Kostylyov , A. V. Sachenko , M. Evstigneev , I. O. Sokolovskyi , A. I. Shkrebtii

Surface recombination affects both light-to-electricity and electricity-to-light conversion in solar cells (SCs). Therefore, quantitative analysis and reduction of surface recombination is an important direction in SC research. In this…

We develop a new approach to calculate the obtainable limit of photoconversion efficiency of tandem solar cells (SCs) and applied it to SCs with both vertical and lateral designs at AM0 and AM1.5 conditions. To get the maximum efficiency,…

Materials Science · Physics 2013-09-13 A. V. Sachenko , V. P. Kostylyov , N. P. Kulish , I. O. Sokolovskyi , A. I. Shkrebtii

The paper proposes a theoretical approach to modeling the key characteristics of highly efficient gallium arsenide-based solar cells (SCs), using a one-dimensional SC model. The following recombination mechanisms are considered in the…

Materials Science · Physics 2026-03-30 A. V. Sachenko , V. P. Kostylyov , I. O. Sokolovskyi , A. I. Shkrebtii

The theoretical analysis of photovoltaic conversion efficiency of highly effective silicon solar cells (SC) is performed for n-type and p-type bases. The case is considered when the Shockley-Read-Hall recombination in the silicon bulk is…

A theoretical approach to photoconversion efficiency modeling in perovskite p-i-n structures is developed. The results of this modeling compare favorably with the experiment and indicate that the surfaces of the perovskite solar cells (SCs)…

Mesoscale and Nanoscale Physics · Physics 2017-04-06 A. V. Sachenko , V. P. Kostylyov , A. V. Bobyl , V. M. Vlasyuk , I. O. Sokolovskyi , E. I. Terukov , M. Evstigneev

We analysed self-consistently photoconversion efficiency of direct-gap A3B5 semicon-ductors based solar cells and optimised their main physical characteristics. Using gallium ar-senide (GaAs) as the example and new efficient optimization…

Materials Science · Physics 2014-02-14 A. V. Sachenko , V. P. Kostylyov , M. R. Kulish , I. O. Sokolovskyi , A. Chkrebtii

The selfconsistent model for the temperature dependence of photoconversion efficiency $\eta$ for highly efficient silicon solar cells (SCs) is developed. It is demonstrated that effect of the efficiency decrease due to increasing…

The Shockley equation (SE), originally derived to describe a p--n junction, was frequently used in the past to simulate current--voltage (j/V) characteristics of organic solar cells (OSC). In order to gain a more detailed understanding of…

Materials Science · Physics 2012-09-06 A. Foertig , J. Rauh , V. Dyakonov , C. Deibel

We introduce a method to calculate defect-assisted Shockley-Read-Hall (SRH) recombination rates in imperfect semiconductors from first principles. The method accounts for the steady state recombination dynamics under given non-equilibrium…

Materials Science · Physics 2025-07-25 Jiban Kangsabanik , Kristian S. Thygesen

We present a multijunction detailed balance model that includes the effects of luminescent coupling, light trapping and nonradiative recombination, suitable for treatment of multijunction solar cells and photonic power converters --…

Applied Physics · Physics 2020-07-15 Daixi Xia , Jacob J. Krich

The spectral response of quantum well solar cells (QWSCs) is well understood. We describe work on QWSC dark current theory which combined with SR theory yields a system efficiency. A methodology published for single quantum well (SQW)…

Mesoscale and Nanoscale Physics · Physics 2010-06-10 James P. Connolly , Jenny Nelson , Ian Ballard , Keith W. J. Barnham , Carsten Rohr , Chris Button , John Roberts , Tom Foxon

Multiple exciton generation solar cells exhibit a low power conversion efficiency owing to nonradiative recombination even if numerous electron and hole pairs are generated per incident photon. This paper elucidates the non-idealities of…

Applied Physics · Physics 2021-04-14 Jongwon Lee

Single junction Si solar cells dominate photovoltaics but are close to their efficiency limits. This paper presents ideal limiting efficiencies for tandem and triple junction multijunction solar cells subject only to the constraint of the…

Materials Science · Physics 2013-12-11 J. P. Connolly , D. Mencaraglia , C. Renard , D. Bouchier

Recombination of photogenerated charge carriers in polymer bulk heterojunction (BHJ) solar cells reduces the short circuit current (Jsc) and the fill factor (FF). Identifying the mechanism of recombination is, therefore, fundamentally…

Materials Science · Physics 2015-05-20 Sarah R. Cowan , Anshuman Roy , Alan J. Heeger

The charge carrier mobility is a key parameter for the organic bulk heterojunction solar cell efficiency. It was recently shown that the interplay charge carrier transport and recombination, both depending on electron and hole mobilities,…

Materials Science · Physics 2011-01-17 A. Wagenpfahl , C. Deibel , V. Dyakonov

Drift-diffusion model is an indispensable modeling tool to understand the carrier dynamics (transport, recombination, and collection) and simulate practical-efficiency of solar cells (SCs) through taking into account various carrier…

Mesoscale and Nanoscale Physics · Physics 2017-04-20 Xingang Ren , Zishuai Wang , Wei E. I. Sha , Wallace C. H. Choy

The power conversion efficiency of organic solar cells has recently improved beyond 20%. The active layers of these devices comprise of at least two organic semiconductors, forming a type II heterojunction. Hereby, the device performance is…

Materials Science · Physics 2026-01-22 Jonathan L. Langentepe-Kong , Manasi Pranav , Safa Shoaee , Dieter Neher

The recombination rate in the space charge region (SCR) of a silicon-based barrier structure with long Shockley-Reed-Hall lifetime is calculated theoretically taking into account the concentration gradient of excess electron-hole pairs in…

Other Condensed Matter · Physics 2023-05-23 A. V. Sachenko , V. P. Kostylyov , M. Evstigneev
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